Muutke küpsiste eelistusi

Spectrophotometric Determination of Palladium & Platinum: Methods & Reagents [Kõva köide]

  • Formaat: Hardback, 118 pages, kõrgus x laius: 229x152 mm, kaal: 453 g, 2 Tables, black and white; 4 Line drawings, black and white; 4 Illustrations, black and white
  • Ilmumisaeg: 28-Mar-2023
  • Kirjastus: CRC Press
  • ISBN-10: 1032232447
  • ISBN-13: 9781032232447
Teised raamatud teemal:
Spectrophotometric Determination of Palladium & Platinum: Methods & ReagentsSuurem pilt
  • Formaat: Hardback, 118 pages, kõrgus x laius: 229x152 mm, kaal: 453 g, 2 Tables, black and white; 4 Line drawings, black and white; 4 Illustrations, black and white
  • Ilmumisaeg: 28-Mar-2023
  • Kirjastus: CRC Press
  • ISBN-10: 1032232447
  • ISBN-13: 9781032232447
Teised raamatud teemal:
Püsilink: https://www.kriso.ee/db/9781032232447.html
Märksõnad:

This versatile resource consolidates available methods for the spectrophotometric determination of palladium and platinum and serves as a practical ready-to-use guide for those researching palladium and platinum and for those working in the field of medicinal metal complexes of the two metals. The beauty of spectrophotometric methods lies in their simplicity, convenience, and easy operability, not to mention their cost-effectiveness. They can be automated easily and are thus the most affordable methods for the below reasons:

  • Address analysts from all areas of industry, research labs and postgraduate students of analytical or medicinal chemistry as well as material science.?

  • Detail all recently developed methods for palladium and platinum determination using spectrophotometry in a single source.?

  • Organized so that anyone interested in a particular method using a specific reagent can go directly to those details.?

  • Facilitates the development of better methods for specific conditions of a sample.??



This versatile resource consolidates new and available methods for the determination of palladium and platinum and serves as a practical ready-to-use guide for those researching palladium and platinum and for those working in the field of medicinal metal complexes of the two metals.
Preface xv
Acknowledgements xvii
Author xix
Introduction 1(2)
Chapter 1 Spectrophotometric Determination of Palladium and Platinum: Methods & Reagents
3(30)
1.1 Introduction
3(1)
1.2 Spectrophotometric Methods
4(1)
1.3 Theory behind the Technique
5(3)
1.4 Important Characteristics of Spectrophotometric Method
8(1)
1.5 Procedural Details of Spectrophotometric Methods -- A Brief Outline
9(1)
1.6 Spectrophotometric Reagents
10(23)
References
29(4)
Section A Spectrophotometric Determination of Palladium -- Reagents and Methods
Chapter 2 Analytical Reagents Having Oxygen (O)as Donor Atom
33(6)
2.1 Naphthols
33(6)
2.1.1 1-Nitroso-2-Naphthol
33(1)
2.1.2 1-(5-Benzylthiazol-2yl) Azonaphthalen-2-ol (BnTAN)
