| Preface |
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ix | |
| Acknowledgments |
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xi | |
| Acronyms |
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xiii | |
| Chapter 1 Introduction: Fundamental Properties of Uranium and Its Compounds, the Nuclear Fuel Cycle, and Analytical Methods Used for Characterizing Uranium |
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1 | (62) |
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1 | (2) |
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1.2 Fundamentals of Uranium and Its Chemistry |
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3 | (22) |
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1.2.1 History and Properties of the Element |
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3 | (11) |
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1.2.1.1 Discovery and History |
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3 | (1) |
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4 | (1) |
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1.2.1.3 Physical Properties |
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4 | (1) |
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1.2.1.4 Nuclear Properties and Isotopes |
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5 | (4) |
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1.2.1.5 Radioactive Decay Chains |
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9 | (3) |
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1.2.1.6 Fission of U-235 by Neutrons |
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12 | (2) |
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14 | (1) |
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1.2.1.8 Chemical Properties |
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14 | (1) |
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1.2.2 Mineralogy of Uranium |
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14 | (2) |
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1.2.3 Major Uranium Compounds |
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16 | (9) |
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1.2.3.1 Binary Oxides of Uranium |
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17 | (2) |
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1.2.3.2 Binary Fluorides of Uranium |
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19 | (4) |
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1.2.3.3 Oxyfluorides of Uranium |
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23 | (1) |
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1.2.3.4 Other Uranyl Compounds |
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23 | (2) |
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1.2.3.5 Other Uranium Compounds in the Nuclear Industry |
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25 | (1) |
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25 | (14) |
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27 | (1) |
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28 | (1) |
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1.3.3 Uranium Conversion Facility |
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29 | (2) |
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31 | (3) |
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1.3.5 Fabrication of Nuclear Fuel and Irradiation |
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34 | (1) |
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1.3.6 Treatment and Disposal of Irradiated Fuel |
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35 | (1) |
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36 | (1) |
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1.3.8 Reactor Fuel and Fuel Elements |
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37 | (2) |
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1.3.8.1 Reactor Types, Moderators, and Coolants |
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38 | (1) |
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39 | (1) |
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1.4 Modern Analytical Techniques in a Nutshell |
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39 | (21) |
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1.4.1 Photon Counting Techniques |
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41 | (10) |
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1.4.1.1 Atomic Absorption Spectrometry |
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41 | (2) |
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1.4.1.2 Atomic Emission Spectrometry or Optical Emission Spectrometry |
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43 | (2) |
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1.4.1.3 X-Ray Fluorescence Spectrometry |
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45 | (1) |
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1.4.1.4 Neutron Activation Analysis |
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45 | (2) |
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1.4.1.5 Gamma Spectrometry |
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47 | (2) |
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1.4.1.6 Electron Microscopy |
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49 | (1) |
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1.4.1.7 Other Spectroscopic Techniques |
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50 | (1) |
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1.4.2 Ion Counting Techniques |
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51 | (8) |
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1.4.2.1 Mass Spectrometry (MS) |
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51 | (5) |
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1.4.2.2 Alpha Spectrometry |
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56 | (2) |
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1.4.2.3 Other Ion Counting Techniques |
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58 | (1) |
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1.4.3 Generic Sample Preparation and Uranium Separation Techniques |
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59 | (1) |
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60 | (1) |
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60 | (3) |
| Chapter 2 Industrial Applications |
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63 | (56) |
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2.1 Industrial Considerations |
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63 | (5) |
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63 | (3) |
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2.1.2 World Resources and Production of Uranium |
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66 | (2) |
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2.2 Analytical Chemistry of Uranium Ores |
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68 | (9) |
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2.2.1 Prospecting Methods |
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68 | (5) |
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2.2.1.1 Aerial and Ground-Level Gamma-Ray Surveys |
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69 | (2) |
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2.2.1.2 Geophysical Methods |
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71 | (1) |
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2.2.1.3 Other Prospecting Strategies |
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72 | (1) |
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2.2.2 Assay of Minerals and Uranium Ores |
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73 | (4) |
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2.3 Analytical Chemistry in the NFC |
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77 | (30) |
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2.3.1 Analytical Characterization of UF6 for Enrichment Facilities |
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80 | (7) |
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2.3.1.1 Sampling of Uranium Hexafluoride |
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80 | (3) |
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2.3.1.2 Isotopic Analysis of Uranium Hexafluoride |
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83 | (3) |
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2.3.1.3 Determination of Impurities in Uranium Hexafluoride |
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86 | (1) |
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2.3.2 Analytical Characterization of UO2 Fuel |
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87 | (6) |
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2.3.3 Analytical Characterization of Uranium and Uranium Alloys |
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93 | (1) |
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2.3.4 Analytical Characterization of Fuel Elements |
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94 | (1) |
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2.3.5 Analysis at the Back End of the NFC |
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95 | (8) |
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2.3.5.1 Characterizing SNF |
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97 | (6) |
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103 | (2) |
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2.3.7 Analysis of Waste in the NFC |
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105 | (2) |
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2.4 Depleted Uranium and Its Characterization |
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107 | (3) |
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110 | (1) |
