Muutke küpsiste eelistusi

Materials Science of DNA [Kõva köide]

Edited by (AFRL/RXPS, Wright Patterson Air Force Base, Ohio, USA), Edited by (Korea University, Seoul, South Korea)
  • Formaat: Hardback, 338 pages, kõrgus x laius: 234x156 mm, kaal: 830 g, 14 Tables, black and white; 16 Illustrations, color; 195 Illustrations, black and white
  • Ilmumisaeg: 12-Dec-2011
  • Kirjastus: CRC Press Inc
  • ISBN-10: 1439827419
  • ISBN-13: 9781439827413
Teised raamatud teemal:
Materials Science of DNASuurem pilt
  • Formaat: Hardback, 338 pages, kõrgus x laius: 234x156 mm, kaal: 830 g, 14 Tables, black and white; 16 Illustrations, color; 195 Illustrations, black and white
  • Ilmumisaeg: 12-Dec-2011
  • Kirjastus: CRC Press Inc
  • ISBN-10: 1439827419
  • ISBN-13: 9781439827413
Teised raamatud teemal:
Püsilink: https://www.kriso.ee/db/9781439827413.html
Märksõnad:
The field of materials science and technology has undergone revolutionary advances due to the development of novel analytical tools, functional materials, and multidisciplinary approaches to engineering. Additionally, theoretical predictions combined with increasingly improved models and computational capabilities are making impressive contributions to the progress of materials science and technology. In particular, the materials science of DNA has emerged as a vital area of research and is expected to immensely broaden the horizon of material science and nanotechnology in this century.

Materials Science of DNA highlights the most important subjects and perspectives in the field, with the aim of stimulating the interdisciplinary community and bringing this intensively interesting, emerging field of molecular-scale materials science to maturation. The editors have not only been involved in the research of materials science of DNA for the past decade, but also lead the series of International Biotronics Workshops supported by the US Air Force Research Laboratory.