33(1)
2.1.3 5-Hydroxyimino-4-Imino-Thiazolidin-2-One (HITO)
34(1)
2.1.4 3-Hydroxy-2-(2'-Thienyl)-4-H-Chromen-4-One
34(1)
2.1.5 Dibromo-O-Nitro-Phenylfluorone (DBON-PF)
34(1)
2.1.6 Pyridyl-Azo-Naphthol (PAN)
35(1)
2.1.7 4-(2-Pyridylazo)-Resorcinol (PAR)
35(1)
2.1.8 2-(2-Quinolinylazo)-5-Dimethyl Aminobenzoic Acid (QADMAB)
35(1)
2.1.9 α-Benzyl Monoxide-Molten Benzophenone
36(1)
2.1.10 1-(2-Pyridylazo)-2-Naphthol (PAN)
36(1)
2.1.11 2-Arylthio-p-Nitro-Acetophenone
36(1)
2.1.12 Pyrogallol Red (PGR) with H2O2
36(1)
2.1.13 Pyridylazo Resorcinol
37(1)
References
37(2)
Chapter 3 Analytical Reagents Having Nitrogen (N)as Donor Atom
39(6)
3.1 2-(5-Bromo-2-Pyridylazo)-5-[ N-n-Propyl-N-(3-Sulfopropyl) Amino] Aniline
39(1)
3.2 L-Cystine
39(1)
3.3 2-Hydrazinopyridine
39(1)
3.4 2-Hydroxy-5-Methylacetophenone Isonicotionoylhydrazone (HMAINH)
40(1)
3.5 Isonitroso-p-Me.acetophenonephenyl Hydrazone (HIMAPH)
40(1)
3.6 1-(2-Naphthalene)-3-(2-Thiazole)-Triazene (NTT)
40(1)
3.7 p-Antipyrinylazo Benzoic Acid (AABA)
41(1)
3.8 3,4-Dihydroxybenzaldehydeisonicotinoyl-hydrazone (3,4-DHBINH)
41(1)
3.9 N,N,N',N'-Tetra(2-ethylhexyl) Thiodiglycomide T(2EH) TDGA
41(1)
3.10 2-Hydroxy-1-naphthalene Carboxaldehyde Hydrazine Carboxamide
42(1)
3.11 1-(4-Antipyrine)-3-(2-thiazolyl)triazene (ATTA)
42(1)
3.12 N-Bulyl-N'-(sodium p-amino-benzenesulfonate) Thiourea (BPT
42(1)
3.13 Methdilazine Hydrochloride
43(1)
3.14 2-Hydroxy-3-carboxy-5-sulfophenyldiazoaminoazobenzene (HCSDAA)
43(1)
3.15 3-Hydroxy-3-phenyl-1-p-carboxyphenyltriazene
43(2)
References
44(1)
Chapter 4 Analytical Reagents Having (N) and (O) as Donor Atoms
45(8)
4.1 4-(4'-Fluorobenzylideneimino)-3-methyl- 5-mercapto-1,2,4-triazole (FBIMMT)
45(1)
4.2 1-(2-Benzothiozolyazo)-2-hydroxy-3-naphthoic acid (BTAHN)
45(1)
4.3 2,4-Dihydroxy-5-iodo-α-phenyl acetophenone oxime [ DHI-α-PAO]
46(1)
4.4 α-Furildioxime
46(1)
4.5 3,4-Dihydroxybenzaldehyde Isonicotinoyl Hydrazone (3,4-DHBINH)
47(1)
4.6 2,4-Dihydroxybenzophenone Oxime (DHBPO)
47(1)
4.7 5-Methyl-2,3-hexanedione dioxime (H2MHDDO)
47(1)
4.8 2,6-Dibromo-4-carboxybenzenediazo-aminoazobenzene (DBCDAA) and 1,10-phenanthroline (phen)
48(1)
4.9 p-Nitroisonitrosoacetophenone
48(1)
4.10 1-Phenyl-1-2-butanedione Dioxime (H2PBDD)
48(1)
4.11 2-Cis-3,7-di-Me 2,6-octadien-1-oxime (CDOO)
49(1)
4.12 2,2'-Dipyridyl-2-pyridylhydrazone (DPPH)
49(1)
4.13 8-Aminoquinoline-5-azo-p-benzoic Acid
49(1)
4.14 5,6-Dimethyl-1,3-indanedione-2-oxime
50(3)
References
50(3)
Chapter 5 Analytical Reagents Having (O), (N) and (S) as Donor Atoms and Miscellaneous Reagents
53(12)
5.1 Pyridoxal Thiosemicarbazone
53(1)
5.2 4-[ N'-(4-Imino-2-oxo-thiazolidin-5-ylidene)-hydrazino]-benzenesulfonic Acid (ITHBA)
53(1)
5.3 5,6-Diphenyl-2,3-dihydro 1,2,4-Triazene-3-thione
54(1)
5.4 N-Decylpyridine-4-amine and Pyridine-2-thiol
54(1)
5.5 Pyridoxal Thiosemicarbazone (PDT)
54(1)
