Preface |
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xix | |
1 Composites from Natural Fibers and Bio-resins |
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1 | (26) |
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2 | (1) |
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1.2 Lignocellulosic Fibers |
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2 | (8) |
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1.2.1 Chemical Treatment of Banana Fiber |
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6 | (4) |
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10 | (4) |
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12 | (1) |
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1.3.1.1 Physical and chemical properties of BS bio-resin |
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13 | (1) |
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14 | (3) |
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1.5 Biodegradability of Hybrid Biocomposites |
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17 | (1) |
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18 | (9) |
2 Advancements and Potential Prospects of Polymer/Metal Oxide Nanocomposites: From Laboratory Synthesis to Commercialization |
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27 | (38) |
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28 | (2) |
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2.2 Different Approaches for Nanocomposite Synthesis |
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30 | (5) |
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30 | (1) |
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31 | (2) |
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33 | (1) |
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2.2.4 Solution Intercalation |
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33 | (1) |
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34 | (1) |
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35 | (1) |
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2.3 Polymer-Based Metal Oxide Nanocomposites |
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35 | (8) |
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2.3.1 Polymer-Iron Oxide-Based Nanocomposites |
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36 | (2) |
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2.3.2 Polymer-Zinc Oxide-Based Nanocomposites |
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38 | (2) |
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2.3.3 Polymer-Silica-Based Nanocomposites |
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40 | (2) |
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2.3.4 Polymer-Titanium Oxide-Based Nanocomposites |
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42 | (1) |
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2.4 Role of Metal Oxide Nanoparticles in Enhancing the Properties of Nanocomposites |
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43 | (2) |
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2.5 Applications of Nanocomposites |
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45 | (9) |
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45 | (3) |
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48 | (1) |
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49 | (2) |
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51 | (1) |
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52 | (2) |
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2.6 Commercial Opportunities for Metal Oxide/Polymer Nanocomposites |
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54 | (1) |
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2.7 Conclusion and Future Prospects |
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55 | (10) |
3 Biomedical Insights of Lipid-and Protein-Based Biocomposites |
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65 | (32) |
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66 | (1) |
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3.2 Protein-Based Biocomposites |
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67 | (11) |
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3.2.1 Medical Applications of Protein-Based Composites |
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71 | (7) |
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3.2.1.1 Tissue engineering |
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72 | (3) |
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75 | (1) |
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76 | (2) |
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3.3 Lipid-Based Biocomposites |
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78 | (7) |
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3.3.1 Medical Applications of Lipid-Based Composites |
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79 | (22) |
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79 | (2) |
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81 | (1) |
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3.3.1.3 Antimicrobial application |
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82 | (1) |
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83 | (1) |
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3.3.1.5 Dental application |
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84 | (1) |
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84 | (1) |
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85 | (12) |
4 Biocomposites for Hyperthermia Applications |
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97 | (38) |
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98 | (3) |
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4.2 Synthesis of Iron Nanoparticles |
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101 | (4) |
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102 | (2) |
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4.2.2 Hydrothermal Method |
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104 | (1) |
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4.3 Magnetite: Tumor Treatment Using External Magnetic Field |
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105 | (1) |
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4.4 In Vivo Studies Demonstrating the Anticancer Effect of Magnetic Nanocarriers |
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105 | (2) |
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4.5 In Vitro Studies Demonstrating the Improvement in Intake Rate of Anticancer Agents Loaded into Nanoparticles in Different Tumor Cells |
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107 | (1) |
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4.6 Saturated Fatty Acids as Coatings for MNPs with Improved Properties as Anticancer Drugs Carriers |
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108 | (2) |