Biotechnology and DNA-based biopolymers are not only applicable for genomic sequencing and clinical diagnosis and treatment, but can also have a major impact on nonbiotech applicationssuch as electronics and photonics opening up a whole new field for bioengineering. New concepts and insights gained from DNA research are expected to prove genuinely useful in a variety of devices in nano, micro, and macro dimensions in the future. Where silicon has been the building block of inorganic electronics and photonics, DNA holds promise to become the building block for organic electronics and photonics.
Preface vii
The Editors ix
Contributors xi
Chapter 1 Materials Science of DNA: An Introduction
1(12)
Jung-Il Jin
1.1 Naturally Occurring Organic Polymers
1(1)
1.2 Structures of Nucleic Acids
2(5)
1.3 Materials Science of DNA
7(6)
References
9(4)
Chapter 2 Nanostructures and Nanomaterials via DNA-Based Self-Assembly
13(36)
Yuanqin Zheng
Zhaoxiang Deng
2.1 Introduction
13(2)
2.2 Self-Assembly of DNA Nanostructures
15(15)
2.2.1 One-Dimensional DNA Nanostructures
16(2)
2.2.2 Two-Dimensional DNA Self-Assembly
18(4)
2.2.3 3D Self-Assembly of DNA Polyhedra
22(3)
2.2.4 3D Self-Assembly of Periodical DNA Crystals
25(2)
2.2.5 DNA Origami
27(3)
2.3 DNA-Based Self-Assembly of Nanomaterials
30(11)
2.3.1 DNA-Based Self-Assembly of Gold Nanoparticles in One and Two Dimensions
30(2)
2.3.2 3D Ordering of Gold Nanoparticles with DNA
32(2)
2.3.3 DNA-Based Self-Assembly of Carbon Nanotubes
34(3)
2.3.4 DNA-Based Self-Assembly of Gold-Carbon Hybrid Nanostructures
37(4)
2.3.5 Molecular Lithography
41(1)
2.4 Summary and Outlook
41(8)
Acknowledgments
43(1)
References
43(6)
Chapter 3 Intercalation of Organic Ligands as a Tool to Modify the Properties of DNA
49(28)
Heiko Ihmels
Laura Thomas
3.1 Introduction
49(5)
3.2 Intercalation---General Principles
54(8)
3.2.1 Determination of the Intercalator-DNA Association
55(2)
3.2.2 Thermodynamics
57(3)
3.2.3 Dynamic Aspects of Intercalation
60(2)
3.3 Structural Changes of DNA upon Intercalation
62(15)
References
69(8)
Chapter 4 DNA and Carbon-Based Nanomaterials: Preparation and Properties of Their Composites
77(44)
Thathan Premkumar
Kurt E. Geckeler
4.1 Introduction
77(2)
4.2 Deoxyribonucleic Acid (DNA)
79(1)
4.3 Carbon Nanotubes (CNTs)
80(2)
4.4 DNA-CNT Hybrids
82(20)
4.4.1 Covalent Linkage
83(8)
4.4.2 Encapsulation of DNA in CNTs
91(2)
4.4.3 Noncovalent Interactions Between DNA and CNTs
93(9)
4.5 Graphene (GRP)
102(2)
4.6 DNA-Graphene Hybrids
104(5)
4.7 Advantages and Disadvantages of Synthetic Approaches
109(1)
4.8 Conclusions
110(11)
Acknowledgments
112(1)
References
112(9)
Chapter 5 Electrical and Magnetic Properties of DNA
121(42)
Chang Hoon Lee
Young-Wan Kwon
Jung-Il Jin
5.1 Electrical Properties of DNA
121(13)
5.1.1 Charge Transport in Dry DNA
121(9)
5.1.2 Electrical Conductivity of DNA---A Summary
130(4)
5.2 Magnetic Properties of DNA
134(19)
5.2.1 Historical Recount
134(1)
5.2.2 DNA Magnetism
135(17)
5.2.3 Discotic Liquid Crystals as DNA-Mimicking Compounds
152(1)
5.3 Concluding Remarks
153(10)
References
154(9)
Chapter 6 DNA Ionic Liquid
163(16)
Naomi Nishimura
Hiroyuki Ohno
6.1 Introduction
163(1)
6.2 DNA and Ionic Liquid Mixture
164(1)
6.3 Ionic liquidized DNA-Inner Column
164(6)
6.3.1 Low-Molecular-Weight Model Compounds
165(2)
6.3.2 Ionic liquidized Bases in DNA
167(3)
6.4 Ionic liquidized DNA-Outer Column
170(6)
6.5 Conclusion
176(3)
Acknowledgments
176(1)
References
176(3)
Chapter 7 DNA-Surfactant Thin-Film Processing and Characterization
179(52)
Emily M. Heckman
Carrie M. Bartsch
Perry P. Yaney
Guru Subramanyam
Fahima Ouchen
James G. Grote
7.1 Introduction
180(1)
7.2 DNA Processing
180(5)
7.2.1 Molecular Weight
180(1)
7.2.2 Precipitation with CTMA Surfactant
181(1)
7.2.3 Preparation of DNA-CTMA Films
182(1)
7.2.3.1 Non-Cross-Linked DNA-CTMA Films
182(1)
7.2.3.2 Cross-Linked DNA-CTMA Films
183(1)
7.2.3.3 DNA-CTMA-Chromophore Films
184(1)
7.2.3.4 DNA:PEDOT:CTMA
185(1)
7.3 Material Characterization
185(5)
7.3.1 DNA-CTMA Structure
185(2)
7.3.2 Index of Refraction
187(1)
7.3.3 Optical Loss
187(1)
7.3.3.1 Absorption Loss
187(2)
7.3.3.2 Propagation Loss
189(1)
7.3.4 Thermal Properties
189(1)
7.4 RF Electrical Characterization
190(13)
7.4.1 Capacitive Test Structure
190(4)
7.4.1.1 Experimental Procedure
194(2)
7.4.1.2 Results and Analysis
196(4)
7.4.1.3 Capacitance Measurements
200(1)
7.4.2 Electric Force Microscopy
201(2)
7.5 DC Resistivity Studies
203(28)
7.5.1 Introduction
203(2)
7.5.2 Measurement Technique
205(3)
7.5.3 Data Analysis
208(4)
7.5.4 DATA
212(1)
7.5.4.1 DNA Compared to Nonbiopolymers
212(3)
7.5.4.2 Silk
215(1)
7.5.4.3 Effect of Humidity and Measurement Accuracy
216(2)
7.5.4.4 DNA with Conductive Dopants
