Foreword |
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xv | |
Preface |
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xvii | |
Acknowledgements |
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xix | |
1 Introduction |
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1 | (8) |
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1 | (1) |
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1.2 Historical background |
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1 | (2) |
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1.3 Overview of petrographic methods |
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3 | (2) |
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5 | (1) |
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1.5 Objectives and coverage |
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5 | (1) |
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6 | (3) |
2 Petrographic equipment and methods |
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9 | (48) |
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2.1 Petrographic examination of concrete |
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9 | (1) |
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2.2 Initial laboratory examination |
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9 | (3) |
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2.3 Petrographic laboratory |
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12 | (7) |
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2.3.1 Low-power stereomicroscope |
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13 | (1) |
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2.3.2 Petrographic polarising microscope |
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14 | (2) |
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2.3.2.1 Adjustment of the polarising microscope for transmitted light |
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14 | (1) |
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2.3.2.2 Centring the objective lenses |
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15 | (1) |
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2.3.2.3 Calibrating the eyepiece micrometre graticule |
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15 | (1) |
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2.3.2.4 Reflected or incident-light illumination |
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15 | (1) |
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2.3.3 Construction features of the polarising microscope |
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16 | (3) |
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2.3.4 Photomicrographic equipment |
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19 | (1) |
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2.4 Quantitative methods of component analysis |
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19 | (5) |
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2.4.1 Standard modal analysis methods |
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20 | (4) |
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2.5 Complementary and specialised techniques |
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24 | (18) |
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2.5.1 Petrographic examination under ultraviolet illumination |
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24 | (1) |
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2.5.2 Scanning electron microscopy and microanalysis |
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24 | (9) |
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2.5.2.1 Components of a scanning electron microscope |
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26 | (4) |
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2.5.2.2 Elemental x-ray microanalysis |
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30 | (1) |
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2.5.2.3 Mineral and element recognition and mapping |
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31 | (2) |
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2.5.3 X-ray powder diffraction techniques |
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33 | (1) |
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2.5.4 Fourier transform infrared spectroscopy |
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34 | (3) |
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2.5.4.1 Sample preparation |
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35 | (2) |
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2.5.4.2 Spectral interpretation |
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37 | (1) |
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2.5.5 Thermal methods of analysis |
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37 | (1) |
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2.5.6 Chemical methods of analysis |
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38 | (4) |
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2.5.6.1 Chemical analysis of unhydrated blended cements |
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38 | (1) |
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2.5.6.2 Chemical analysis of hardened cement pastes in concrete |
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39 | (2) |
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2.5.6.3 Identification of polymer additions in mortars and concrete |
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41 | (1) |
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2.6 Computer-aided petrographic methods |
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42 | (10) |
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2.6.1 Quantitative image analysis |
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42 | (5) |
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43 | (2) |
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45 | (1) |
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2.6.1.3 Segmentation and thresholding |
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45 | (1) |
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46 | (1) |
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2.6.2 Case study applications of image analysis |
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47 | (10) |
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2.6.2.1 Estimation of pyrite content in mudstone aggregate |
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47 | (1) |
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2.6.2.2 Modal analysis of a mortar specimen |
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47 | (2) |
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2.6.2.3 Quantitative investigation of fractures |