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4.7 Fabrication, Characterization, and In Vitro Assay of Antitumor Activity of Magnetite Coated with Non-polar Shell Without Using External Magnetic Field |
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110 | (1) |
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4.8 Biocomposites from Iron Nanoparticles: Biopolymers |
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111 | (5) |
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4.9 Biocomposites from Iron Nanoparticles: Hydroxyapatite |
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116 | (3) |
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119 | (16) |
5 Biocomposites Based on Natural Fibers: Concept and Biomedical Applications |
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135 | (28) |
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136 | (1) |
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5.2 Types of Natural Fibers |
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136 | (3) |
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5.3 Natural Fiber-Based Biocomposites |
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139 | (3) |
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5.4 Biomedical Applications of Natural Fibers |
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142 | (9) |
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143 | (3) |
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146 | (1) |
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147 | (1) |
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148 | (3) |
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151 | (12) |
6 Algae-Based Composites and Their Applications |
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163 | (18) |
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164 | (1) |
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6.2 Bio-based Natural Fibers |
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165 | (4) |
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6.2.1 Algal versus Other Natural and Synthetic Fibers |
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166 | (1) |
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6.2.2 Algal Constituents as Biocomposite Candidate |
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167 | (2) |
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167 | (1) |
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168 | (1) |
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168 | (1) |
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169 | (1) |
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6.3 Synthesis of Biocomposites |
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169 | (2) |
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169 | (1) |
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6.3.2 Extraction of Algal Fiber |
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169 | (1) |
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6.3.3 Natural Fiber Processing |
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170 | (1) |
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6.4 Applications of Algae-Based Composites |
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171 | (5) |
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6.4.1 Biosorption of Heavy Metals |
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172 | (1) |
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6.4.2 Automotive Industry |
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172 | (1) |
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6.4.3 Construction Materials |
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173 | (1) |
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6.4.4 Medical Applications |
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173 | (1) |
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174 | (1) |
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174 | (1) |
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175 | (1) |
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175 | (1) |
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6.5 Challenges and Future Prospects |
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176 | (5) |
7 Going Green Using Colocasia esculenta Starch and Starch Nanocrystals in Food Packaging |
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181 | (18) |
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182 | (1) |
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182 | (5) |
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7.2.1 Conventional Synthetic Packaging |
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183 | (2) |
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7.2.2 Biofilms, Edible Films, and Coatings |
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185 | (2) |
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187 | (4) |
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189 | (1) |
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189 | (1) |
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190 | (1) |
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190 | (1) |
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191 | (3) |
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192 | (1) |
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7.4.1.1 Water extraction method |
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192 | (1) |
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7.4.1.2 Alkaline extraction method |
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192 | (1) |
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7.4.2 Preparation of Starch Nanocrystals |
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192 | (1) |
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193 | (8) |
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7.4.3.1 Scanning electron microscopy |
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193 | (1) |
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7.4.3.2 Transmission electron microscopy |
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194 | (1) |
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194 | (5) |
8 Bionanocomposite Materials: Concept, Applications, and Recent Advancements |
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199 | (18) |
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200 | (1) |
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8.2 Types of Bionanocomposites |
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201 | (3) |
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8.2.1 Polysaccharide-Based Bionanocomposites |
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201 | (2) |
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8.2.1.1 Chitosan-based bionanocomposites |
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201 | (1) |
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8.2.1.2 Cellulose-based bionanocomposites |
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202 | (1) |
