| Foreword |
|
vii | |
| Preface |
|
ix | |
| Scheme of the Book, Figures, Notes, and Abbreviations |
|
xi | |
| Acknowledgments |
|
xiii | |
|
List of 42 Marcus' Papers Closely Followed, Summarized or Abridged in
Chapters 2--11 and of 10 Papers Considered in the Oral Interviews of
Chapters 12 and 13 |
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|
xix | |
|
List of Marcus' Papers Considered in the
Chapters of the Book |
|
|
xxvii | |
|
|
|
1 | (40) |
|
Chapter 2 Foundations of the Theory, Its First Formulation |
|
|
41 | (34) |
|
Chapter 3 Extensions, Electron Transfer at Electrodes, Applications |
|
|
75 | (70) |
|
Chapter 4 Theory of Electrochemical Electron Transfer |
|
|
145 | (30) |
|
Chapter 5 Statistical Mechanical Theory of Electron Transfer, Equivalent Equilibrium Distribution, Reaction Coordinate for ET, Inverted Free Energy Effect, Interactions in Polar Media |
|
|
175 | (86) |
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Chapter 6 Unified General Theory of Electron Transfer Reactions |
|
|
261 | (82) |
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Chapter 7 Theory of Electron Transfer Reactions of Solvated Electrons and of Chemiluminescent Electron Transfer Reactions |
|
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343 | (78) |
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Chapter 8 Rate Constants, Barriers, and Brønsted Slopes, Electron Transfer at Electrodes and in Solution: Theory versus Experiment---Electrode Reactions of Organic Compounds |
|
|
421 | (60) |
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Chapter 9 Activated-Complex Theory, Application to Electron Transfer Reactions. Marcus' Notes on Electron Transfer, on Proton Transfer and on Electrode Kinetics |
|
|
481 | (56) |
|
Chapter 10 Unusual Activation Parameters, Electron and Nuclear Tunneling, Mechanisms of Charge Separation, Spin Exchange and Electron Transfer in Photosynthesis; Electron Transfer versus Proton Transfer at Electrodes and in Solution, Hydrogen Evolution, Quantum Effects, Classical and Semiclassical Calculations of Electron Transfer Rates |
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|
537 | (96) |
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Chapter 11 Mixed Reaction-Diffusion Rates, Quantum Effects in the Inverted Region, Frequency Factor in Electron Transfer: Its Role in the Highly Exothermic Regime, Highly Exothermic Electron Transfer, Electron and Proton Transfer, Nonadiabatic Processes, Quantum-like and Classical-like Coordinates, Applications to Nonadiabatic Electron Transfers |
|
|
633 | (120) |
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Chapter 12 Entropic, Electrolyte, and Orientation Effects in Electron Transfer, Electron Transfer in Chemistry and Biology, Application of Electron Transfer to Systems of Biological Interest, Barriers for Thermal and Optical Electron Transfer in Solution, Semiclassical Model for Orientation Effects in Electron Transfer, Orientation Effects on Electron Transfer between Porphyrins |
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753 | (38) |
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Chapter 13 Dynamical Effects in Electron Transfer Reactions, Dielectric Relaxation and Intramolecular Electron Transfer, Solvent Dynamics, and Vibrational Effects in Electron Transfer |
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791 | |
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