Introduction |
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xix | |
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Section I Advanced Oxidation Processes |
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1 | (170) |
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1 Advanced Oxidation Processes: Fundamental, Technologies, Applications and Recent Advances |
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3 | (24) |
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4 | (1) |
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1.2 Background and Global Trend of Advanced Oxidation Process |
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5 | (3) |
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1.3 Advanced Oxidation Systems |
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8 | (7) |
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9 | (1) |
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10 | (1) |
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10 | (2) |
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12 | (1) |
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13 | (1) |
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1.3.6 Electrochemical Oxidation |
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14 | (1) |
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1.4 Comparison and Challenges of AOP Technologies |
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15 | (4) |
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1.5 Conclusion and Perspective |
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19 | (8) |
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20 | (7) |
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2 A Historical Approach for Integration of Cavitation Technology with Conventional Wastewater Treatment Processes |
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27 | (30) |
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2.1 Introduction to Cavitation for Wastewater Treatment |
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28 | (2) |
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2.1.1 Mechanistic Aspects of Ultrasound Cavitation |
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28 | (1) |
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2.1.2 Mechanistic Aspects of Hydrodynamic Cavitation |
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29 | (1) |
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2.2 Importance of Integrating Water Treatment Technology in Present Scenario |
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30 | (1) |
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2.3 Integration Ultrasound Cavitation (UC) with Conventional Treatment Techniques |
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31 | (9) |
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2.3.1 Sonosorption (UC+ Adsorption) |
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32 | (6) |
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2.3.2 Son-Chemical Oxidation (UC + Chemical Oxidation) |
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38 | (1) |
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39 | (1) |
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2.4 Integration of Hydrodynamic Cavitation (HC) with Conventional Treatment Techniques |
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40 | (10) |
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2.4.1 Hydrodynamic Cavitation + Adsorption |
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40 | (2) |
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2.4.2 Hydrodynamic Cavitation + Biological Oxidation |
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42 | (1) |
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2.4.3 Hydrodynamic Cavitation + Chemical Treatment |
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43 | (7) |
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2.5 Scale-Up Issues with Ultrasound Cavitation Process |
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50 | (1) |
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2.6 Conclusion and Future Perspectives: Hydrodynamic Cavitation as a Future Technology |
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50 | (7) |
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51 | (1) |
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51 | (6) |
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3 Hydrodynamic Cavitation: Route to Greener Technology for Wastewater Treatment |
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57 | (60) |
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58 | (14) |
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3.2 Cavitation: General Perspective |
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72 | (16) |
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72 | (1) |
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3.2.2 Types of Cavitation |
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73 | (1) |
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3.2.3 Hydrodynamic Cavitation |
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74 | (6) |
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3.2.4 Bubble Dynamics Model |
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80 | (1) |
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3.2.4.1 Rayleigh-Plesset Equation |
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80 | (1) |
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80 | (4) |
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3.2.4.3 Nonequilibrium Effects |
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84 | (1) |
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3.2.5 Physio-Chemical Effects |
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84 | (1) |
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3.2.5.1 Thermodynamic Effects |
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85 | (1) |
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3.2.5.2 Mechanical Effects |
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86 | (1) |
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87 | (1) |
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3.2.5.4 Biological Effects |
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88 | (1) |
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3.3 Hydrodynamic Cavitation Reactors |
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88 | (6) |
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3.3.1 Liquid Whistle Reactors |
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89 | (1) |
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3.3.2 High-Speed Homogenizers |
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89 | (1) |
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90 | (1) |
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3.3.4 High-Pressure Homogenizers |
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90 | (1) |
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3.3.5 Orifice Plates Setup |
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91 | (1) |
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3.3.5.1 Effect of the Ratio of Total Perimeter to Total Flow Area |
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92 | (1) |