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49 | (1) |
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2.6.2.4 Evaluation of shape and distribution of voids |
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49 | (3) |
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52 | (5) |
3 Sampling and specimen preparation |
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57 | (46) |
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3.1 Sampling concrete and related materials |
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57 | (1) |
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3.2 Inspection of structures |
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57 | (2) |
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3.2.1 Surface expression of concrete deterioration |
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58 | (1) |
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3.3 Representative sample |
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59 | (16) |
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3.3.1 Particulate materials |
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59 | (2) |
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3.3.2 Statistical considerations |
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61 | (3) |
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3.3.3 Examination of particulate materials |
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64 | (1) |
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65 | (4) |
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3.3.5 Practical sampling methods for solids |
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69 | (1) |
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3.3.6 Preparation of subsample specimens for investigation |
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70 | (5) |
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3.4 Preparation of thin sections and finely ground or polished surfaces |
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75 | (16) |
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3.4.1 Laboratory methods of cutting concrete |
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76 | (2) |
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3.4.2 Laboratory preparation of ground surfaces |
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78 | (4) |
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3.4.3 Laboratory preparation of polished surfaces |
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82 | (1) |
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3.4.4 Resins for impregnation and mounting concrete specimens |
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82 | (4) |
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3.4.5 Preparation of petrographic thin sections |
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86 | (5) |
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3.5 Specimen preparation for special purposes |
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91 | (8) |
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3.5.1 Small selected specimens |
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92 | (1) |
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92 | (1) |
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3.5.3 Preparations involving etches, stains and dyes |
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93 | (1) |
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3.5.4 Dyes for use with resins |
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94 | (1) |
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3.5.5 Stains for identification of minerals |
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95 | (1) |
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3.5.6 Etching procedures for cement clinkers |
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96 | (3) |
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99 | (4) |
4 Composition of concrete |
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103 | (194) |
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103 | (1) |
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4.2 Cement types and binder content |
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103 | (54) |
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4.2.1 Anhydrous Portland cement phases and clinker |
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103 | (7) |
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4.2.1.1 Calcium silicates (C3S, C2S) |
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106 | (2) |
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4.2.1.2 Calcium aluminates and calcium aluminoferrites (C3A, C4AF) |
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108 | (1) |
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4.2.1.3 Lime and periclase (CaO, MgO) |
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108 | (1) |
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4.2.1.4 Other phases and gypsum |
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109 | (1) |
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4.2.2 Identification of cement type in concrete |
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110 | (6) |
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4.2.2.1 General principle of optical microscopical methods |
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111 | (1) |
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4.2.2.2 Microscopical procedure |
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111 | (2) |
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4.2.2.3 Interpretation of the findings and some difficulties |
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113 | (2) |
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4.2.2.4 SEM and other methods |
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115 | (1) |
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4.2.3 Hydrated cement phases |
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116 | (15) |
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4.2.3.1 CSH and the microstructure of cement paste |
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118 | (2) |
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4.2.3.2 Degree of hydration |
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120 | (1) |
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4.2.3.3 Portlandite (Ca(OH)2) |
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121 | (3) |
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4.2.3.4 Ettringite and some other complex phases |
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124 | (7) |
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4.2.4 Blended and special cements |
