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Third Generation Solar Cells [Kõva köide]

(Lublin University of Technology, Poland)
  • Formaat: Hardback, 150 pages, kõrgus x laius: 246x174 mm, kaal: 430 g, 8 Tables, black and white; 48 Line drawings, black and white; 12 Halftones, black and white; 60 Illustrations, black and white
  • Ilmumisaeg: 20-Jan-2023
  • Kirjastus: Routledge
  • ISBN-10: 1032052554
  • ISBN-13: 9781032052557
  • Formaat: Hardback, 150 pages, kõrgus x laius: 246x174 mm, kaal: 430 g, 8 Tables, black and white; 48 Line drawings, black and white; 12 Halftones, black and white; 60 Illustrations, black and white
  • Ilmumisaeg: 20-Jan-2023
  • Kirjastus: Routledge
  • ISBN-10: 1032052554
  • ISBN-13: 9781032052557
This book presents the principle of operation, materials used and possible applications of third generation solar cells that are under investigation and have been not commercialized on a large scale yet. The third generation photovoltaic devices include promising emerging technologies such as: organic, dye sensitized, perovskite and quantum dot sensitized photocells. This book introduces the reader to the basics of third generation photovoltaics and presents in an accessible way phenomena and a diversity of materials used. In this book one will find the description of the working principle of new promising solar technologies, their advantages and disadvantages, prospect applications and preliminary analysis of their impact on the environment. The fundamentals of traditional solar cell operation are also included in the book facilitating understanding of new ideas.

This book is ideal reading for everyone who is interested in novel solutions in photovoltaics as well as applications of nanotechnology, photochemistry and materials research.
Preface ix
Author xi
1 Fundamentals of Photovoltaics
1(25)
1.1 Introduction
1(1)
1.2 Solar cell: the principle of operation
1(5)
1.3 Crystalline silicon solar cells of the first generation
6(6)
1.3.1 The structure of crystalline silicon solar cells
7(1)
1.3.2 Light absorption
8(1)
1.3.3 Recombination of carriers
9(1)
1.3.4 The impact of external conditions on the performance of the solar cell
9(2)
1.3.5 Recent progress in silicon cells
11(1)
1.4 Thin-film photovoltaic technologies of the second generation
12(10)
1.4.1 CdS/CdTe cell
14(2)
1.4.2 CIGS solar cell
16(1)
1.4.3 Silicon thin-film solar cell
17(4)
1.4.4 GaAs solar cell
21(1)
1.5 Summary
22(4)
2 Organic Solar Cells
26(21)
2.1 Introduction
26(1)
2.2 Organic semiconductors
26(1)
2.3 Device architecture and performance
27(10)
2.3.1 Single-layer organic photocell
28(1)
2.3.2 Binary organic photocell
28(1)
2.3.3 Bulk heterojunction organic photocell
29(5)
2.3.4 Inverted structure of organic photocell
34(2)
2.3.5 Ternary blends
36(1)
2.4 Light trapping
37(3)
2.5 Stability
40(1)
2.6 Summary
41(6)
3 Dye-sensitized Solar Cells
47(22)
3.1 Introduction
47(1)
3.2 Structure and basics of DSSC operation
47(6)
3.2.1 Work cycle of DSSC
50(2)
3.2.2 Inverted configuration of DSSC
52(1)
3.3 Review of materials used in DSSC
53(10)
3.3.1 Mesoporous semiconductor layer
53(3)
3.3.2 Sensitizers
56(3)
3.3.3 Counter electrode
59(1)
3.3.4 Electrolytes
60(3)
3.4 Summary
63(6)
4 Perovskite Solar Cells
69(33)
4.1 Introduction
69(1)
4.2 Brief history of perovskite photocells
69(2)
4.3 Operation of perovskite solar cells
71(11)
4.3.1 General characteristics of perovskite materials
71(5)
4.3.2 Solar cells based on organic-inorganic and all-inorganic perovskites
76(6)
4.4 Architecture of perovskite cells
82(6)
4.4.1 ETL
83(2)
4.4.2 HTL
85(2)
4.4.3 ETL-free and HTL-free perovskite photocells
87(1)
4.5 Hysteresis
88(2)
4.6 Stability
90(4)
4.6.1 Thermal stability
90(1)
4.6.2 Illumination
91(1)
4.6.3 Moisture and oxygen
92(1)
4.6.4 The methods of stability improvement
92(2)
4.7 Lead-free perovskite cells
94(1)
4.8 Summary
95(7)
5 Quantum Dot-sensitized Solar Cells
102(17)
5.1 Introduction
102(1)
5.2 Structure and operation principle of quantum dot-sensitized solar cells
102(2)
5.3 Quantum dots as sensitizers
104(5)
5.3.1 Doped quantum dots
105(1)
5.3.2 Alloy dots
106(1)
5.3.3 Core-shell structure
106(2)
5.3.4 Co-sensitization
108(1)
5.4 Multiple exciton generation
109(1)
5.5 Sensitization process - deposition of quantum dots
110(3)
5.5.1 In situ deposition
110(1)
5.5.2 Ex situ deposition
111(2)
5.6 Other components of QDSSC
113(2)
5.6.1 Electron transport layer
113(1)
5.6.2 Electrolyte
114(1)
5.6.3 Counter electrode
115(1)
5.7 Summary
115(4)
6 Environmental Impact of Emerging Photovoltaics
119(18)
6.1 Introduction
119(1)
6.2 Life cycle assessment of photovoltaic technologies
119(2)
6.3 The end-of-life treatment of photovoltaic modules
121(2)
6.4 Application of life cycle assessment to emerging photovoltaic technologies
123(11)
6.4.1 Life cycle assessment of organic photovoltaic cells
123(4)
6.4.2 Life cycle assessment of dye-sensitized photovoltaic cells
127(3)
6.4.3 Life cycle assessment of perovskite photovoltaic cells
130(3)
6.4.4 Life cycle assessment of quantum dot-sensitized photovoltaic cells
133(1)
6.5 Summary
134(3)
7 Applications of Emerging Photovoltaics - Future Outlook
137(12)
7.1 Introduction
137(1)
7.2 Organic photocells
138(1)
7.3 Dye-sensitized photocells
139(1)
7.4 Perovskite photocells
140(1)
7.5 Quantum dot-sensitized photocells
141(1)
7.6 Indoor applications of emerging photovoltaics
141(1)
7.7 Tandem photocells
142(2)
7.8 Summary
144(5)
Index 149
Agata Zdyb holds the position of Associate Professor at Lublin University of Technology, Poland and she is the head of the Department of Renewable Energy Engineering. She graduated in physics in 1993 from the Faculty of Mathematics, Physics, and Chemistry of University of Maria Curie Sklodowska in Lublin then received her PhD in 2002 from Gdansk University of Technology in Poland. She completed the habilitation in 2012 at AGH University of Science and Technology in Cracow, thesis title: "The research on the improvement of dye-sensitized solar cells efficiency".

Agata Zdyb is author or co-author of over 50 peer-reviewed articles and 5 patent applications. She participated in 5 scientific projects, currently she is the member of Reviewer Board for Applied Sciences MDPI journal (IF 2.47) and guest editor for the special issue of Sustainability MDPI journal (IF 2.57). Agata Zdyb was the reviewer of 38 scientific publications. Her scientific topics of interest are: thin film solar cells, dye-sensitized solar cells (DSSC), emerging photovoltaics, nanotechnology for applications in solar cells, photovoltaic systems, renewable energy sources.