Muutke küpsiste eelistusi

Analytical Chemistry of Uranium: Environmental, Forensic, Nuclear, and Toxicological Applications [Kõva köide]

  • Formaat: Hardback, 324 pages, kõrgus x laius: 234x156 mm, kaal: 760 g, 34 Tables, black and white; 99 Illustrations, black and white
  • Ilmumisaeg: 21-Nov-2014
  • Kirjastus: CRC Press Inc
  • ISBN-10: 148222058X
  • ISBN-13: 9781482220582
  • Formaat: Hardback, 324 pages, kõrgus x laius: 234x156 mm, kaal: 760 g, 34 Tables, black and white; 99 Illustrations, black and white
  • Ilmumisaeg: 21-Nov-2014
  • Kirjastus: CRC Press Inc
  • ISBN-10: 148222058X
  • ISBN-13: 9781482220582
Karpas presents this applied chemistry handbook for detecting and analyzing uranium. The first of five chapters covers the basic properties of uranium and its common compounds, outlines the processes employed to use it for nuclear fuel, and describes the basis of analytical techniques used to characterize it, including atomic absorption and emission spectroscopy, X-ray fluorescence spectrometry, neutron activation analysis, gamma spectroscopy, electron microscopy, mass spectrometry, alpha spectrometry, and miscellaneous spectroscopic and ion counting techniques. The remaining four chapters treat uranium analysis in specific contexts: characterization of uranium ores, fuel, alloys, and waste in industry; detection of uranium in environmental samples; monitoring of exposure and toxicity by analysis of body tissues or fluids, and trace analysis for nuclear forensics. Chapters present the preferred analytical instrumentation and methodology for each application along with rationale and discussion of supporting studies. Annotation ©2015 Ringgold, Inc., Portland, OR (protoview.com)

Accurate uranium analysis, and particularly for isotope measurements, is essential in many fields, including environmental studies, geology, hydrogeology, the nuclear industry, health physics, and homeland security. Nevertheless, only a few scientific books are dedicated to uranium in general and analytical chemistry aspects in particular.Analytical Chemistry of Uranium: Environmental, Forensic, Nuclear, and Toxicological Applicationscovers the fascinating advances in the field of analytical chemistry of uranium.

Exploring a broad range of topics, the book focuses on the analytical aspects of industrial processes that involve uranium, its presence in the environment, health and biological implications of exposure to uranium compounds, and nuclear forensics.

Topics include:

  • Examples of procedures used to characterize uranium in environmental samples of soil, sediments, vegetation, water, and air
  • Analytical methods used to examine the rigorous specifications of uranium and its compounds deployed in the nuclear fuel cycle
  • Health aspects of exposure to uranium and the bioassays used for exposure assessment
  • Up-to-date analytical techniques used in nuclear forensics for safeguards in support of non-proliferation, including single particle characterization

Each chapter includes an overview of the topic and several examples to demonstrate the analytical procedures. This is followed by sample preparation, separation and purification techniques where necessary. The book supplies readers with a solid understanding of the analytical chemistry approach used today for characterizing the different facets of uranium, providing a good starting point for further investigation into this important element.