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131 | (15) |
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4.2.4.1 Portland-limestone cements |
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131 | (1) |
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4.2.4.2 Ggbs and Portland blast furnace cements |
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131 | (4) |
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4.2.4.3 Pfa, fly ash and Portland pozzolanic cements |
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135 | (3) |
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4.2.4.4 High-alumina cement |
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138 | (7) |
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4.2.4.5 Supersulphated and other special cements |
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145 | (1) |
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4.2.5 Building lime and cement/lime mixtures |
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146 | (10) |
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147 | (6) |
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4.2.5.2 Cement/lime mixtures |
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153 | (3) |
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4.2.6 Cement or binder contents in concrete |
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156 | (1) |
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4.3 Aggregate types and characteristics |
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157 | (29) |
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4.3.1 Petrographic identity of aggregate |
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157 | (6) |
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4.3.1.1 Typical aggregate combinations |
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158 | (1) |
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4.3.1.2 Crushed rock coarse aggregates |
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158 | (3) |
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4.3.1.3 Natural gravel coarse aggregates |
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161 | (1) |
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4.3.1.4 Crushed rock and natural sand fine aggregates |
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161 | (1) |
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4.3.1.5 Recycled aggregates |
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162 | (1) |
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4.3.2 Particle size and aggregate size grading |
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163 | (8) |
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171 | (2) |
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4.3.4 Particle shape recognition |
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173 | (9) |
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4.3.4.1 Form and sphericity |
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173 | (1) |
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4.3.4.2 Roundness and angularity |
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174 | (1) |
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175 | (1) |
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4.3.4.4 Use of desktop flat-bed scanners |
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176 | (6) |
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4.3.5 Other particle characteristics |
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182 | (4) |
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186 | (23) |
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4.4.1 Definitions and relationship to concrete properties |
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186 | (2) |
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4.4.2 Indicators of water/cement ratio |
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188 | (5) |
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4.4.2.1 Water voids and bleeding |
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189 | (1) |
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4.4.2.2 Capillary porosity |
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189 | (3) |
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4.4.2.3 Mineralogical features |
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192 | (1) |
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4.4.3 Determination of water/cement ratio by the physico-chemical method |
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193 | (2) |
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4.4.4 Determination of water/cement ratio by fluorescence microscopy |
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195 | (12) |
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4.4.4.1 Principle of the method |
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195 | (1) |
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4.4.4.2 Transmitted and reflected light procedures for determination of equivalent water/cement ratio using thin sections |
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196 | (8) |
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4.4.4.3 Reflected light procedure for the determination of equivalent water/cement ratio using ground polished specimens |
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204 | (3) |
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4.4.5 Determination of water/cement ratio using scanning electron microscopy |
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207 | (2) |
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4.5 Air-void content and air entrainment |
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209 | (24) |
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4.5.1 Types of voids in concrete |
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209 | (7) |
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4.5.1.1 Entrapped air voids |
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210 | (1) |
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4.5.1.2 Entrained air voids |
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211 | (5) |
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4.5.2 Quantification of air-void content in hardened concrete |
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216 | (8) |
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4.5.2.1 Visual assessment of excess voidage |
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216 | (3) |
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4.5.2.2 Other methods for assessing air-void content |
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219 | (1) |