218(2)
7.5.4.5 Discussion
220(4)
7.5.5 Summary
224(2)
Acknowledgments
226(1)
References
226(5)
Chapter 8 Applications of DNA to Photonics and Biomedicals
231(24)
Naoya Ogata
8.1 Introduction
231(1)
8.2 Photonic Applications of DNA
232(13)
8.2.1 Stability Improvements of DNA Photonic Devices by Blending with Synthetic Polymers
233(1)
8.2.1.1 Experimentals
233(2)
8.2.1.2 Results and Discussion
235(2)
8.2.2 Chelation of DNA with Novel Metals or Rare Earth Metal Compounds
237(5)
8.2.3 Conclusion
242(3)
8.3 Biomedical Application of DNA Films
245(5)
8.3.1 UV Cross-Linking of DNA Films
245(1)
8.3.2 Cell Culture on DNA Films
246(1)
8.3.3 Wound-Healing Effect of DNA and Cross-Linked DNA Films
247(3)
8.3 Conclusion
250(5)
References
253(2)
Chapter 9 DNA-Based Thin-Film Devices
255(36)
Carrie M. Bartsch
Joshua A. Hagen
Emily M. Heckman
Fahima Ouchen
James G. Grote
9.1 All-DNA-Based Electro-Optic Waveguide Modulator
256(7)
9.1.1 Fabrication
256(1)
9.1.2 Electro-Optic Coefficient
257(2)
9.1.3 Device Testing and Performance
259(3)
9.1.4 Conclusions
262(1)
9.2 Field-Effect Transistors
263(10)
9.2.1 Principles of Operation
263(1)
9.2.2 Polymer FETs
264(1)
9.2.2.1 All-Polymer FETs
265(1)
9.2.2.2 Sensor Applications
265(1)
9.2.3 DNA Biopolymer as the Semiconducting Layer
266(1)
9.2.3.1 Measurement Setup
266(1)
9.2.3.2 Initial Bottom-Gate BioFET
267(4)
9.2.3.3 Improvements to the BioFET
271(2)
9.3 Development of a BioLED: DNA as an Electron-Blocking Layer in Organic Light-Emitting Diodes
273(13)
9.3.1 Materials Used for the Fabrication of BioLEDs
273(1)
9.3.1.1 Emitting Molecules Used in BioLEDs
273(1)
9.3.1.2 Hole Transport Layers Used in BioLEDs
273(1)
9.3.1.3 Hole Blocking Layer Used in BioLEDs
274(1)
9.3.1.2 ETL Used in BioLEDs
274(1)
9.3.1.3 EBL Used in BioLEDs
274(2)
9.3.2 Fabrication of BioLEDs
276(1)
9.3.2.1 Anode Patterning and Deposition
276(1)
9.3.2.2 Solvent-Based Deposition of HTL and EBL
277(1)
9.3.2.3 Molecular Beam Deposition
277(1)
9.3.3 Green (Alq3)-Emitting BioLED Results
278(2)
9.3.4 Comparison of DNA-CTMA to Other Optoelectronic Polymers
280(3)
9.3.5 Lifetime of BioLED and Baseline Devices
283(3)
9.4 Conclusions
286(5)
References
286(5)
Chapter 10 Nucleic Acids-Based Biosensors
291(20)
Sara Tombelli
Ilaria Palchetti
Marco Mascini
10.1 Introduction
291(2)
10.2 DNA-Based Biosensors for Diagnostics
293(4)
10.3 DNA-Based Biosensor for Environmental Application
297(2)
10.4 New Frontiers in Nucleic Biosensors: Aptamer-Based Biosensors
299(12)
References
305(6)
Chapter 11 Materials Science of DNA---Conclusions and Perspectives
311(8)
James G. Grote
Index 319
Jung-Il Jin is a Professor Emeritus, Chemistry Department of Korea University, Seoul, Korea. He is the immediate Past President of International Union of Pure and Applied Chemistry, IUPAC. He is the founding President of the Federation of the Asian Polymer Societies, FAPS. He obtained his Ph.D. in 1969 from the City University of New York (Advisor: Richard H. Wiley) and was a visiting professor at the University of Massachusetts, USA and the University of Cambridge, UK. His research areas have been liquid crystalline and polyconjugated polymers and materials science of DNA. He has published about 400 original research articles and contributed many chapters to various monographs related to functional polymers.

James G. Grote is a Principal Electronics Research Engineer with the Air Force Research Laboratory, Materials and Manufacturing Directorate at Wright-Patterson Air Force Base, Ohio, where he conducts research in polymer and biopolymer based opto-electronics. He is also an adjunct professor at the University of Dayton and University of Cincinnati. Dr. Grote received his BS degree in Electrical Engineering for Ohio University and both his MS and Ph.D. degrees in Electrical Engineering from the University of Dayton, with partial study at the University of California, San Diego. He was a visiting scholar at the Institut dOptique, Universite de Paris, Sud in the summer of 1995 and a visiting scholar at the University of Southern California, the University of California in Los Angeles and the University of Washington in 2001. He received Doctor Honoris Causa from the Politehnica University of Bucharest in 2010. Dr. Grote is an Air Force Research Laboratory Fellow, a Fellow of the International Society for Optics and Photonics (SPIE), a Fellow of the Optical Society of America (OSA), a Fellow of the European Optical Society (EOS) and a Senior Member of the Institute of Electrical and Electronics Engineers (IEEE). He has co-authored more than 130 journal and conference papers, including 2 book chapters, and has served as editor for more than 25 conference proceedings and journal publications.