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Surface Active Behaviour of Performance Surfactants [Kõva köide]

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  • Formaat: Hardback, 218 pages, kõrgus x laius x paksus: 242x163x20 mm, kaal: 567 g
  • Ilmumisaeg: 01-Oct-2000
  • Kirjastus: Wiley-Blackwell
  • ISBN-10: 1841271195
  • ISBN-13: 9781841271194
  • Formaat: Hardback, 218 pages, kõrgus x laius x paksus: 242x163x20 mm, kaal: 567 g
  • Ilmumisaeg: 01-Oct-2000
  • Kirjastus: Wiley-Blackwell
  • ISBN-10: 1841271195
  • ISBN-13: 9781841271194
Volume 3 of Annual Surfactants Review focuses on the diversity of surfactants, both in terms of chemical structure and physico-chemical / surface active properties. These properties may be predictable for simple molecules, but for most commercial surfactants (which may be regarded as multi-component blends) this is not so easy. In the first chapter of this volume, detailed consideration is given to surfactant applications in the context of structure-performance relationships. The end uses of surface active agents are classified by industrial sector and the surfactant properties required for each application are presented in detail. The result is a unique guide to the influence of chemical structure on performance in end use. Many applications of surfactants feature formulations which incorporate polymeric materials. The topic of surfactant-polymer interactions is receiving considerable attention at present and so a chapter has been included on this area.

In an attempt to illustrate the diversity of surfactant uses and focus on some of the latest developments in application technology, five areas of application are presented: natural surfactants for drug delivery systems, surfactants used in the construction industry, preparation and end uses of inverse emulsions (for example, as flocculants), the use of surfactants in plastics flotation (part of the plastics recycling process) and the role of surfactants in 'dynamic wetting'.

Arvustused

"A fine book with excellent information presented in a pleasant form. I recommend it for purchase as both a 'technology update' book and as a 'reference' book" - Journal of Surfactants and Detergents

Surfactant applications in the context of structure-performance relationships 1(65) Guido Bognolo Introduction 1(5) Applications for surfactants 6(1) Structure-performance relationships 7(4) General considerations 7(1) Status and trends 8(3) Industrial applications 11(39) Building and construction 12(1) Cosmetics and personal care 13(8) Crop protection 21(5) Emulsion polymerisation 26(3) Food 29(2) Inks, paints and coatings 31(3) Metalworking fluids 34(2) Mining Chemicals 36(1) Oilfield chemicals and petroleum additives 37(3) Pharmaceuticals 40(3) Pulp and paper 43(3) Textiles 46(4) Effect surfactants 50(16) Acetylenic surfactants 50(2) Fluorosurfactants 52(1) Polymeric surfactants 53(6) Silicone surfactants 59(2) Acknowledgments 61(1) References 61(5) Surfactants in inverse (water-in-oil) emulsion polymers of acrylamide 66(31) James N. Greenshields Introduction 66(1) Process 67(1) Mechanism and Kinetics of polymerization 68(7) Emulsifiers 75(11) Primary Emulsifiers 75(8) Secondary, or inverting. emulsifiers 83(3) The mechanism of inversion 86(5) Commercial uses 91(6) References 94(3) Interactions between polymers and surfactants 97(32) Ian D. Robb Introduction 97(1) Nonionic polymers and nonionic surfactants 98(1) Nonionic polymers and ionic surfactants 99(2) Polymers and surfactants of opposite charge 101(10) Anionic polymers with cationic surfactants 101(10) Concentrated systems 111(2) Absorption at surfaces 113(7) Air-liquid interfaces 113(3) Solid-liquid interfaces 116(4) Polymers with hydrophobic side-groups 120(3) Polymer type 120(2) Surfactant type 122(1) Solid-state properties of polymer-surfactant complexes 123(2) Complexes in organic solvents 125(1) Summary 125(4) References 125(4) Use of Surfactants in plastic flotation 129(26) Marcello Ghiani Paolo Bevilacqua Introduction 129(1) Wetting and contact angle 129(5) Measuring the contact angle 132(2) Main characteristics of plastics in relation to flotation 134(2) Molecular structure 134(1) Free Surface energy 134(2) Surface polarity 136(1) Wetting mechanisms of plastic surfaces 136(2) Wetting through control of surface tension 136(2) Wetting through absorption 138(1) Wetting through surface modification 138(1) The theory of absorption 138(4) Electrical effects at interfaces 142(3) Flotation surfactants 145(3) Ionizable surfactants 145(1) Nonionic surfactants 146(2) Wetting of plastics with use of surfactants 148(7) References 153(2) Surface-active agents in the construction industry 155(14) Tatsuya Mizunuma Akifumi Yamada Introduction 155(1) Concrete and surfactants 156(1) Workability 156(1) Strength 156(1) Durability 156(1) History of chemical admixtures 157(1) Types of chemical admixture 158(5) Air-entraining agents 158(1) Water-reducing agents and high-range water-reducing agents 159(4) Applications 163(1) New concrete with air-entraining-type high-range water reducing agents 163(4) Types of air-entraining-type high-range water-reducing agent 165(1) Mechanism of maintaining fluidity over a long period 165(2) Applications 167(1) Summary 167(2) References 168(1) The role of surfactants in dynamic wetting 169(20) Michel J. De Ruijter Introduction 169(1) Dynamic wetting 170(6) Hydrodynamic models 171(2) Molecular-kinetic model 173(2) Combined model 175(1) Microhydrodynamic model 175(1) Equilibrium wetting and surfactants 176(2) Dynamic wetting and surfactants 178(3) Performance surfactants and dynamic wetting 181(1) Impacting drops 182(1) Monolayer and multilayer spreading 183(2) Conclusions 185(4) References 185(4) Interfacial properties of natural surfactants and their application in drug delivery systems 189(13) Hitoshi Yamauchi Introduction 189(1) Interfacial phenomena of some natural surfactants at the oil-water interface 189(2) Behavior of lipids at the oil-water interface 189(2) Molecular interactions between natural surfactants and liqid bilayers 191(4) Molecular interactions between lipids and some steroids in monolayers and bilayers 192(2) Molecular interactions between phospholipid and lipophilic substances in a lipid bilayer 194(1) Molecular interactions between lipids and glycolipids in a bilayer 195(1) Application of liposomes in drug delivery systems 195(4) Selective uptake of liposomes containing lactose monofatty-acid derivatives by hepatic parenchymal cells 196(1) Effect of sialic-acid derivatives on circulation time and tumor concentration of liposomes 197(2) Conclusions 199(3) Acknowledgments 200(1) References 200(2) Index 202