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3.3.5.2 Effect of Flow Area to the Cross-Sectional Area of the Pipe |
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92 | (1) |
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3.3.6 Venture Device Setup |
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92 | (1) |
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3.3.6.1 Effect of Divergence Angle |
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93 | (1) |
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3.3.6.2 Effect of the Ratio of Throat Diameter/Height to Length |
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94 | (1) |
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3.3.7 Vortex-Based HC Reactor |
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94 | (1) |
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3.4 Effect of Operating Parameters of HC |
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94 | (3) |
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3.4.1 Effect of Inlet Pressure |
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94 | (1) |
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3.4.2 Effect of Temperature |
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95 | (1) |
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3.4.3 Effect of Initial Concentration of Pollutant |
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96 | (1) |
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3.4.4 Effect of Treatment Time |
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96 | (1) |
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97 | (1) |
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97 | (3) |
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3.6 Techno-Economic Feasibility |
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100 | (1) |
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101 | (1) |
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3.8 Conclusions and Thoughts About the Future |
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102 | (1) |
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103 | (1) |
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103 | (14) |
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103 | (2) |
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105 | (12) |
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4 Recent Trends in Ozonation Technology: Theory and Application |
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117 | (54) |
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118 | (1) |
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4.2 Fundamentals of Mass Transfer |
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119 | (6) |
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4.3 Mass Transfer of Ozone in Water |
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125 | (22) |
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4.3.1 Solubility of Ozone in Water |
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126 | (1) |
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4.3.1.1 Model for Determining the True Solubility Concentration |
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126 | (2) |
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4.3.2 Mass Transfer Model of Ozone in Water |
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128 | (5) |
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4.3.3 Henry and Volumetric Mass Transfer Coefficient Determination |
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133 | (1) |
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4.3.3.1 Microscopic Ozone Balance in the Gas Phase |
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134 | (1) |
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4.3.3.2 Macroscopic Ozone Balance in the Gas Phase |
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134 | (2) |
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4.3.3.3 Ozone Balance at Constant Ozone Concentrations |
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136 | (1) |
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4.3.4 Single Bubble Model of Mass Transfer |
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137 | (7) |
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4.3.5 Decomposition of Ozone in Water |
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144 | (2) |
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4.3.6 Ozone Contactors and Energy Requirement |
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146 | (1) |
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4.4 Factors Affecting Hydrodynamics and Mass Transfer in Bubble Column Reactor |
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147 | (3) |
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4.4.1 Fluid Dynamics and Regime Analysis |
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148 | (1) |
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149 | (1) |
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4.4.3 Bubble Characteristics |
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149 | (1) |
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4.4.4 Mass Transfer Coefficient |
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150 | (1) |
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150 | (8) |
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4.6 Conclusion and Thoughts About the Future |
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158 | (13) |
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158 | (1) |
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158 | (3) |
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161 | (10) |
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Section II Nanoparticle-Based Treatment |
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171 | (100) |
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5 Nanoparticles and Nanocomposite Materials for Water Treatment: Application in Fixed Bed Column Filter |
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173 | (72) |
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174 | (4) |
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5.2 Target Contaminants: Performance of Nanoparticles and Nanocomposite Materials |
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178 | (48) |
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5.2.1 Inorganic Contaminants |
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178 | (1) |
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178 | (17) |
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5.2.1.2 Nonmetallic Contaminant |
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195 | (2) |
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5.2.2 Organic Contaminant |
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197 | (1) |
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197 | (5) |
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5.2.2.2 Halogenated Hydrocarbons |
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202 | (1) |
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5.2.2.3 Polycyclic Aromatic Hydrocarbon (PAH) |
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203 | (18) |
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5.2.2.4 Miscellaneous Aromatic Pollutant |
