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Photo-Electrochemical Ammonia Synthesis: Nanocatalyst Discovery, Reactor Design, and Advanced Spectroscopy [Kõva köide]

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  • Formaat: Hardback, 152 pages, kõrgus x laius: 234x156 mm, kaal: 358 g, 12 Tables, black and white; 71 Line drawings, black and white; 13 Halftones, black and white; 84 Illustrations, black and white
  • Sari: Emerging Materials and Technologies
  • Ilmumisaeg: 29-Jul-2021
  • Kirjastus: CRC Press
  • ISBN-10: 0367694379
  • ISBN-13: 9780367694371
Teised raamatud teemal:
Photo-Electrochemical Ammonia Synthesis: Nanocatalyst Discovery, Reactor Design, and Advanced SpectroscopySuurem pilt
  • Formaat: Hardback, 152 pages, kõrgus x laius: 234x156 mm, kaal: 358 g, 12 Tables, black and white; 71 Line drawings, black and white; 13 Halftones, black and white; 84 Illustrations, black and white
  • Sari: Emerging Materials and Technologies
  • Ilmumisaeg: 29-Jul-2021
  • Kirjastus: CRC Press
  • ISBN-10: 0367694379
  • ISBN-13: 9780367694371
Teised raamatud teemal:
Püsilink: https://www.kriso.ee/db/9780367694371.html
Märksõnad:
"This book covers the synthesis of novel hybrid plasmonic nanomaterials and their application in photo-electrochemical systems to convert low energy molecules to high value-added molecules and looks specifically at photo-electrochemical nitrogen reduction reaction (NRR) for ammonia synthesis as an attractive alternative to the long-lasting thermochemical process. This book will be of high interest to researchers, advanced students, and industry professionals in working in sustainable energy storage and conversion across the disciplines of Chemical Engineering, Mechanical Engineering, Materials Science and Engineering, Environmental Engineering, and related areas"--

This book covers the synthesis of novel hybrid plasmonic nanomaterials and their application in photo-electrochemical systems to convert low energy molecules to high value-added molecules and looks at photo-electrochemical nitrogen reduction reaction for ammonia synthesis as an attractive alternative to the long-lasting thermochemical process.

Ammonia holds great promise as a carbon-neutral liquid fuel for storing intermittent renewable energy sources and power generation due to its high energy density and hydrogen content. Photo-Electrochemical Ammonia Synthesis: Nanocatalyst Discovery, Reactor Design, and Advanced Spectroscopy covers the synthesis of novel hybrid plasmonic nanomaterials and their application in photo-electrochemical systems to convert low energy molecules to high value-added molecules and looks specifically at photo-electrochemical nitrogen reduction reaction (NRR) for ammonia synthesis as an attractive alternative to the long-lasting thermochemical process.

  • Provides an integrated scientific framework, combining materials chemistry, photo-electrochemistry, and spectroscopy to overcome the challenges associated with renewable energy storage and transport

  • Reviews materials chemistry for the synthesis of a range of heterogeneous (photo) electrocatalysts including plasmonic and hybrid plasmonic-semiconductor nanostructures for selective and efficient conversion of N2 to NH3

  • Covers novel reactor design to study the redox processes in the photo-electrochemical energy conversion system and to benchmark nanocatalysts’ selectivity and activity toward NRR

  • Discusses the use of advanced spectroscopic techniques to probe the reaction mechanism for ammonia synthesis

  • Offers techno-economic analysis and presents performance targets for the scale-up and commercialization of electrochemical ammonia synthesis

This book is of value to researchers, advanced students, and industry professionals working in sustainable energy storage and conversion across the disciplines of Chemical Engineering, Mechanical Engineering, Materials Science and Engineering, Environmental Engineering, and related areas.