Preface ix
Acknowledgments xi
Acronyms xiii
Chapter 1 Introduction: Fundamental Properties of Uranium and Its Compounds, the Nuclear Fuel Cycle, and Analytical Methods Used for Characterizing Uranium 1(62)
1.1 Introduction
1(2)
1.2 Fundamentals of Uranium and Its Chemistry
3(22)
1.2.1 History and Properties of the Element
3(11)
1.2.1.1 Discovery and History
3(1)
1.2.1.2 Occurrence
4(1)
1.2.1.3 Physical Properties
4(1)
1.2.1.4 Nuclear Properties and Isotopes
5(4)
1.2.1.5 Radioactive Decay Chains
9(3)
1.2.1.6 Fission of U-235 by Neutrons
12(2)
1.2.1.7 Alloys
14(1)
1.2.1.8 Chemical Properties
14(1)
1.2.2 Mineralogy of Uranium
14(2)
1.2.3 Major Uranium Compounds
16(9)
1.2.3.1 Binary Oxides of Uranium
17(2)
1.2.3.2 Binary Fluorides of Uranium
19(4)
1.2.3.3 Oxyfluorides of Uranium
23(1)
1.2.3.4 Other Uranyl Compounds
23(2)
1.2.3.5 Other Uranium Compounds in the Nuclear Industry
25(1)
1.3 Uranium in the NFC
25(14)
1.3.1 Uranium Mining
27(1)
1.3.2 Uranium Milling
28(1)
1.3.3 Uranium Conversion Facility
29(2)
1.3.4 Isotope Enrichment
31(3)
1.3.5 Fabrication of Nuclear Fuel and Irradiation
34(1)
1.3.6 Treatment and Disposal of Irradiated Fuel
35(1)
1.3.7 Types of NFCs
36(1)
1.3.8 Reactor Fuel and Fuel Elements
37(2)
1.3.8.1 Reactor Types, Moderators, and Coolants
38(1)
1.3.8.2 Type of Fuel
39(1)
1.4 Modern Analytical Techniques in a Nutshell
39(21)
1.4.1 Photon Counting Techniques
41(10)
1.4.1.1 Atomic Absorption Spectrometry
41(2)
1.4.1.2 Atomic Emission Spectrometry or Optical Emission Spectrometry
43(2)
1.4.1.3 X-Ray Fluorescence Spectrometry
45(1)
1.4.1.4 Neutron Activation Analysis
45(2)
1.4.1.5 Gamma Spectrometry
47(2)
1.4.1.6 Electron Microscopy
49(1)
1.4.1.7 Other Spectroscopic Techniques
50(1)
1.4.2 Ion Counting Techniques
51(8)
1.4.2.1 Mass Spectrometry (MS)
51(5)
1.4.2.2 Alpha Spectrometry
56(2)
1.4.2.3 Other Ion Counting Techniques
58(1)
1.4.3 Generic Sample Preparation and Uranium Separation Techniques
59(1)
1.5 Summary
60(1)
References
60(3)
Chapter 2 Industrial Applications 63(56)
2.1 Industrial Considerations
63(5)
2.1.1 Introduction
63(3)
2.1.2 World Resources and Production of Uranium
66(2)
2.2 Analytical Chemistry of Uranium Ores
68(9)
2.2.1 Prospecting Methods
68(5)
2.2.1.1 Aerial and Ground-Level Gamma-Ray Surveys
69(2)
2.2.1.2 Geophysical Methods
71(1)
2.2.1.3 Other Prospecting Strategies
72(1)
2.2.2 Assay of Minerals and Uranium Ores
73(4)
2.3 Analytical Chemistry in the NFC
77(30)
2.3.1 Analytical Characterization of UF6 for Enrichment Facilities
80(7)
2.3.1.1 Sampling of Uranium Hexafluoride
80(3)
2.3.1.2 Isotopic Analysis of Uranium Hexafluoride
83(3)
2.3.1.3 Determination of Impurities in Uranium Hexafluoride
86(1)
2.3.2 Analytical Characterization of UO2 Fuel
87(6)
2.3.3 Analytical Characterization of Uranium and Uranium Alloys
93(1)
2.3.4 Analytical Characterization of Fuel Elements
94(1)
2.3.5 Analysis at the Back End of the NFC
95(8)
2.3.5.1 Characterizing SNF
97(6)
2.3.6 Reprocessing SNF
103(2)
2.3.7 Analysis of Waste in the NFC
105(2)
2.4 Depleted Uranium and Its Characterization
107(3)
2.5 Summary
110(1)
References
111(8)
Chapter 3 Determination of Uranium in Environmental Samples 119(48)
3.1 Introduction and General Overview
119(7)
3.1.1 Transport of Uranium in the Environment
120(2)
3.1.2 Analytical Procedures for the Determination of Uranium in Environmental Samples
122(3)
3.1.3 Analytical Methods for the Determination of Uranium
125(1)
3.2 Uranium Content in Soil
126(13)