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221 | (1) |
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5.2.3 Emerging Contaminants |
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222 | (1) |
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5.2.3.1 Pharmaceuticals and Personal Care Products |
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222 | (3) |
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5.2.3.2 Miscellaneous Compounds |
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225 | (1) |
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5.3 Application of Nanoparticles and Nanocomposite Materials in Fixed Bed Column Filter for Water Treatment |
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226 | (19) |
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5.3.1 Fate and Transport Process of Contaminants in the Fixed Bed Column Filter |
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226 | (2) |
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5.3.2 Application of Nanoparticles and Nanocomposite Materials in Fixed Bed Column Filter |
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228 | (3) |
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231 | (14) |
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6 Nanomaterials for Wastewater Treatment: Potential and Barriers in Industrialization |
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245 | (26) |
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245 | (3) |
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6.2 Nanomaterials in Wastewater Treatment |
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248 | (5) |
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6.2.1 Nanotechnological Processes for Wastewater Treatment |
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249 | (1) |
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249 | (1) |
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249 | (1) |
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249 | (1) |
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250 | (1) |
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6.2.2 Different Nanomaterials for Wastewater Treatment |
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250 | (1) |
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6.2.2.1 Zerovalent Metal Nanoparticles |
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250 | (1) |
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6.2.2.2 Metal Oxide Nanoparticles |
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251 | (1) |
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6.2.2.3 Other Nanoparticles |
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252 | (1) |
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6.3 Smart Nanomaterials: Molecularly Imprinted Polymers (MIP) |
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253 | (4) |
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6.3.1 Molecularly Imprinted Polymers (MIP) |
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253 | (1) |
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6.3.2 Application of MIP-Based Nanomaterials in Wastewater Treatment |
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254 | (1) |
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6.3.2.1 Recognition of Pollutants |
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254 | (1) |
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6.3.2.2 Removal of Pollutants |
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255 | (1) |
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6.3.2.3 Catalytic Degradation of Organic Molecules |
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256 | (1) |
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6.3.3 Barriers in Industrialization |
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257 | (1) |
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6.4 Cheap Alternative Nanomaterials |
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257 | (4) |
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6.4.1 Nanoclay for Wastewater Treatment |
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258 | (1) |
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6.4.1.1 Water Filtration by Nanoclays |
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258 | (1) |
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6.4.1.2 Water Treatment by Hybrid Gel |
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258 | (1) |
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259 | (1) |
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6.4.2 Nanocellulose for Wastewater Treatment |
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259 | (1) |
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6.4.2.1 Adsorption of Heavy Metals by Nanocellulose |
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260 | (1) |
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6.4.2.2 Adsorption of Dyes by Nanocellulose |
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260 | (1) |
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6.4.2.3 Barriers in Industrialization |
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260 | (1) |
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6.5 Toxicity Associated with Nanotechnology in Wastewater Treatment |
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261 | (1) |
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6.6 Barriers in Industrialization |
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262 | (1) |
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6.7 Future Aspect and Conclusions |
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263 | (8) |
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264 | (7) |
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Section III Membrane-Based Treatment |
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271 | (144) |
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7 Microbial Fuel Cell Technology for Wastewater Treatment |
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273 | (52) |
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274 | (2) |
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276 | (10) |
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276 | (3) |
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7.2.2 Role of MFC Components |
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279 | (1) |
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7.2.3 Performance Indicator of MFC |
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280 | (2) |
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282 | (1) |
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7.2.5 Types of Microbial Fuel Cell |
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283 | (3) |
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7.3 Recent Development in MFC Component |
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286 | (12) |
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7.3.1 Recent Development in Cathode Used in MFC |
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286 | (5) |
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7.3.2 Recent Development in Anode Used in MFC |
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291 | (4) |
