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Statistical Dynamics: A Stochastic Approach To Nonequilibrium Thermodynamics (2nd Edition) 2nd Revised ed. [Kõva köide]

(King's College London, Uk)
  • Formaat: Hardback, 392 pages
  • Ilmumisaeg: 03-Apr-2009
  • Kirjastus: Imperial College Press
  • ISBN-10: 1848162448
  • ISBN-13: 9781848162440
Teised raamatud teemal:
  • Formaat: Hardback, 392 pages
  • Ilmumisaeg: 03-Apr-2009
  • Kirjastus: Imperial College Press
  • ISBN-10: 1848162448
  • ISBN-13: 9781848162440
Teised raamatud teemal:
How can one construct dynamical systems obeying the first and second laws of thermodynamics: mean energy is conserved and entropy increases with time? This book answers the question for classical probability (Part I) and quantum probability (Part II). A novel feature is the introduction of heat particles which supply thermal noise and represent the kinetic energy of the molecules. When applied to chemical reactions, the theory leads to the usual nonlinear reaction-diffusion equations as well as modifications of them. These can exhibit oscillations, or can converge to equilibrium.In this second edition, the text is simplified in parts and the bibliography has been expanded. The main difference is the addition of two new chapters; in the first, classical fluid dynamics is introduced. A lattice model is developed, which in the continuum limit gives us the Euler equations. The five Navier-Stokes equations are also presented, modified by a diffusion term in the continuity equation. The second addition is in the last chapter, which now includes estimation theory, both classical and quantum, using information geometry.
Preface v
Classical Statistical Dynamics 1
1. Introduction
3
2. Probability Theory
13
2.1 Sample Spaces and States
13
2.2 Random Variables, Algebras
24
2.3 Entropy
34
2.4 Exercises
39
3. Linear Dynamics
43
3.1 Reversible Dynamics
43
3.2 Random Dynamics
48
3.3 Convergence to Equilibrium
60
3.4 Markov Chains
66
3.5 Exercises
69
4. Isolated Dynamics
73
4.1 The Boltzmann Map
73
4.2 The Heat-Particle
87
4.3 The Hard-Core Model of Chemical Kinetics
94
4.3.1 Isomers and Diffusion in a Force-Field
95
4.3.2 Markov Dynamics
100
4.3.3 Entropy Production
102
4.3.4 Osmosis
103
4.3.5 Exchange Diffusion
104
4.3.6 General Diffusions
105
4.4 Chemical Reactions
106
4.4.1 Unimolecular Reactions
106
4.4.2 Balanced Reactions
107
4.5 Energy of Solvation
111
4.6 Activity-led Reactions
111
4.7 Exercises
119
5. Isothermal Dynamics
123
5.1 Legendre Transforms
124
5.2 The Free-energy Theorem
126
5.3 Chemical Kinetics
130
5.4 Convergence in Norm
137
5.5 Dilation of Markov Chains
146
5.6 Exercises
149
6. Driven Systems
151
6.1 Sources and Sinks
151
6.2 A Poor Conductor
152
6.3 A Driven Chemical System
155
6.4 How to Add Noise
162
6.5 Exercises
165
7. Fluid Dynamics
167
7.1 Hydrostatics of a Gas of Hard Spheres
168
7.2 The Fundamental Equation
171
7.3 The Euler Equations
177
7.4 Entropy Production
178
7.5 A Correct Navier-Stokes System
181
Quantum Statistical Dynamics 187
8. Introduction to Quantum Theory
189
9. Quantum Probability
197
9.1 Algebras of Observables
197
9.2 States
204
9.3 Quantum Entropy
213
9.4 Exercises
217
10. Linear Quantum Dynamics
221
10.1 Reversible Dynamics
221
10.2 Random Quantum Dynamics
224
10.3 Quantum Dynamical Maps
228
10.4 Exercises
236
11. Isolated Quantum Dynamics
237
11.1 The Quantum Boltzmann Map
237
11.2 The Quantum Heat-Particle
240
11.3 Fermions and Ions with a Hard Core
256
11.4 The Quantum Boltzmann Equation
272
11.5 Exercises
281
12. Isothermal and Driven Systems
283
12.1 Isothermal Quantum Dynamics
283
12.2 Convergence to Equilibrium
289
12.3 Driven Quantum Systems
292
12.4 Exercises
296
13. Infinite Systems
297
13.1 The Algebra of an Infinite System
299
13.2 The Reversible Dynamics
300
13.3 Return to Equilibrium
302
13.4 Irreversible Linear Dynamics
306
13.5 Exercises
309
14. Proof of the Second Law
311
14.1 von Neumann Entropy
311
14.2 Entropy Increase in Quantum Mechanics
312
14.3 The Quantum Kac Model
314
14.4 Equilibrium
315
14.5 The e-Limit
316
14.6 The Marginals and Entropy
316
14.7 The Results
317
15. Information Geometry
319
15.1 The Jaynes-Ingarden Theory
319
15.2 Non-Linear Ising Dynamics
322
15.3 Ising Model Close to Equilibrium
327
15.4 Non-linear Heisenberg Model
329
15.5 Estimation; the Cramer-Rao Inequality
333
15.6 Efron, Dawid and Amari
337
15.7 Entropy Methods, Exponential Families
340
15.8 The Work of Pistone and Sempi
341
15.9 The Finite-Dimensional Quantum Info-Manifold
346
15.10 Araki's Expansionals and the Analytic Manifold
352
15.11 The Quantum Young Function
354
15.12 The Quantum Cramer Class
359
15.13 The Parameter-Free Quantum Manifold
360
15.14 Exercises
364
Bibliography 367
Index 377