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4.5.2.3 Use of desktop flat-bed scanners |
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220 | (4) |
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4.5.3 Microscopical measurement of the air-void system |
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224 | (7) |
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4.5.4 Aerated and foamed concrete |
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231 | (2) |
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4.6 Mineral additions and pigments |
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233 | (20) |
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4.6.1 Fly ash and pulverised-fuel ash |
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233 | (5) |
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4.6.1.1 Identifying fly ash or pfa |
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234 | (1) |
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4.6.1.2 Quantifying the content of fly ash or pfa |
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235 | (3) |
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4.6.2 Blastfurnace slag materials |
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238 | (6) |
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240 | (3) |
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4.6.2.2 Quantifying the content of ggbs |
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243 | (1) |
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4.6.3 Ultra-fine additions |
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244 | (6) |
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4.6.3.1 Microsilica (condensed silica fume) |
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245 | (4) |
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249 | (1) |
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4.6.4 Natural pozzolanas and other additions |
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250 | (1) |
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251 | (2) |
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253 | (3) |
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256 | (9) |
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260 | (2) |
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262 | (1) |
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4.8.3 Polymer and other organic fibres |
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262 | (3) |
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265 | (9) |
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4.9.1 Quantitative analysis of concrete composition |
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265 | (3) |
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4.9.2 Estimation of cement replacement by pfa or ggbs |
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268 | (2) |
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4.9.3 Applications of concrete composition by petrography |
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270 | (28) |
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4.9.3.1 Comparison of actual and design concrete mixes |
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270 | (3) |
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4.9.3.2 Concrete in a murder case |
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273 | (1) |
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274 | (23) |
5 Appearance and textures of cementitious materials |
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297 | (88) |
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297 | (1) |
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5.2 Optical observations of the hardened Portland cement paste matrix |
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298 | (19) |
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5.2.1 Typical composition of hardened Portland cement |
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300 | (1) |
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5.2.2 Remnant or oversize cement clinker grains |
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301 | (3) |
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5.2.3 Colour of hardened concrete |
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304 | (1) |
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5.2.4 Ettringite in hardened concrete |
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305 | (2) |
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5.2.5 Calcium hydroxide in hardened cement paste |
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307 | (7) |
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5.2.6 Modification of calcium hydroxide in Portland cement concretes |
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314 | (3) |
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5.3 Concretes containing mineral admixtures |
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317 | (10) |
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5.3.1 Portland limestone cement concrete |
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317 | (1) |
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5.3.2 Pozzolanic and Portland slag cements |
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317 | (8) |
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5.3.3 Petrographic examination of slags and pozzolanas |
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325 | (2) |
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5.4 High-alumina or calcium aluminate cement concretes |
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327 | (4) |
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5.5 Carbonation of Portland cement concretes |
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331 | (10) |
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5.5.1 Effects of carbonation on porosity and strength |
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333 | (1) |
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5.5.2 Typical textures of carbonation |
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334 | (2) |
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5.5.3 Carbonation of the outer layers of concrete |
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336 | (1) |
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5.5.4 Carbonation associated with crack systems |
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337 | (1) |
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5.5.5 Carbonation associated with aggregate types in concrete |
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338 | (1) |
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5.5:6 Surface exudations and efflorescence |
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339 | (2) |