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8.2.1.3 Starch-based bionanocomposites |
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202 | (1) |
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8.2.1.4 Chitin-based bionanocomposites |
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202 | (1) |
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8.2.2 Nanoclay-Based Nanocomposites |
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203 | (1) |
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8.2.3 Hallyosite-Based Nanocomposites |
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203 | (1) |
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8.3 Preparation and Modifications |
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204 | (1) |
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8.4 Special Properties of Bionanocomposites |
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205 | (2) |
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8.4.1 Mechanical and Barrier Properties |
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205 | (1) |
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8.4.1.1 Young's modulus and tensile strength |
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206 | (1) |
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8.4.1.2 Toughness and strain |
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206 | (1) |
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8.4.2 Biological Properties |
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206 | (1) |
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206 | (1) |
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8.4.4 Antimicrobial Properties |
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207 | (1) |
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8.5 Recent Advances in the Field of Bionanocomposites |
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207 | (1) |
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8.6 Applications of Bionanocomposites |
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208 | (2) |
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8.6.1 Electronic, Sensor, and Energy Generation |
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208 | (1) |
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8.6.2 Biomedical Applications |
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209 | (1) |
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8.6.3 Packaging Applications |
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209 | (1) |
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210 | (1) |
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8.8 Conclusion and Future Trends |
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210 | (7) |
9 Plant Fiber-Reinforced Thermoset and Thermoplastic-Based Biocomposites |
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217 | (58) |
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218 | (1) |
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9.2 Natural Fibers as Reinforcement |
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218 | (5) |
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9.3 Woven and Non-woven Fabric |
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223 | (2) |
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223 | (1) |
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224 | (1) |
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9.4 Comparison of Non-woven and Woven Fabrics |
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225 | (1) |
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9.5 Mechanical Properties: Woven versus Non-woven Kenaf Fibers |
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226 | (2) |
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9.6 Types of Plant Fibers and Chemical Treatments |
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228 | (6) |
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9.6.1 Types of Plant Fibers |
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228 | (1) |
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9.6.2 Chemical and Thermal Treatment of Fibers |
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229 | (5) |
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9.6.2.1 Alkali treatments |
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230 | (1) |
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231 | (1) |
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9.6.2.3 Pyrolysis treatments |
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232 | (1) |
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9.6.2.4 Coating with silane treatment |
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233 | (1) |
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9.6.2.5 Benzoylation treatment |
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234 | (1) |
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9.7 Plant Fiber-Reinforced Thermoplastic Composites |
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234 | (13) |
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9.7.1 Processing and Characterization for the Processing of Natural Fiber-Reinforced Thermoplastics |
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235 | (6) |
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9.7.1.1 Polymer solution casting |
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236 | (2) |
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9.7.1.2 Compression molding |
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238 | (1) |
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9.7.1.3 Injection molding |
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239 | (2) |
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9.7.2 Mechanical, Thermal, and Physical Properties |
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241 | (2) |
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9.7.3 Flame-Retardant Properties of NFPCs |
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243 | (1) |
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9.7.4 Biodegradability of NFPCs |
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244 | (1) |
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9.7.5 Energy Absorption of NFPCs |
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244 | (1) |
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9.7.6 Water Absorption Characteristics of NFPCs |
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245 | (2) |
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9.8 Products and Applications of Plant Fiber-Reinforced Thermoplastics |
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247 | (2) |
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9.9 Plant Fiber-Reinforced Thermoset Composites |
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249 | (10) |
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9.9.1 General Characteristics of NFPCs |