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111 | (8) |
| Chapter 3 Determination of Uranium in Environmental Samples |
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119 | (48) |
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3.1 Introduction and General Overview |
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119 | (7) |
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3.1.1 Transport of Uranium in the Environment |
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120 | (2) |
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3.1.2 Analytical Procedures for the Determination of Uranium in Environmental Samples |
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122 | (3) |
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3.1.3 Analytical Methods for the Determination of Uranium |
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125 | (1) |
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3.2 Uranium Content in Soil |
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126 | (13) |
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3.2.1 Digestion and Sample Preparation |
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126 | (9) |
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3.2.2 Soil Sample Preparation for Methods That Do Not Require Extensive Treatment |
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135 | (4) |
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3.3 Uranium Content in Plants and Vegetation |
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139 | (5) |
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3.4 Soil-to-Plant Transfer Factors |
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144 | (3) |
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3.5 Uranium Content in Natural Freshwater Sources and Oceans |
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147 | (7) |
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3.5.1 Preconcentration of Uranium from Aqueous Samples |
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148 | (3) |
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3.5.2 Uranium in Ocean Water and Seawater |
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151 | (1) |
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3.5.3 Uranium in Surface Waters |
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152 | (2) |
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3.6 Uranium Content in Air and Other Environmental Samples |
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154 | (4) |
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158 | (3) |
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161 | (6) |
| Chapter 4 Exposure, Toxicity, and Biomonitoring of Uranium Exposure |
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167 | (70) |
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167 | (1) |
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167 | (21) |
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4.2.1 Sources of Environmental and Occupational Exposures |
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167 | (15) |
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4.2.1.1 Daily Intake of Uranium through Ingestion |
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168 | (6) |
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4.2.1.2 Daily Intake of Uranium through Inhalation |
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174 | (1) |
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4.2.1.3 Exposure to Uranium through Skin and Injury |
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175 | (2) |
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4.2.1.4 Analytical Methods for the Determination of Uranium in Drinking Water |
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177 | (2) |
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4.2.1.5 Analytical Methods for the Determination of Uranium in Food Products |
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179 | (3) |
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4.2.2 Distribution of Uranium in the Body (Biokinetic Models) |
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182 | (6) |
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188 | (9) |
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4.3.1 Toxicity of Uranium |
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188 | (4) |
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192 | (3) |
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4.3.3 Radiological Toxicity |
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195 | (1) |
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4.3.4 Other Health Effects |
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195 | (2) |
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4.4 Bioassays for Uranium Exposure |
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197 | (29) |
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4.4.1 Analytical Methods for the Determination of Uranium in Urine |
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201 | (11) |
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4.4.2 Urinalysis for Special Populations |
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212 | (4) |
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4.4.3 Blood and Feces Analysis |
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216 | (2) |
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4.4.4 Uranium Content Analysis in Hair and Nails |
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218 | (7) |
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4.4.5 Uranium Content Analysis in Other Bioassays |
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225 | (1) |
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4.5 Dose Assessment and Treatment of Exposed People |
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226 | (1) |
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227 | (1) |
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228 | (9) |
| Chapter 5 Trace Analysis and Nuclear Forensics |
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237 | (58) |
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237 | (9) |
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237 | (3) |
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5.1.2 Adaptation of Analytical Techniques for Trace Analysis |
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240 | (2) |
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5.1.3 Thermal Ionization Mass Spectrometry |
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242 | (2) |
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5.1.4 Secondary Ion Mass Spectrometry |
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244 | (1) |
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5.1.5 Inductively Coupled Plasma Mass Spectrometry |
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245 | (1) |
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246 | (15) |
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5.2.1 Standards and Certified Reference Materials |
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248 | (1) |
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5.2.2 Fingerprinting of Uranium Ores |
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248 | (5) |
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5.2.3 Uranium Conversion Facilities and Enrichment Plants |
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253 | (1) |
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5.2.4 Fingerprinting Operations with UF6 |
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253 | (5) |
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5.2.5 Nuclear Fuel Fabrication and Spent Fuel |
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258 | (2) |
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258 | (2) |
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5.2.6 Postdetonation Fingerprints |
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260 | (1) |
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5.3 Bulk Analysis and Single Particle Analysis |
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261 | (13) |
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5.3.1 Bulk Analysis for Safeguards Purposes |
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261 | (2) |
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5.3.2 Single Particle Analysis |
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263 | (10) |
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5.3.3 Locating Uranium in Single Particles |
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273 | (1) |
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5.3.4 Characterization of Uranium in Single Particles |
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274 | (1) |
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5.4 Trace Analysis and Safeguards |
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274 | (10) |
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5.4.1 Principles of Age Determination |
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275 | (3) |
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5.4.2 Analytical Procedures Used for Uranium-Based Age Dating |
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278 | (6) |
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284 | (2) |
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5.5.1 Databases for Nuclear Forensic Investigations |
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284 | (1) |
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284 | (2) |
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286 | (3) |
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289 | (6) |
| Chapter 6 Summary |
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295 | (4) |
| Index |
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299 | |