5.6 (+) Cis-1,5-benzothiazepin-4-(5H)one, 3-(acetyloxy)-5-[ 2-(dimethylamino)ethyl]-2,3-dihydro-2-(4-methoxyphenyl)-monohydro chloride (DILTIAZEM)
55(1)
5.7 P-[ N,N-Bis (2-Chloroethyl)amino] Benzaldehyde Thiosemicarbazone (CEABT)
55(1)
5.8 Isonitro p-Nitroacetophenone Thiosemicarbazone (HINATS)
55(1)
5.9 4-(N,N-Diethylamino) Benzaldehyde Thiosemicarbazone (DEABT)
56(1)
5.10 2,5-Dimercapto-1,3,4 Thiadiazole (DMTD)
56(1)
5.11 Allylthiourea
56(1)
5.12 N,N-Diphenyl and N,N'-Diphenylthioureas
56(1)
5.13 1,3-Bis-(4-amino-3-mercapto-1,2,4-triazol-5-yl) Mercaptoethane (AMTME)
57(1)
5.14 4-Hydroxybenzaldehyde Thiosemicarbazone (HBTS)
57(1)
5.15 Benzildithiosemicarbazone
57(1)
5.16 4-(2-Thiazolylazo)-5-diethylaminobenzene (TDEAB)
58(1)
5.17 Nicotinaldehyde-4-phenyl-3-thiosemicarbazone (NPS)
58(1)
5.18 2-Mercapto-4-methyl-5-phenylazopyrimidine
58(1)
5.19 MN'-Dipyridylthiourea (DPyT)
59(1)
5.20 1-Phenyl-3-(3-ethyl-5-mercapto-l,2,4-triazol-4-yl)thiourea
59(1)
5.21 Isonitrosopropionylthiophene
59(1)
5.22 Pyridopyridazine Dithione (PDP)
60(1)
5.23 Pyridoxal-4-phenyl-3-thiosemicarbazone (PPT)
60(1)
5.24 3-Thiophenaldehyde-4-phenyl-3-thiosemicarbazone (TAPS)
60(1)
5.25 2-Mercaptonicotinic Acid (MENA)
61(1)
5.26 5-Bromosalicylaldehyde-4-phenyl-3-thiosemicarbazone (BSPS)
61(1)
5.27 2-N-(2-Mercaptophenyl)-1,2,3-benzothiadiazoline (MBDT)
61(1)
5.28 p-Methylphenyl Thiourea (PMPT)
62(3)
References
62(3)
Chapter 6 Miscellaneous Reagents for Spectrophotometric Determination of Pd(II) Having N/O/S or Other Donor Atoms
65(30)
6.1 Methylene Blue B (MBB)
65(1)
6.2 Cefixime
65(1)
6.3 Naphthol Green B
66(1)
6.4 2-(5-Bromo-2-oxoindolin-3-ylidene) Hydrazine Carbothioamide, [ 5-Bromoisatin Thiosemicarbazone] (HBITSC)
66(1)
6.5 o-Methoxyphenyl-thiourea (OMePT)
67(1)
6.6 Sodium Salt of Hexamethylene Diaminecarbodithioate (NaHMICdt.2H2O)
67(1)
6.7 4-Amino-3-mercapto-6-methyl-1,2,4-triazine (4H)-5-one -- a N, S and O Donor Triazine
67(1)
6.8 Thioglycolic Acid
68(1)
6.9 Thiomichler's Ketone (TMK)
68(1)
6.10 Rubeanic Acid
68(1)
6.11 2,6,7-Trihydroxy-9-(3,5-dibromo-4-hydroxy) Phenylfluorone (DBHPF)
69(1)
6.12 p-Dimethylaminobenzylidene Rhodanine in Methyl Isobutylketone
69(1)
6.13 5-(5-Nitro-2-hydroxyphenylazo) Rhodanine (OP)
69(1)
6.14 N-Cetyl-N'-(sodium p-aminobenzene Sulfonate) Thiourea (OPT)
69(1)
6.15 Anion Exchange Separation of Pd and Spectrophotometric Determination
70(1)
6.16 p-[ 4-(3,5-Dimethylisoxazolyl)azophenylazo]calix (4) Arene
70(1)
6.17 3-Hydroxy-2-methyl-1-phenyl-4-pyridone
70(1)
6.18 3-Phenoxy Benzaldoxime
71(1)
6.19 1-(2-Pyridylazo)-2-naphtholate
71(1)
6.20 Optical Test Strip for Spectrophotometric Determination of Palladium Using 5-(p-Dimethylaminobenzylidene) Rhodanine
71(1)
6.21 Piperonal Thiosemicarbazone
72(1)
6.22 2-(2-Quinolinylazo)-5-diethylaminoaniline (QADEAA)
72(1)
6.23 Novel Salen Ligand
72(1)
6.24 2-Methyl-5-(4-carboxyphenylazo)-8-hydroxyquinoline
73(1)