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250 | (2) |
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9.9.2 Vacuum-Assisted Resin Transfer Molding |
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252 | (3) |
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9.9.3 Resin Transfer Molding |
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255 | (1) |
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256 | (1) |
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9.9.5 Mechanical Properties of NFPCs |
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257 | (1) |
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9.9.6 Viscoelastic Behavior of NFPCs |
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257 | (2) |
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9.10 Applications of Natural Fiber Polymer Composites |
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259 | (3) |
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9.10.1 Natural Fiber Applications in the Industry |
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260 | (2) |
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9.11 Rubber Composite Materials (Natural Fibers) |
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262 | (14) |
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9.11.1 Properties of Rubber Composites |
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263 | (2) |
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9.11.2 Manufacturing Process of Rubber Composites |
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265 | (1) |
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9.11.3 Applications of Rubber Composites |
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265 | (1) |
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9.12 Conclusion and Future Scope |
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266 | (9) |
10 Multifaceted Applications of Nanoparticles and Nanocomposites Decorated with Biopolymers |
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275 | (22) |
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Periyasamy Sivagurunathan |
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276 | (3) |
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10.2 Biosynthesis of Metal Nanocomposites |
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279 | (6) |
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10.2.1 Gold Nanoparticles |
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279 | (3) |
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10.2.2 Silver Nanoparticles |
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282 | (1) |
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10.2.3 Platinum Nanoparticles |
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283 | (1) |
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10.2.4 Copper Nanoparticles |
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283 | (1) |
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10.2.5 Titanium Oxide Nanoparticles |
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284 | (1) |
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285 | (4) |
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10.3.1 Nanocomposites from Bacteria |
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287 | (1) |
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10.3.2 Polyhydroxyalkanoates |
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288 | (1) |
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10.3.3 Application of Biopolymer-Metal Nanocomposites |
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289 | (1) |
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10.4 Biomedical Applications |
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289 | (3) |
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10.4.1 Tissue Engineering |
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289 | (2) |
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10.4.2 Drug-Delivery Systems |
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291 | (1) |
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292 | (5) |
11 Bionanocomposites, Their Processing, and Environmental Applications |
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297 | (32) |
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Chaudhery Mustansar Hussain |
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11.1 Introduction: Biodegradable Polymers |
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298 | (2) |
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11.2 Conventional Polymers versus Biodegradable Polymers |
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300 | (1) |
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11.3 Classification and Properties of Biodegradable Polymers |
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301 | (15) |
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11.3.1 Natural Biodegradable Polymers |
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302 | (5) |
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302 | (1) |
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11.3.1.2 Lignocellulosic complex (fibers) |
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303 | (1) |
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304 | (1) |
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11.3.1.4 Chitin and chitosan |
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305 | (1) |
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306 | (1) |
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11.3.2 Polypeptides of Natural Origin |
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307 | (3) |
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11.3.2.1 Collagen and gelatin |
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307 | (1) |
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308 | (1) |
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308 | (1) |
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309 | (1) |
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11.3.2.5 Casein and caseinate |
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309 | (1) |
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309 | (1) |
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11.3.3 Biopolymers Synthesized from Bio-derived and Synthetic Monomers |
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310 | (3) |
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11.3.3.1 Poly(lactic acid) or polylactide |
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310 | (1) |
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11.3.3.2 Poly(glycolic acid) |
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310 | (1) |
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11.3.3.3 Poly(E-caprolactone) |
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311 | (1) |
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11.3.3.4 Poly(butylene succinate) and its copolymer |