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7.3.3 Recent Developments in Membranes Used in MFC |
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295 | (3) |
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7.4 MFC for Wastewater Treatment |
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298 | (3) |
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7.4.1 Advantages of MFC Over Conventional Treatment |
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299 | (1) |
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7.4.2 Challenges in the Wastewater Treatment Using MFC |
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300 | (1) |
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7.5 Different Ways for Increasing the Throughput of MFC |
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301 | (5) |
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301 | (1) |
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302 | (1) |
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303 | (1) |
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303 | (1) |
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7.5.5 Separating Material |
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304 | (1) |
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7.5.6 Harnessing Output Energy |
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304 | (1) |
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7.5.7 Increasing Long-Term Stability |
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305 | (1) |
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7.5.8 Coupling of MFC with Other Techniques |
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305 | (1) |
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7.6 Different Case Studies Indicating Commercial Use of MFC |
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306 | (4) |
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7.7 Other Applications of MFC |
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310 | (1) |
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7.8 Conclusions and Recommendations (Future Work) |
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311 | (14) |
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313 | (12) |
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8 Ceramic Membranes in Water Treatment: Potential and Challenges for Technology Development |
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325 | (58) |
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326 | (22) |
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8.1.1 Background and Current State-of-the-Art |
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326 | (1) |
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8.1.2 Ceramic Membranes: An Approach to Trade-Off the Bridge Between Theoretical Research and Industrial Applications |
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327 | (2) |
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8.1.3 Industrial Wastewater Treatment |
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329 | (12) |
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8.1.4 Domestic Wastewater Treatment |
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341 | (7) |
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8.2 Treatment of Contaminated Groundwater and Drinking Water |
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348 | (9) |
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8.2.1 Arsenic Contaminated Water |
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348 | (2) |
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8.2.2 Treatment of Fluoride Contaminated Water |
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350 | (1) |
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8.2.3 Treatment of Nitrate Contaminated Water |
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351 | (1) |
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8.2.4 Treatment of Water Spiked with Emerging Contaminants |
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352 | (2) |
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8.2.5 Treatment of Water Contaminated with Pathogens |
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354 | (3) |
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8.3 Classification of Filtration Based on Configuration |
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357 | (11) |
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8.3.1 Direct Membrane Filtration |
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357 | (3) |
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360 | (8) |
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368 | (1) |
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8.5 Challenges of Ceramic Membranes |
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369 | (1) |
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8.6 Conclusion and Future Scope of Ceramic Membranes |
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370 | (13) |
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371 | (12) |
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9 Membrane Distillation for Acidic Wastewater Treatment |
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383 | (18) |
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383 | (1) |
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9.2 Membrane Distillation and Its Configurations |
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384 | (1) |
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9.3 Sources of Acidic Effluent |
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385 | (2) |
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9.4 Applications of MD for Acidic Wastewater Treatment |
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387 | (1) |
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388 | (7) |
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395 | (6) |
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395 | (6) |
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10 Demonstration of Long-Term Assessment on Performance of VMD for Textile Wastewater Treatment |
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401 | (14) |
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401 | (2) |
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403 | (2) |
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10.3 Impact of Process Variables on Permeate Flux |
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405 | (3) |
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10.4 Long-Term Performance Analysis of VMD |
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408 | (3) |
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10.5 Scale Formation in Long-Term Assessment |
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411 | (4) |
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412 | (1) |
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412 | (1) |
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413 | (1) |
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413 | (2) |
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Section IV Emerging Technologies & Processes |
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415 | (228) |
