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Introduction To Marcus Theory Of Electron Transfer Reactions [Kõva köide]

(Sapienza Univ Of Rome, Italy)
  • Formaat: Hardback, 872 pages
  • Ilmumisaeg: 20-Apr-2020
  • Kirjastus: World Scientific Publishing Co Pte Ltd
  • ISBN-10: 9811208468
  • ISBN-13: 9789811208461
Teised raamatud teemal:
  • Formaat: Hardback, 872 pages
  • Ilmumisaeg: 20-Apr-2020
  • Kirjastus: World Scientific Publishing Co Pte Ltd
  • ISBN-10: 9811208468
  • ISBN-13: 9789811208461
Teised raamatud teemal:
This book, with a foreword from Nobel Laureate Rudolph A Marcus, aims at introducing the reader to the Marcus theory of electron transfer reactions from a reading of excerpts of Marcus' papers. Notes from the author may be of help to the student or the beginner. Marcus' notes at the end of each paper, with his comments and remarks, are an invaluable supplement to his articles for students and scholars in the field of electron transfer reactions.
Foreword vii
Preface ix
Scheme of the Book, Figures, Notes, and Abbreviations xi
Acknowledgments xiii
List of 42 Marcus' Papers Closely Followed, Summarized or Abridged in
Chapters 2--11 and of 10 Papers Considered in the Oral Interviews of
Chapters 12 and 13
xix
List of Marcus' Papers Considered in the
Chapters of the Book
xxvii
Chapter 1 Introduction
1(40)
Chapter 2 Foundations of the Theory, Its First Formulation
41(34)
Chapter 3 Extensions, Electron Transfer at Electrodes, Applications
75(70)
Chapter 4 Theory of Electrochemical Electron Transfer
145(30)
Chapter 5 Statistical Mechanical Theory of Electron Transfer, Equivalent Equilibrium Distribution, Reaction Coordinate for ET, Inverted Free Energy Effect, Interactions in Polar Media
175(86)
Chapter 6 Unified General Theory of Electron Transfer Reactions
261(82)
Chapter 7 Theory of Electron Transfer Reactions of Solvated Electrons and of Chemiluminescent Electron Transfer Reactions
343(78)
Chapter 8 Rate Constants, Barriers, and Brønsted Slopes, Electron Transfer at Electrodes and in Solution: Theory versus Experiment---Electrode Reactions of Organic Compounds
421(60)
Chapter 9 Activated-Complex Theory, Application to Electron Transfer Reactions. Marcus' Notes on Electron Transfer, on Proton Transfer and on Electrode Kinetics
481(56)
Chapter 10 Unusual Activation Parameters, Electron and Nuclear Tunneling, Mechanisms of Charge Separation, Spin Exchange and Electron Transfer in Photosynthesis; Electron Transfer versus Proton Transfer at Electrodes and in Solution, Hydrogen Evolution, Quantum Effects, Classical and Semiclassical Calculations of Electron Transfer Rates
537(96)
Chapter 11 Mixed Reaction-Diffusion Rates, Quantum Effects in the Inverted Region, Frequency Factor in Electron Transfer: Its Role in the Highly Exothermic Regime, Highly Exothermic Electron Transfer, Electron and Proton Transfer, Nonadiabatic Processes, Quantum-like and Classical-like Coordinates, Applications to Nonadiabatic Electron Transfers
633(120)
Chapter 12 Entropic, Electrolyte, and Orientation Effects in Electron Transfer, Electron Transfer in Chemistry and Biology, Application of Electron Transfer to Systems of Biological Interest, Barriers for Thermal and Optical Electron Transfer in Solution, Semiclassical Model for Orientation Effects in Electron Transfer, Orientation Effects on Electron Transfer between Porphyrins
753(38)
Chapter 13 Dynamical Effects in Electron Transfer Reactions, Dielectric Relaxation and Intramolecular Electron Transfer, Solvent Dynamics, and Vibrational Effects in Electron Transfer
791