| Preface |
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Chapter 1 Generalities and Fundamental Laws |
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1 | (7) |
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1.2 Zeroth law of thermodynamics |
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8 | (3) |
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1.3 First law of thermodynamics |
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11 | (14) |
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1.4 State functions and process-dependent entities |
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25 | (3) |
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1.5 Second law of thermodynamics |
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28 | (27) |
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1.6 Third law of thermodynamics |
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55 | (2) |
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1.7 Extension to other forms of energy transfer |
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57 | (7) |
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1.8 Equations derived from the Gibbs equation |
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64 | (3) |
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1.9 Partial state functions |
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67 | (3) |
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1.10 The Gibbs-Duhem relation |
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70 | (1) |
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1.11 Thermodynamic (or absolute) temperature and empirical temperature |
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71 | (8) |
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Chapter 2 Closed Systems and General Thermodynamic Relations |
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2.1 Fundamental equations for a closed and homogeneous system |
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79 | (1) |
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80 | (1) |
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2.3 Thermodynamic processes and diagrams |
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81 | (2) |
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2.4 Thermal and calorific factors |
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83 | (2) |
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85 | (2) |
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2.6 Mathematical Relations between the state functions, the different factors and the specific heats |
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87 | (8) |
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2.7 Extension to the evolution of heterogeneous closed systems and the notion of thermodynamic equilibrium |
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95 | (8) |
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Chapter 3 Balance of Extensive Properties |
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3.1 Spatial and substancial balance of a scalar extensive property |
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103 | (6) |
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3.2 Spatial and substantial balance of an extensive vector entity |
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109 | (2) |
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111 | (2) |
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113 | (8) |
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121 | (4) |
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125 | (1) |
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3.7 Balance of the moment of Momentum |
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126 | (3) |
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Chapter 4 Open systems, In steady State Operation |
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4.1 Fundamental equations of an open system, in steady state operation |
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129 | (16) |
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4.2 Static and dynamic state properties (functions) |
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145 | (6) |
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4.3 Plane propagation of perturbations of small amplitude |
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151 | (6) |
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4.4 Flow in a channel of constant cross section |
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157 | (13) |
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4.5 Adiabatic flow in a nozzle |
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170 | (13) |
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4.6 Flow in a throttled channel |
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183 | (5) |
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4.7 Non-adiabatic flow in a fixed channel |
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188 | (8) |
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4.8 Turbine and compressor |
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196 | (21) |
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Chapter 5 Thermodynamic Properties of Matter |
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5.1 Description of the various states of matter |
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217 | (9) |
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5.2 Perfect gases. Kinetic gas theory |
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226 | (8) |
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234 | (2) |
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5.4 General properties of perfect and ideal gases |
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236 | (8) |
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244 | (15) |
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259 | (1) |
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5.7 Synthesis of cubic equations of state |
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260 | (2) |
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5.8 Equation of Lee Kesler modified from the equation of Benedict-Webb-Rubin (BWR) |
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262 | (1) |
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263 | (1) |
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5.10 Real bodies of matter |
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264 | (8) |
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5.11 Clausius-Clapeyron equation |
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272 | (4) |
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5.12 Specific heats of solids |
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276 | (3) |
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5.13 Approximate relations for solids and liquids |
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279 | (1) |
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5.14 Appendix: example of water as a real fluid |
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280 | (9) |
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Chapter 6 Mixture of Perfect or Ideal Gases |
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289 | (1) |
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6.2 Pressures, volumes and entropies of mixture: Dalton's and Amagat's laws |
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290 | (8) |
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6.3 Internal energies, enthalpies, temperatures, gas constants and specific heats of mixture |
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298 | (3) |
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6.4 Mixtures with differing initial conditions |
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301 | (4) |
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305 | (4) |
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Chapter 7 Mixtures of a Gas and a Condensable Substance |
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309 | (8) |
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317 | (7) |
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7.3 Mixture of two mixtures, at steady-state operation |
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324 | (3) |
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7.4 Heating or cooling of any arbitrary mixture |