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311 | (1) |
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11.3.3.5 Poly(p-dioxanone) |
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312 | (1) |
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11.3.3.6 Poly(hydroxyalcanoate) |
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312 | (1) |
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11.3.4 Other Important Biodegradable Polymers |
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313 | (3) |
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11.3.4.1 Bacterial cellulose |
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313 | (1) |
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11.3.4.2 Poly(vinyl alcohol) and Poly(vinyl acetate) |
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313 | (1) |
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314 | (1) |
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314 | (1) |
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11.3.4.5 Polyamide and poly(ester-amide) |
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315 | (1) |
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315 | (1) |
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11.4 Nanofillers for Bionanocomposites |
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316 | (3) |
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11.4.1 Cellulose-Based Nanofillers |
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317 | (1) |
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318 | (1) |
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318 | (1) |
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11.5 Processing Aspects of Bionanocomposites |
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319 | (4) |
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11.5.1 Conventional Manufacturing Techniques |
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319 | (2) |
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11.5.2 In Situ Intercalative Polymerization |
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321 | (1) |
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11.5.3 Exfoliation-Adsorption |
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321 | (1) |
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11.5.4 Melt Intercalation |
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322 | (1) |
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11.5.5 Foam Processing Using Supercritical CO2 |
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322 | (1) |
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11.5.6 Template Synthesis |
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323 | (1) |
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11.6 Environmental Applications of Bionanocomposites |
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323 | (2) |
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325 | (4) |
12 Bionanocomposites in Water and Wastewater Treatment |
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329 | (34) |
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330 | (3) |
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12.2 Polymer Bionanocomposites |
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333 | (20) |
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12.2.1 Polysaccharide-Based Bionanocomposites |
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336 | (17) |
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12.2.1.1 Chitosan-based polymer bionanocomposites |
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337 | (4) |
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12.2.1.2 Gum polysaccharide-based bionanocomposites |
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341 | (6) |
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12.2.1.3 Cellulose nanocomposites |
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347 | (6) |
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12.2.2 Protein-Based Bionanocomposites |
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353 | (1) |
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12.3 Conclusion and Future Perspectives |
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353 | (10) |
13 Gamma Radiation Studies on Thermoplastic Polyurethane/Nanosilica Composites |
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363 | (12) |
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364 | (3) |
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13.2 Preparation of Thermoplastic Polyurethane/Nanosilica Composite |
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367 | (1) |
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13.2.1 Preparation of Nanocomposites |
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367 | (1) |
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13.3 Results and Discussions |
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368 | (5) |
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13.3.1 Mechanical Properties |
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368 | (1) |
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13.3.2 Electrical Properties |
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369 | (2) |
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13.3.2.1 Comparison of mechanical properties with normal silica versus nanosilica |
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371 | (1) |
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13.3.3 Thermal Analysis of Nanosilica Composites |
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371 | (6) |
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13.3.3.1 Comparison of thermal properties with nanosilica versus normal silica |
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372 | (1) |
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373 | (2) |
14 Removal of Heavy Metals and Textile Dyes in Industrial Wastewater Using Biopolymers and Biocomposites |
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375 | (30) |
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376 | (1) |
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14.2 Removal of Heavy Metals in Industrial Wastewater Using Biopolymers and Biocomposites |
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377 | (14) |
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14.2.1 Types of Heavy Metals in Industrial Wastewater |
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377 | (1) |
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14.2.2 Removal of Heavy Metals Using Biopolymers |
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377 | (1) |
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14.2.3 Removal of Heavy Metals Using Biocomposites |
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378 | (3) |
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14.2.4 Method for Treatment of Heavy Metals in Wastewater |
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381 | (1) |