6.25 Phthalaldehyde Acid Thiosemicarbazone (PAATSC)
73(1)
6.26 Flow Injection Analysis and Spectrophotometric Determination of Palladium
73(1)
6.27 2-Aminoacetophenone Isonicotinoylhydrazone (2-AAINH)
74(1)
6.28 Crystal Violet with Hypophosphite
74(1)
6.29 O-Methylphenylthiourea
74(1)
6.30 Diacetylmonoxime-(p-anisyl)-thiosemicarbazone
75(1)
6.31 2-Hydroxy-3-methoxybenzaldehyde Thiosemicarbazone (HMBATSC)
75(1)
6.32 Hexylbenzimidazolylsulfide (HBMS)
75(1)
6.33 p-Sulfobenzylidene-Rhodanine
76(1)
6.34 3,5-Dimethoxy-4-hydroxybenzaldehydeisonicotinoylhydrazone
76(1)
6.35 1,3-Bis(hydroxymethyl)benzimidazole-2-thione
76(1)
6.36 2,6-Diacetylpyridine bis-4-phenyl-3-thiosemicarbazone (2,6-DAPBPTSC)
77(1)
6.37 2-Hydrazinopyridine
77(1)
6.38 4-(5-Chloro-2-pyridine)-azo-l,3-diaminobenzene
77(1)
6.39 Bromosulfonazo III
78(1)
6.40 2-(3,5-Dichloro-pyrdylazo)-5-dimethylaminoaniline (3,5-diCl-PADMA)
78(1)
6.41 3-Hydroxy-3-propyl-1-(4-carbamidosulfamoyl)phenyltriazene (CSPT)
78(1)
6.42 Ion Floatation Spectrophotometric Determination
78(1)
6.43 2-(2-Quinolinoylazo)-1,3-diaminobenzene (QADAB)
79(1)
6.44 p-Sulfobenzylidinerhodanine (SBDR)
79(1)
6.45 5-Iodo-[ calix(4)arene]aminoquinoline (ICAQ)
79(1)
6.46 2,4-Dichlorophenylfluorone (DCIPF)
79(1)
6.47 2-(5-Carboxy-1,3,4-triazolylazo)-5-diethylaminoaniline (CTZAN)
80(1)
6.48 4-(2-Pyridylazo) Resorcinol and 1-(2-Pyridylazo)-2-naphthol
80(1)
6.49 2-Hydroxy-3-nitroso-5-methyl Acetophenone Oxime (HNMA)
80(1)
6.50 4-(2-Thiazolylazo)-5-diethylamine-aminobenzene
81(1)
6.51 Nanocatalytic Spectrophotometric Determination of Palladium (II) Using NiCl2- NaH2PO4 System
81(1)
6.52 p-Iodochlorophosphonazo-Tween-60
81(1)
6.53 Solid-Phase Transmission Spectrophotometric Determination of Palladium
82(1)
6.54 4-Hydroxy-1-Naphthalrhodanine (HNR)
82(1)
6.55 2-(2-Quinolinylazo)-5-dimethylaminobenzoic Acid (QADMAB)
82(1)
6.56 2-(p-Carboxyphenylazo)benzothiazole
83(1)
6.57 2-(2-Quinolylazo)-5-Diethylaminobenzoic Acid (QADEAB)
83(1)
6.58 4-(5-Chloro-2-pyridyl)-azo-1,3-diaminobenzene
83(1)
6.59 N-Decylpyridine-4-amine
84(1)
6.60 2-(5-Carboxy-1,3,4-triazolyl-azo)-5-diethylaminobenzoic Acid (CTZDBA)
84(1)
6.61 1-(2'-Benzothiazole)-3-(4'-carboxybenzene)triazene (BTCBT)
84(1)
6.62 Tween 80-(NH4)2SO4-PAR System
85(1)
6.63 1-(2-Pyridylazo)-2-naphthol (PAN)
85(1)
6.64 (p-Methoxyphenyl)ethane-1,2-Dione-1-Oxime
85(1)
6.65 4-(N'-4-Imino-2-oxo-thiazolidine-5-ylidene)-hydrazinobenzoic Acid (p-ITYBA)
86(1)
6.66 Simultaneous Injection Effective Mixing Flow Analysis System of Palladium Determination Spectrophotometrically
86(1)
6.67 N-Amyl-N'-(sodium p-aminobenzenesulfonate)thiourea (APT)
86(1)
6.68 p-Dimethylaminobenzaldehyde-(p-anisyl)-thiosemicarbazone (DBATSC) and Glyoxal (p-anisyl)-thio Semicarbazone (GATSC)
87(1)
6.69 Food Additive Dye (Yellow-6)
87(1)
6.70 2-Acetylthiopyran Thiocyanate (l-Thiopyran-2-yl)ethanone Thiocyanate (ATPT)
87(8)
References
88(7)