3.2.1 Digestion and Sample Preparation
126(9)
3.2.2 Soil Sample Preparation for Methods That Do Not Require Extensive Treatment
135(4)
3.3 Uranium Content in Plants and Vegetation
139(5)
3.4 Soil-to-Plant Transfer Factors
144(3)
3.5 Uranium Content in Natural Freshwater Sources and Oceans
147(7)
3.5.1 Preconcentration of Uranium from Aqueous Samples
148(3)
3.5.2 Uranium in Ocean Water and Seawater
151(1)
3.5.3 Uranium in Surface Waters
152(2)
3.6 Uranium Content in Air and Other Environmental Samples
154(4)
3.7 Summary
158(3)
References
161(6)
Chapter 4 Exposure, Toxicity, and Biomonitoring of Uranium Exposure 167(70)
4.1 Introduction
167(1)
4.2 Exposure Pathways
167(21)
4.2.1 Sources of Environmental and Occupational Exposures
167(15)
4.2.1.1 Daily Intake of Uranium through Ingestion
168(6)
4.2.1.2 Daily Intake of Uranium through Inhalation
174(1)
4.2.1.3 Exposure to Uranium through Skin and Injury
175(2)
4.2.1.4 Analytical Methods for the Determination of Uranium in Drinking Water
177(2)
4.2.1.5 Analytical Methods for the Determination of Uranium in Food Products
179(3)
4.2.2 Distribution of Uranium in the Body (Biokinetic Models)
182(6)
4.3 Toxicity
188(9)
4.3.1 Toxicity of Uranium
188(4)
4.3.2 Chemical Toxicity
192(3)
4.3.3 Radiological Toxicity
195(1)
4.3.4 Other Health Effects
195(2)
4.4 Bioassays for Uranium Exposure
197(29)
4.4.1 Analytical Methods for the Determination of Uranium in Urine
201(11)
4.4.2 Urinalysis for Special Populations
212(4)
4.4.3 Blood and Feces Analysis
216(2)
4.4.4 Uranium Content Analysis in Hair and Nails
218(7)
4.4.5 Uranium Content Analysis in Other Bioassays
225(1)
4.5 Dose Assessment and Treatment of Exposed People
226(1)
4.6 Summary
227(1)
References
228(9)
Chapter 5 Trace Analysis and Nuclear Forensics 237(58)
5.1 Introduction
237(9)
5.1.1 Nuclear Forensics
237(3)
5.1.2 Adaptation of Analytical Techniques for Trace Analysis
240(2)
5.1.3 Thermal Ionization Mass Spectrometry
242(2)
5.1.4 Secondary Ion Mass Spectrometry
244(1)
5.1.5 Inductively Coupled Plasma Mass Spectrometry
245(1)
5.2 Nuclear Fingerprints
246(15)
5.2.1 Standards and Certified Reference Materials
248(1)
5.2.2 Fingerprinting of Uranium Ores
248(5)
5.2.3 Uranium Conversion Facilities and Enrichment Plants
253(1)
5.2.4 Fingerprinting Operations with UF6
253(5)
5.2.5 Nuclear Fuel Fabrication and Spent Fuel
258(2)
5.2.5.1 Uranium Oxide
258(2)
5.2.6 Postdetonation Fingerprints
260(1)
5.3 Bulk Analysis and Single Particle Analysis
261(13)
5.3.1 Bulk Analysis for Safeguards Purposes
261(2)
5.3.2 Single Particle Analysis
263(10)
5.3.3 Locating Uranium in Single Particles
273(1)
5.3.4 Characterization of Uranium in Single Particles
274(1)
5.4 Trace Analysis and Safeguards
274(10)
5.4.1 Principles of Age Determination
275(3)
5.4.2 Analytical Procedures Used for Uranium-Based Age Dating
278(6)
5.5 Nuclear Forensics
284(2)
5.5.1 Databases for Nuclear Forensic Investigations
284(1)
5.5.2 Case Studies
284(2)
5.6 Summary
286(3)
References
289(6)
Chapter 6 Summary 295(4)
Index 299
Dr. Zeev Karpas received his Ph. D. in 1976 (Weizmann Institute of Science, Rehovot, Israel). In 1978 he joined the Nuclear Research Centre, Negev (Beer-Sheva, Israel) from which he retired as a Senior Research Scientist in 2013. Dr. Karpas has research interests mainly in the toxicological and environmental applications of laser-ablation and ICPMS and in the technology and science of ion mobility spectrometry and is the co-author of three monographs on the subject.