Notes on the Authors vii
Preface ix
Acknowledgements xi
Chapter 1 Ammonia: A Multi-Purpose Chemical
1(8)
1.1 Introduction: Nanocatalysis using Metallic and Semiconductor Nanoparticles
1(2)
1.2 Ammonia as a Medium for Intermittent Renewable Energy Storage
3(3)
1.3 Global Nitrogen Cycle
6(3)
Chapter 2 Conventional Methods for Nitrogen Fixation
9(8)
2.1 Introduction
9(1)
2.2 Natural Nitrogen Fixation
9(3)
2.3 Thermocatalytic Process
12(5)
Chapter 3 Electrocatalytic Nitrogen Reduction Reaction for Ammonia Synthesis
17(44)
3.1 Introduction
17(2)
3.2 Fundamental Understanding of Electrocatalytic N2 Reduction
19(3)
3.3 Lithium Cycling Strategy
22(1)
3.4 Electrocatalytic NRR on Au Plasmonic Nanoparticles
23(10)
3.5 Electrocatalytic NRR using Pore-size Controlled Hollow Bimetallic Au-Ag Nanocages
33(8)
3.6 The Role of Oxidation of Silver in Bimetallic Gold-silver Nanocages on the Electrocatalytic Activity of NRR
41(7)
3.7 Incorporating the Transition Metal into Plasmonic Nanocatalysts
48(13)
Chapter 4 Electrochemical Reactor Design
61(18)
4.1 Introduction
61(1)
4.2 Single Chamber Cell
61(1)
4.3 Two Compartment Cells (H-type Cells)
62(2)
4.4 Membrane Electrode Assembly (MEA)-type Cell
64(1)
4.5 Comparison of Liquid- and Gas-phase Systems for Electrochemical Ammonia Synthesis
65(14)
Chapter 5 Plasma-Enabled Nitrogen Fixation
79(8)
5.1 Introduction
79(1)
5.2 Different Plasma Types for Energy Applications
80(2)
5.3 Plasma-based N2 Fixation
82(5)
Chapter 6 Photocatalytic Nitrogen Fixation
87(18)
6.1 Introduction
87(2)
6.2 Design of Hybrid Photocatalysts
89(2)
6.3 Photocatalytic Efficiency Measurements
91(2)
6.4 Photocatalytic NRR Activities of Hybrid Photocatalysts
93(12)
Chapter 7 Ammonia Detection
105(8)
7.1 Introduction
105(1)
7.2 Nessler's Reagent Method
106(1)
7.3 Indophenol Blue Method
107(1)
7.4 Ion Chromatography
107(1)
7.5 1H Nuclear Magnetic Resonance (NMR) Quantifications
108(2)
7.6 Various Sources of Contamination in NRR Experiments
110(3)
Chapter 8 Reaction Mechanisms for Nitrogen Fixation
113(12)
8.1 Introduction
113(1)
8.2 Sabatier Principle and Scaling Relations
113(1)
8.3 Transition-Metal Catalysts
114(4)
8.4 Ex Situ Characterizations of Catalysts
118(1)
8.5 Operando Surface-Enhanced Raman Spectroscopy (SERS) Measurements
118(4)
8.6 Other In Situ Spectroscopic Techniques
122(3)
Chapter 9 Performance Targets and Opportunities for Green Ammonia Synthesis
125(6)
9.1 Introduction
125(1)
9.2 Market Need
126(3)
9.3 Performance Targets for Green Ammonia Synthesis
129(2)
Chapter 10 Conclusion
131(2)
References 133(18)
Index 151
Mohammadreza Nazemi is a postdoctoral fellow in the School of Chemistry and Biochemistry at the Georgia Institute of Technology (Georgia Tech). He received his Ph.D. from the Woodruff School of Mechanical Engineering at Georgia Tech under the supervision of Prof. Mostafa El-Sayed in May 2020. He received his BS degree (2013) in Aerospace Engineering from the Sharif University of Technology and MS degree (2015) in Mechanical Engineering from Michigan Technological University. His current research focuses on the development and testing of hollow plasmonic nanostructures for photoelectrochemical energy generation. In addition, he is using ultrafast spectroscopy to study the energy transfer in plasmonic nanomaterials and semiconductors.

Mostafa A. El-Sayed is the director of the Laser Dynamics Laboratory, Regents Professor and Julius Brown Chair in the School of Chemistry and Biochemistry at the Georgia Institute of Technology (Georgia Tech). He obtained his Ph.D. from Florida State University in 1959 with Michael Kasha, and after postdoctoral fellowships at Harvard, Yale, and Caltech, he joined the faculty of School of Chemistry and Biochemistry at UCLA in 1961 and Georgia Tech later in 1994. He is currently an elected member of the U.S. National Academy of Science, an elected fellow of the American Academy of Arts and Sciences, former editor-in-chief of the Journal of Physical Chemistry. He is the recipient of several prestigious awards including ACS Priestly medal, Ahmed Zewail prize in molecular sciences, the ACS Irving Langmuir Prize in Chemical Physics, the Glenn T. Seaborg Medal, and the U.S. National Medal of Science. He was included in the top 1% most cited researchers in 2017 and 2018 (web of science).