Section B Spectrophotometric Determination of Platinum -- Reagents and Methods
Chapter 7 Spectrophotometric Determination Methods for Platinum
95(11)
7.1 Carbon-Polyurethane Powder
95(1)
7.2 Leucoxylene Cyanol FF
96(1)
7.3 1-3-Dimethyl-2-Thiourea and Bromocresol Green
96(1)
7.4 Astrafloxin FF
96(1)
7.5 Piperonal Thiosemicarbazone
97(1)
7.6 4-[ N,N-(Diethyl)amino]benzaldehyde Thiosemicarbazone (DEABT)
97(1)
7.7 N-(3,5-Dimethylphenyl)-N'-(4-Aminobenzenesulfonate) thiourea (DMMPT)
98(1)
7.8 1-Phenyl-4-Ethylthiosemicarbazide (PETS)
98(1)
7.9 Phenanthrenequinonemonosemicarbazone (PQSC)
98(1)
7.10 Anthranilic Acid
99(1)
7.11 Flow Injection Analysis Spectrophotometric Determination of Platinum
99(1)
7.12 Isonitroso p-Methyl Acetophenone Phenylhydrazone (HIMAPH)
99(1)
7.13 Potassium Bromate and 2-(4-Chloro-2-phosphonophenyl)azo-7-(2,4,6-trichlorophenyl) Azo-1,8-dihydroxy-3,6-naphthalene Disulfonic Acid
100(1)
7.14 1-(2-Pyridylazo)-2-naphthol
100(1)
7.15 2-(5-Bromo-2-oxoindolin-3-ylidene)hydrazine Carbothioamide (HBITSC)
100(1)
7.16 o-Methylphenylthiourea and Iodide
101(1)
7.17 o-Aminobenzylidenerhodanine
101(1)
7.18 Microwave Digestion and Spectrophotometric Determination of Platinum
101(1)
7.19 2-Hydroxy-1-naphthalrhodanine
102(1)
7.20 p-Sulfobenzylidenerhodanine (SBDR)
102(1)
7.21 5-(H)-Acidazorhodanine
102(1)
7.22 5-(2-Hydroxy-4-sulfo-5-chlorophenol-1-azo)thiorhodanine (HSCT)
102(1)
7.23 2-Hydroxy-5-sulfobenzenediazoaminoazobenzene (HSDAA)
103(1)
7.24 Tetrabromofluorescein and Rhodamine 6G
103(1)
7.25 2-(5Todine-2-pyridylazo)-5-dimethylaminoaniline (5-I-PADMA)
103(1)
7.26 Polyamide Resin
103(1)
7.27 3,4-Diaminobenzoic Acid
104(1)
7.28 2-(p-Carboxyphenylazo)benzothiazole (CPABT)
104(1)
7.29 4/5-Dibromo-2-nitrophenylfluorone
104(1)
7.30 N-(3,5-Dihydroxyphenyl)-N'-(4-Aminobenzenesulfonate) thiourea
105(1)
7.31 5-(5-Iodo-2-pyridylazo)-2,4-diaminotoluene (5-I-PADAT)
105(1)
7.32 p-Rhodanineazobenzoic Acid
105(1)
7.33 4-(2'-Furalideneimino)-3-methyl-5-mercapto-1,2,4-triazole in n-Butanol
106(1)
References 106(3)
Index 109
Prof. Ajay Kumar Goswami is an erudite scholar in the field of analytical chemistry and particularly analytical reagents and spectrophotometry. He has taught for thirty-five years, Co-ordination Chemistry and application of metal complexes to medicinal chemistry. He has an experience of more than thirty-five years both in India and abroad. He has published more than 150 research papers in journals of impact and has a list of 30 Ph.D. students to his credit. He has been a UGC BSR Faculty Fellow and has contributed various academic and administrative position of the University. He has published more than 10 books on various topics of graduate and post-graduate curriculum and has recently published three books from renowned publishers as CRC, De-Gruyter to name a few. He is an extremely knowledgeable professor, writer, and researcher.