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5.6 Interfaces within concrete |
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341 | (6) |
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5.6.1 Aggregate/cement paste interface |
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|
342 | (2) |
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5.6.2 Steel reinforcement/cement paste interfaces |
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344 | (1) |
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5.6.3 Fibre reinforcement/cement paste interfaces |
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345 | (1) |
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346 | (1) |
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5.6.5 Other cementitious interfaces |
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346 | (1) |
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347 | (8) |
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5.7.1 Entrapped air voids |
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349 | (1) |
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5.7.2 Entrained air void systems |
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350 | (2) |
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5.7.3 Capillary and gel pores |
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352 | (1) |
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5.7.4 Other air voids in concrete |
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352 | (2) |
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5.7.5 Aerated and no-fines concretes |
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354 | (1) |
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355 | (20) |
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5.8.1 Cracks resulting from tensile strain |
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356 | (1) |
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5.8.2 Differentiating between structural and non-structural cracks |
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356 | (2) |
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5.8.3 Non-structural cracks in concrete |
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358 | (12) |
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5.8.3.1 Cracking subparallel to, and restricted to, the near surface |
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358 | (3) |
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5.8.3.2 Cracking approximately perpendicular to, and restricted to, the near surface |
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361 | (4) |
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5.8.3.3 Cracking reflecting interior expansion of the concrete |
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365 | (3) |
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5.8.3.4 Cracking limited to the interior of the concrete |
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368 | (2) |
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5.8.4 Petrographic examination and the interpretation of crack systems |
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370 | (3) |
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5.8.5 Cracking as artefacts of sampling and preparation |
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373 | (2) |
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375 | (10) |
6 Examination of deteriorated and damaged concrete |
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385 | (228) |
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385 | (11) |
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6.1.1 Background to concrete durability |
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385 | (2) |
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6.1.2 Durability investigation and classification |
|
|
387 | (3) |
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6.1.3 Quantification of deterioration and damage |
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390 | (6) |
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|
391 | (2) |
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6.1.3.2 Interpretation and reproducibility |
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393 | (2) |
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6.1.3.3 Alternative methods |
|
|
395 | (1) |
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6.2 Plastic and drying shrinkage |
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396 | (6) |
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396 | (1) |
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6.2.2 Macroscopic effects of plastic and drying shrinkage |
|
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396 | (1) |
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6.2.3 Petrographic examination of shrinkage cracking |
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|
397 | (1) |
|
6.2.4 Shrinkage of aggregates in concrete |
|
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398 | (4) |
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6.3 Corrosion of steel reinforcement |
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|
402 | (14) |
|
6.3.1 Role, depth and quality of concrete cover |
|
|
404 | (2) |
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6.3.2 Steel reinforcement corrosion mechanisms and factors |
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|
406 | (3) |
|
6.3.3 Carbonation, loss of alkalinity and corrosion of reinforcement |
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|
409 | (2) |
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6.3.4 Chlorides and corrosion of steel reinforcement |
|
|
411 | (5) |
|
6.3.5 Prevention of reinforcement corrosion |
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416 | (1) |
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6.4 Frost and freeze-thaw action |
|
|
416 | (6) |
|
6.4.1 Freeze-thaw mechanisms and factors |
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|
418 | (1) |
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6.4.2 Macroscopic and microscopic evidence of freeze-thaw action |
|
|
418 | (4) |
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|
422 | (67) |
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422 | (1) |
|
6.5.2 Ground and groundwater sulphates |
|
|
423 | (6) |
|
6.5.3 Conventional sulphate attack |
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|
429 | (10) |
|
6.5.3.1 Properties of concrete relating to sulphate attack |
|
|
429 | (1) |
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6.5.3.2 External appearance of concrete attacked by sulphate |
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|
430 | (2) |
|
6.5.3.3 Internal textures of concrete attacked by sulphate |