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11 Application of Zero Valent Iron to Removal Chromium and Other Heavy Metals in Metallurgical Wastewater |
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417 | (24) |
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418 | (5) |
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11.1.1 Wastewater Sources from Metallurgical Factories |
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418 | (1) |
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11.1.2 Characteristics of Wastewater in Metallurgical Factories |
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419 | (1) |
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11.1.3 Conventional Technologies for Treating Wastewater in Metallurgical Factories |
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420 | (2) |
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11.1.4 Zero Valent Iron for Removing Heavy Metals |
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422 | (1) |
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11.1.5 Objectives of the Study |
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422 | (1) |
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11.2 Materials and Methods |
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423 | (5) |
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11.2.1 Metallurgical Wastewater |
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423 | (1) |
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11.2.2 Preparation of Zero Valent Iron |
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424 | (1) |
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424 | (1) |
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425 | (3) |
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11.3 Results and Discussion |
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428 | (7) |
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11.3.1 Effects of pH on Hexavalent Chromium Removal |
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428 | (2) |
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11.3.2 Effects of Fe° on Hexavalent Chromium Removal |
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430 | (1) |
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11.3.3 Effects of Contact Time on Hexavalent Chromium Removal |
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431 | (1) |
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11.3.4 Effects of pH on Heavy Metals Removal |
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432 | (1) |
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11.3.5 Effects of PAC on Heavy Metals Removal |
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433 | (1) |
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11.3.6 Effects of PAM on Heavy Metals Removal |
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434 | (1) |
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435 | (6) |
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436 | (1) |
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436 | (5) |
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12 Removal of Arsenic and Fluoride from Water Using Novel Technologies |
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441 | (46) |
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12.1 Background Study of Arsenic |
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442 | (3) |
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12.1.1 Source and Existence of Arsenic |
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442 | (1) |
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12.1.2 Effects of Arsenic |
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443 | (1) |
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12.1.3 Regulation and Permissible Limit of Arsenic in Drinking Water |
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444 | (1) |
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12.2 Background Study of Fluoride |
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445 | (2) |
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12.2.1 Source and Existence of Fluoride |
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445 | (1) |
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12.2.2 Effects of Fluoride |
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445 | (1) |
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12.2.3 Regulation and Permissible Limit of Fluoride in Drinking Water |
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446 | (1) |
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12.3 Technologies Used for Arsenic Removal from Contaminated Groundwater |
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447 | (9) |
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447 | (3) |
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12.3.2 Coagulation-Precipitation Method |
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450 | (1) |
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12.3.3 Ion-Exchange Method |
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450 | (1) |
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451 | (5) |
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12.4 Technologies for Fluoride Removal from Contaminated Groundwater |
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456 | (4) |
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12.4.1 Coagulation-Precipitation Method |
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456 | (1) |
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12.4.2 Nalgonda Technique |
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456 | (2) |
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458 | (1) |
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12.4.4 Ion-Exchange Method |
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458 | (2) |
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12.5 Membrane Technology Used for Arsenic and Fluoride Mitigations |
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460 | (27) |
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12.5.1 Introduction of Membrane Technology |
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460 | (2) |
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12.5.2 Arsenic Removal by Membrane Filtration |
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462 | (1) |
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12.5.2.1 Arsenic Removal by Microfiltration System |
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462 | (2) |
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12.5.2.2 Arsenic Removal by Ultrafiltration System |
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464 | (2) |
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12.5.2.3 Arsenic Removal by Nanofiltration System |
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466 | (6) |
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12.5.2.4 Arsenic Removal by Other Membrane-Based Process |
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472 | (3) |
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12.5.3 Fluoride Removal by Different Membrane Filtration System |
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475 | (5) |
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480 | (7) |