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327 | (1) |
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7.5 Introduction of a liquid in a dry mixture |
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327 | (6) |
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7.6 Application of the notion of limit temperature |
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333 | (2) |
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335 | (1) |
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7.8 Solids and dry mixtures |
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336 | (1) |
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7.9 Example of application |
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337 | (4) |
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Chapter 8 Thermodynamic Processes and Diagrams |
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8.1 Typical thermodynamic processes |
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341 | (9) |
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350 | (1) |
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8.3 Thermodynamic diagrams |
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351 | (23) |
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8.4 Paraisothermal process |
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374 | (7) |
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Chapter 9 Simple Examples of Application of the First and Second Laws |
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9.1 Transformation of mechanical energy into internal energy (Joule's experiment) |
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381 | (2) |
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9.2 Expansion without work (Gay-Lussac-Joule experiment) |
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383 | (2) |
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385 | (2) |
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387 | (4) |
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9.5 Evolution of a heterogeneous system |
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391 | (1) |
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9.6 Heat transfer between two bodies |
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392 | (2) |
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9.7 Heat transmitter (heat exchanger) |
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394 | (3) |
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9.8 Compression of a perfect gas mixture |
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397 | (2) |
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Chapter 10 Energy and Exergy Analyses (Thermomechanical Processes) |
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399 | (7) |
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406 | (43) |
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10.3 Heating by mechanical or electrical energy |
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449 | (7) |
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10.4 Heating and cooling by heat transfer |
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456 | (5) |
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10.5 Heating or cooling by transformation energy |
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461 | (13) |
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474 | (5) |
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479 | (6) |
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485 | (5) |
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10.9 Synthesis of the energy and exergy approaches |
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490 | (1) |
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Chapter 11 Energy and Exergy Analyses (With Reactive Processes) |
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491 | (1) |
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11.2 Basic chemical equations |
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492 | (3) |
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495 | (7) |
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11.4 Energy (heating) values of afuel |
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502 | (16) |
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11.5 Energy balances and combustion temperature |
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518 | (15) |
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11.6 Exergy values of a fuel |
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533 | (17) |
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11.7 Incomplete combustion |
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550 | (11) |
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11.8 Thermodynamic properties of combustion gases |
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561 | (5) |
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11.9 Evolution of a combustion process |
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566 | (4) |
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570 | (7) |
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11.11 Synthesis of the energy and exergy approaches with reactive processes |
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577 | (2) |
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Chapter 12 Application Examples of
Chapters 10 and 11 |
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579 | (6) |
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585 | (13) |
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12.3 Internal combustion engine |
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598 | (9) |
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Chapter 13 Thermodynamic Cycles |
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607 | (1) |
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13.2 General features of cycles |
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608 | (3) |
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13.3 Single thermal source cycles |
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611 | (6) |
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617 | (3) |
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13.5 Bithermal power cycles |
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620 | (19) |
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13.6 Bithermal heat pump cycles |
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639 | (17) |
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13.7 Synthesis of bithermal cycles |
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656 | (11) |
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Chapter 14 Application Examples of
Chapters 10 Through 13 |
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667 | (29) |
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14.2 Gas cycles power plants |
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696 | (17) |
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14.3 Advanced power plants |
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713 | (6) |
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719 | (24) |
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Chapter 15 Linear Thermodynamics of Irreversible Phenomena |
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15.1 Phenomenological approach |
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743 | (2) |
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15.2 Reciprocal Onsager and Casimir relation |
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745 | (3) |
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15.3 Prigogine's principle |
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748 | (2) |
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15.4 Thermoelectrical effects |
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750 | (8) |
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15.5 Particular thermoelectrical effects |
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758 | (7) |
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15.6 Applications of thermoelectric effects |
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765 | (8) |
| Bibliography |
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773 | (6) |
| Nomenclature |
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779 | (8) |
| Index |
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787 | |