|
|
432 | (7) |
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|
439 | (4) |
|
6.5.5 Sulphate attack in sewerage systems |
|
|
443 | (7) |
|
6.5.6 Thaumasite sulphate attack (TSA) |
|
|
450 | (11) |
|
|
450 | (4) |
|
6.5.6.2 Petrography of TSA |
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454 | (7) |
|
6.5.7 Internal sulphate attack |
|
|
461 | (5) |
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466 | (9) |
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6.5.8.1 Background to the mundic problem |
|
|
466 | (3) |
|
6.5.8.2 Petrographic examination of mundic concrete |
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|
469 | (2) |
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6.5.8.3 RICS classification scheme |
|
|
471 | (4) |
|
6.5.9 Delayed ettringite formation (DEF) |
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|
475 | (14) |
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6.5.9.1 Background and mechanism of DEF |
|
|
477 | (4) |
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6.5.9.2 Petrographic investigation of DEF |
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|
481 | (8) |
|
6.6 Acid and alkaline attacks |
|
|
489 | (18) |
|
6.6.1 Natural acid waters and 'aggressive carbonation' |
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|
491 | (10) |
|
6.6.1.1 Petrographic textures |
|
|
493 | (3) |
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6.6.1.2 Estimation of rates of attack |
|
|
496 | (5) |
|
6.6.2 Carbonation and corrosion by geothermal fluids |
|
|
501 | (2) |
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6.6.2.1 Textures of grouts exposed to geothermal fluids |
|
|
501 | (2) |
|
6.6.3 Acid-type attack from sulphates, sulphides, brine and microbial action |
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|
503 | (1) |
|
6.6.4 Industrial chemical attack |
|
|
504 | (3) |
|
6.6.4.1 Petrographic investigation |
|
|
506 | (1) |
|
6.7 Weathering and leaching |
|
|
507 | (3) |
|
6.7.1 General aspects of weathering and deterioration |
|
|
507 | (1) |
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|
508 | (1) |
|
|
509 | (1) |
|
6.8 Alkali-aggregate reaction (AAR) |
|
|
510 | (43) |
|
|
510 | (2) |
|
6.8.2 Chemistry of the alkali-silica reaction |
|
|
512 | (2) |
|
6.8.3 External appearance of concrete affected by ASR |
|
|
514 | (5) |
|
6.8.4 Microscopic textures and features of concrete affected by ASR |
|
|
519 | (25) |
|
6.8.4.1 Observations on cores and polished slices |
|
|
521 | (2) |
|
6.8.4.2 Observations on thin sections |
|
|
523 | (8) |
|
6.8.4.3 Reactive aggregates |
|
|
531 | (11) |
|
6.8.4.4 Lightweight aggregates |
|
|
542 | (2) |
|
6.8.5 Examination of concretes suspected of ASR |
|
|
544 | (6) |
|
6.8.5.1 Interpretation of ASR textures |
|
|
544 | (3) |
|
6.8.5.2 Practical examination |
|
|
547 | (1) |
|
6.8.5.3 Other considerations |
|
|
548 | (2) |
|
6.8.6 International schemes for assessment, diagnosis and specification |
|
|
550 | (3) |
|
6.9 AAR involving carbonate aggregates |
|
|
553 | (16) |
|
6.9.1 Background and current position on ACR |
|
|
554 | (4) |
|
6.9.1.1 De-dolomitisation |
|
|
554 | (1) |
|
6.9.1.2 Alkali-silica reaction |
|
|
555 | (1) |
|
|
556 | (1) |
|
6.9.1.4 Natural de-dolomitisation |
|
|
557 | (1) |
|
6.9.2 Practical examination of concretes suspected of ACR |
|
|
558 | (8) |
|
|
559 | (1) |
|
6.9.2.2 Reaction rims in aggregates |
|
|
560 | (2) |
|
6.9.2.3 Carbonate haloes in cement paste |
|
|
562 | (1) |
|
6.9.2.4 Alkali-silica gel |
|
|
563 | (2) |
|
6.9.2.5 Cryptocrystalline quartz |
|
|
565 | (1) |
|
6.9.3 Ancillary techniques for assessing ACR potential |
|
|
566 | (3) |
|
6.9.3.1 Acid-insoluble residues |
|
|
566 | (1) |
|
6.9.3.2 Crystallinity index (CI) of quartz |
|
|
567 | (1) |
|
6.9.3.3 Uranyl fluorescence method |
|
|
567 | (1) |
|
|
567 | (1) |
|
6.9.3.5 Rock cylinder test |
|
|
568 | (1) |
|
6.9.3.6 Concrete and mortar expansion tests |
|
|
568 | (1) |
|
6.10 Damage from thermal cycling and fire |
|
|
569 | (13) |
|
6.10.1 Thermal expansion and cracking of concrete |
|
|
570 | (2) |
|
6.10.2 Effects of fire damage on concrete |
|
|
572 | (4) |
|
|
573 | (1) |
|
6.10.2.2 Surface spalling |
|
|
574 | (2) |
|
6.10.3 Investigation of fire-damaged concrete |
|
|
576 | (48) |
|
|
576 | (4) |
|
6.10.3.2 Other methods of investigation |
|
|
580 | (2) |
|
|
582 | (31) |
7 Precast and special concretes |
|
613 | (34) |
|
7.1 Standard precast concrete units |
|
|
613 | (1) |
|
7.2 Precast, block, brick, tile and pavers |
|
|
614 | (3) |
|
7.3 Precast concrete pipes |
|
|
617 | (3) |
|
7.4 Reinforced precast concrete units |
|
|
620 | (1) |
|
7.5 Steam-cured precast concrete units |
|
|
621 | (1) |
|
7.6 Composite precast concrete units and reconstituted (artificial) stone |
|
|
622 | (2) |
|
7.7 Fibre-reinforced products |
|
|
624 | (9) |
|
7.7.1 Asbestos-cement products |
|
|
624 | (5) |
|
7.7.2 Synthetic fibre-reinforced concrete products |
|
|
629 | (3) |
|
7.7.3 Natural fibre-reinforced concrete products |
|
|
632 | (1) |
|
7.8 Polymer cement products |
|
|
633 | (2) |
|
7.9 Special floor coatings |
|
|
635 | (2) |
|
7.10 Self-compacting concrete |
|
|
637 | (1) |
|
7.11 Lightweight aggregates and concretes |
|
|
637 | (6) |
|
|
643 | (4) |
8 Portland cement mortar, screeds, renders and special cements |
|
647 | (22) |
|
8.1 Mortar and related materials |
|
|
647 | (1) |
|
|
647 | (7) |
|
|
651 | (1) |
|
8.2.2 Tiled surface finishes |
|
|
652 | (2) |
|
8.3 Renders and cementitious plasters |
|
|
654 | (2) |
|
8.3.1 Cementitious plasters |
|
|
654 | (1) |
|
8.3.2 Petrographic methods of examination |
|
|
655 | (1) |
|
8.4 Jointing and bedding mortars |
|
|
656 | (1) |
|
8.5 Special cements and grouts |
|
|
657 | (5) |
|
8.5.1 Cementitious grouts |
|
|
658 | (1) |
|
|
659 | (1) |
|
8.5.3 Petrographic investigation of oil-well cements |
|
|
660 | (1) |
|
8.5.4 White and coloured Portland cements |
|
|
661 | (1) |
|
8.5.5 Other Portland-based cements |
|
|
662 | (1) |
|
|
662 | (3) |
|
8.7 Cementitious repair materials |
|
|
665 | (1) |
|
8.8 Cementitious levelling compounds |
|
|
665 | (1) |
|
8.9 Cementitious adhesive compounds |
|
|
666 | (1) |
|
|
666 | (3) |
9 Non-Portland cementitious materials, plasters and mortars |
|
669 | (26) |
|
9.1 Lime-based materials and products |
|
|
669 | (2) |
|
|
669 | (2) |
|
9.2 Lime plasters, mortars and screeds |
|
|
671 | (4) |
|
9.3 Gypsum-based wall plasters and plasterboard |
|
|
675 | (6) |
|
9.3.1 Petrographic investigation of hemihydrate and anhydrite products |
|
|
679 | (1) |
|
9.3.2 Gypsum and plaster finishes |
|
|
679 | (2) |
|
|
681 | (5) |
|
9.5 Calcium silicate products |
|
|
686 | (4) |
|
9.6 Special flooring finishes |
|
|
690 | (1) |
|
|
690 | (1) |
|
|
691 | (4) |
Glossary of minerals |
|
695 | (60) |
Index |
|
755 | |