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13 A Zero Liquid Discharge Strategy with MSF Coupled with Crystallizer |
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487 | (30) |
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488 | (2) |
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13.2 Minimum Energy Required for Desalination Process |
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490 | (4) |
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13.2.1 Minimum Work Requirement |
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492 | (2) |
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494 | (1) |
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13.3 Methodology and Simulation |
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494 | (10) |
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13.3.1 MSF Process Description |
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494 | (1) |
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13.3.2 Crystallizer Process Description |
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495 | (1) |
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13.3.3 Modeling and Simulation |
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496 | (5) |
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501 | (3) |
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13.4 Results and Discussion |
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504 | (7) |
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13.4.1 Comparison of Energy Demand Between Simulated Model and Theoretical Model |
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504 | (3) |
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13.4.2 Impact of Temperature and Flowrate on Thermal Energy |
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507 | (1) |
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13.4.3 Impact on Thermal Energy During MLD and ZLD |
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507 | (4) |
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13.4.4 Crystallization of Salts |
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511 | (1) |
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511 | (1) |
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512 | (5) |
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512 | (5) |
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14 A Critical Review on Prospects and Challenges in "Conceptualization to Technology Transfer" for Nutrient Recovery from Municipal Wastewater |
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517 | (50) |
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518 | (2) |
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14.2 Chemical Processes for Resources Recovery |
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520 | (8) |
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14.2.1 Chemical Precipitation |
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521 | (1) |
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14.2.1.1 Magnesium and Calcium-Phosphorous Precipitation |
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521 | (1) |
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14.2.1.2 Aluminum - Phosphorous Precipitation |
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522 | (1) |
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14.2.1.3 Ferric - Phosphorous Precipitation |
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523 | (1) |
|
14.2.2 Adsorption and Ion-Exchange |
|
|
524 | (4) |
|
14.3 Biological Processes for Resources Recovery |
|
|
528 | (6) |
|
14.3.1 Anammox Process for Nutrients Recovery |
|
|
529 | (1) |
|
14.3.2 Algal Methods for Sewage Treatment and Nutrient Recovery |
|
|
530 | (1) |
|
14.3.2.1 Nutrients Recovery from Micro-Algae Growth |
|
|
530 | (3) |
|
14.3.2.2 Nutrients Recovery from Wetland Plants Growth |
|
|
533 | (1) |
|
14.4 Membrane-Based Hybrid Technologies for Nutrients, Energy, and Water Recovery |
|
|
534 | (17) |
|
14.4.1 Membrane Based Nutrients Recovery |
|
|
534 | (3) |
|
14.4.2 Bio Electrochemical Systems (BES) for Resources Recovery |
|
|
537 | (7) |
|
14.4.3 Nutrients Recovery via Osmotic Membrane Bioreactor |
|
|
544 | (1) |
|
14.4.4 Economics and Feasibility of Processes |
|
|
545 | (6) |
|
|
551 | (16) |
|
|
551 | (1) |
|
|
551 | (1) |
|
|
551 | (16) |
|
15 Sustainable Desalination: Future Scope in Indian Subcontinent |
|
|
567 | (24) |
|
|
|
|
|
567 | (1) |
|
15.2 Water Supply and Demand in India |
|
|
568 | (3) |
|
15.3 Current Status of Desalination in India |
|
|
571 | (1) |
|
15.4 Commercially Available Technologies |
|
|
572 | (4) |
|
15.4.1 Reverse Osmosis (RO) |
|
|
572 | (1) |
|
15.4.2 Electrodialysis (ED) |
|
|
573 | (1) |
|
15.4.3 Membrane Capacitive Deionization (MCDI) |
|
|
574 | (1) |
|
15.4.4 Thermal Desalination |
|
|
574 | (2) |
|
15.5 Possible Technological Intervention |
|
|
576 | (7) |
|
15.5.1 Solar Desalination |
|
|
576 | (1) |
|
|
577 | (2) |
|
15.5.1.2 Photovoltaic (PV) Powered Desalination in India |
|
|
579 | (1) |
|
15.5.2 Wave Power Desalination |
|
|
580 | (1) |
|
15.5.3 Geothermal Desalination |
|
|
580 | (1) |
|
15.5.4 Low-Temperature Thermal Desalination (LTTD) |
|
|
580 | (1) |
|
15.5.5 Membrane Distillation (MD) |
|
|
581 | (1) |
|
15.5.6 Forward Osmosis (FO) |
|
|
582 | (1) |
|
15.6 Challenges and Implementation Strategies for Sustainable Use of Desalination Technologies |
|
|
583 | (8) |
|
|
584 | (7) |
|
16 Desalination: Thermodynamic Modeling and Energetics |
|
|
591 | (52) |
|
|
|
|
|
|
|
|
592 | (1) |
|
16.2 Thermodynamics Modeling of Desalination |
|
|
593 | (6) |
|
16.2.1 Electrolyte Solutions |
|
|
594 | (2) |
|
16.2.2 Generalized Minimum Work of Separation |
|
|
596 | (1) |
|
|
597 | (1) |
|
|
598 | (1) |
|
16.3 Modeling of Major Thermal Desalination Techniques |
|
|
599 | (16) |
|
16.3.1 A General Multi-Effect Distillation (MED) Process Configuration for Desalination |
|
|
601 | (1) |
|
16.3.1.1 Steady State Process Model of a MED System |
|
|
601 | (5) |
|
16.3.1.2 Performance Parameters Analysis |
|
|
606 | (1) |
|
16.3.2 A General Process Configuration of Multi-Stage Flash (MSF) Desalination |
|
|
607 | (1) |
|
16.3.2.1 Steady State Process Model of an MSF System |
|
|
608 | (4) |
|
16.3.3 A General Process Configuration of Mechanical Vapor Compression (MVC) Desalination |
|
|
612 | (1) |
|
16.3.3.1 Steady State Process Model of an MVC System |
|
|
613 | (2) |
|
16.4 Advantage of RO Above Other Mentioned Technologies |
|
|
615 | (8) |
|
16.4.1 Advantages of RO Process |
|
|
616 | (1) |
|
16.4.2 Energy Requirement in Desalination by an Evaporation Technique |
|
|
617 | (1) |
|
16.4.3 Energy Requirements for Desalination by Reversible RO Process |
|
|
617 | (2) |
|
16.4.4 Energy Analysis of Different Desalination Techniques |
|
|
619 | (1) |
|
16.4.5 Economic Analysis of Different Desalination Techniques |
|
|
620 | (3) |
|
16.5 Exergy Analysis of Reverse Osmosis |
|
|
623 | (8) |
|
16.5.1 General Exergy Analysis in Desalination and Its Necessity |
|
|
625 | (3) |
|
16.5.1.1 Exergy Efficiency and Its Improvement Potential Analysis |
|
|
628 | (2) |
|
16.5.2 A Case Study on Reverse Osmosis Based Desalination Unit Reporting Exergy Performance |
|
|
630 | (1) |
|
|
631 | (12) |
|
|
632 | (4) |
|
|
636 | (7) |
Index |
|
643 | |