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14.2.5 Adsorption Process |
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381 | (5) |
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14.2.6 Advantages and Disadvantages of Heavy Metal-Removal Techniques |
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386 | (2) |
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14.2.7 Types of Heavy Metals and Their Effect on Human Health |
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388 | (3) |
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14.3 Removal of Textile Dyes in Industrial Wastewater Using Biopolymers and Biocomposites |
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391 | (6) |
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14.3.1 Classification of Dyes Based on Their Applications |
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391 | (1) |
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14.3.2 Types of Textile Dyes in Industrial Wastewater |
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392 | (1) |
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14.3.3 Removal of Textile Dyes in Industrial Wastewater Using Biopolymers |
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393 | (1) |
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14.3.4 Removal of Textile Dyes in Industrial Wastewater Using Biocomposites |
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394 | (1) |
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14.3.5 Method for Treatment of Textile Dye in Wastewater |
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395 | (1) |
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14.3.6 Advantages and Disadvantages of Various Dye-Removal Techniques |
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396 | (1) |
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397 | (8) |
15 Bio-based Material Protein and Its Novel Applications |
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405 | (28) |
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406 | (1) |
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407 | (1) |
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15.2.1 Classification of Amino Acids |
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407 | (1) |
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15.3 Classification of Proteins |
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408 | (5) |
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409 | (1) |
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15.3.1.1 Fibrous proteins |
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410 | (1) |
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15.3.1.2 Globular proteins |
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410 | (1) |
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15.3.2 Conjugated Proteins |
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410 | (2) |
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15.3.2.1 Glycoproteins or mucoproteins |
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411 | (1) |
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411 | (1) |
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411 | (1) |
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412 | (1) |
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15.3.2.5 Chromoproteins or metalloproteins |
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412 | (1) |
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412 | (1) |
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15.4 Structure of Protein |
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413 | (4) |
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413 | (1) |
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15.4.2 Secondary Structure |
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413 | (2) |
|
15.4.3 Tertiary Structure |
|
|
415 | (1) |
|
15.4.4 Quaternary Structure |
|
|
416 | (1) |
|
15.5 Properties of Proteins |
|
|
417 | (1) |
|
15.5.1 Electrolytic Properties of Protein |
|
|
417 | (1) |
|
15.5.2 Ionic Characteristics |
|
|
417 | (1) |
|
|
417 | (1) |
|
15.5.4 Hydrolytic Characteristic |
|
|
417 | (1) |
|
|
418 | (1) |
|
15.6 Native Proteins and Their Denaturation |
|
|
418 | (2) |
|
|
418 | (2) |
|
|
420 | (1) |
|
|
420 | (1) |
|
15.7.2 Three-Dimensional Network Theories |
|
|
421 | (1) |
|
15.7.3 Particle Orientation Theory |
|
|
421 | (1) |
|
|
421 | (2) |
|
|
422 | (1) |
|
15.8.2 Vegetable Proteins |
|
|
422 | (1) |
|
15.9 Non-traditional Proteins |
|
|
423 | (1) |
|
15.10 Nutritional Importance of Proteins |
|
|
424 | (2) |
|
15.11 Applications of Protein-Based Biocomposites |
|
|
426 | (4) |
|
15.11.1 Protein-Based Biocomposites as Biodegradable Packaging Materials |
|
|
426 | (1) |
|
15.11.2 Protein-Based Thermoplastics in Biomedical Applications |
|
|
427 | (1) |
|
|
428 | (1) |
|
15.11.4 Tissue Engineering |
|
|
428 | (1) |
|
|
429 | (1) |
|
15.11.6 Other Applications |
|
|
429 | (1) |
|
15.12 Conclusion and Future Perspectives |
|
|
430 | (3) |
16 Biopolyesters: Novel Candidates to Develop Multifunctional Biocomposites |
|
433 | (24) |
|
|
|
|
434 | (1) |
|
|
434 | (3) |
|
16.3 Physiochemical Characteristics of Biopolyesters |
|
|
437 | (1) |
|
16.4 Poly(3-hydroxybutyrate) |
|
|
437 | (2) |
|
|
439 | (1) |
|
16.6 Properties of Biocomposites for Biomedical Applications |
|
|
440 | (2) |
|
16.6.1 Biocompatibility and Biodegradability |
|
|
440 | (2) |
|
16.7 Biomedical and Biotechnological Applications |
|
|
442 | (4) |
|
16.7.1 Biomedical Applications |
|
|
443 | (2) |
|
16.7.2 Biotechnological Applications |
|
|
445 | (1) |
|
16.8 Concluding Remarks and Future Considerations |
|
|
446 | (11) |
17 Treatment of Industrial Wastewater Using Biopolymers and Biocomposites |
|
457 | (26) |
|
|
|
|
|
|
|
|
458 | (1) |
|
17.2 Wastewater from Various Industries |
|
|
459 | (6) |
|
17.2.1 Wastewater from Food Industries |
|
|
459 | (1) |
|
17.2.2 Wastewater from Distillery Plants |
|
|
459 | (1) |
|
17.2.3 Wastewater from Coffee Processing |
|
|
460 | (1) |
|
17.2.4 Wastewater from Milk Industries |
|
|
461 | (1) |
|
17.2.5 Wastewater from Slaughterhouses |
|
|
462 | (1) |
|
17.2.6 Wastewater from Other Industries |
|
|
463 | (2) |
|
17.3 Methods of Wastewater Treatment |
|
|
465 | (3) |
|
17.3.1 Physical Treatment |
|
|
465 | (1) |
|
17.3.2 Biological Treatment |
|
|
466 | (1) |
|
17.3.3 Chemical Treatment |
|
|
467 | (1) |
|
17.4 Types of Reactors Used in Wastewater Treatment |
|
|
468 | (4) |
|
17.4.1 Membrane Filtration |
|
|
468 | (1) |
|
|
469 | (1) |
|
17.4.3 Complete Mixed Reactor |
|
|
470 | (1) |
|
|
471 | (1) |
|
17.5 Application of Biopolymer and Biocomposite in Wastewater Treatment |
|
|
472 | (3) |
|
17.5.1 Application of Chitosan in Wastewater Treatment |
|
|
472 | (2) |
|
17.5.2 Application of Alginate in Wastewater Treatment |
|
|
474 | (1) |
|
17.6 Agriculture Byproducts as Low-Cost Biosorbent for Wastewater Treatment |
|
|
475 | (2) |
|
|
477 | (6) |
Index |
|
483 | |