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Polymer Engineering Science and Viscoelasticity: An Introduction 2nd ed. 2015 [Kõva köide]

  • Formaat: Hardback, 482 pages, kõrgus x laius: 235x155 mm, kaal: 9596 g, 82 Illustrations, color; 184 Illustrations, black and white; XVII, 482 p. 266 illus., 82 illus. in color., 1 Hardback
  • Ilmumisaeg: 24-Jan-2015
  • Kirjastus: Springer-Verlag New York Inc.
  • ISBN-10: 1489974849
  • ISBN-13: 9781489974846
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  • Formaat: Hardback, 482 pages, kõrgus x laius: 235x155 mm, kaal: 9596 g, 82 Illustrations, color; 184 Illustrations, black and white; XVII, 482 p. 266 illus., 82 illus. in color., 1 Hardback
  • Ilmumisaeg: 24-Jan-2015
  • Kirjastus: Springer-Verlag New York Inc.
  • ISBN-10: 1489974849
  • ISBN-13: 9781489974846
This book provides a unified mechanics and materials perspective on polymers: both the mathematics of viscoelasticity theory as well as the physical mechanisms behind polymer deformation processes. Introductory material on fundamental mechanics is included to provide a continuous baseline for readers from all disciplines. Introductory material on the chemical and molecular basis of polymers is also included, which is essential to the understanding of the thermomechanical response. This self-contained text covers the viscoelastic characterization of polymers including constitutive modeling, experimental methods, thermal response, and stress and failure analysis. Example problems are provided within the text as well as at the end of each chapter.

New to this edition:

·         One new chapter on the use of nano-material inclusions for structural polymer applications and applications such as fiber-reinforced polymers and adhesively bonded structures





·         Brings up-to-date polymer production and sales data and equipment and procedures for evaluating polymer characterization and classification

·         The work serves as a comprehensive reference for advanced seniors seeking graduate level courses, first and second year graduate students, and practicing engineers
1 Introduction
1(14)
1.1 Historical Background
1(13)
1.1.1 Relation Between Polymer Science and Mechanics
6(4)
1.1.2 Perspective and Scope of This Text
10(4)
1.2 Review Questions
14(1)
2 Stress and Strain Analysis and Measurement
15(42)
2.1 Some Important and Useful Definitions
15(2)
2.2 Elementary Definitions of Stress, Strain and Material Properties
17(6)
2.3 Typical Stress-Strain Properties
23(4)
2.4 Idealized Stress-Strain Diagrams
27(1)
2.5 Mathematical Definitions of Stress, Strain and Material Characteristics
28(12)
2.6 Principal Stresses
40(2)
2.7 Deviatoric and Dilatational Components of Stress and Strain
42(5)
2.8 Failure (Rupture or Yield) Theories
47(3)
2.9 Atomic Bonding Model for Theoretical Mechanical Properties
50(3)
2.10 Review Questions
53(1)
2.11 Problems
54(3)
3 Characteristics, Applications and Properties of Polymers
57(44)
3.1 General Classification and Types of Polymers
57(6)
3.2 Typical Applications
63(5)
3.3 Mechanical Properties of Polymers
68(10)
3.3.1 Examples of Stress-Strain Behavior of Various Polymers
70(8)
3.4 An Introduction to Polymer Viscoelastic Properties and Characterization
78(9)
3.4.1 Relaxation and Creep Tests
78(4)
3.4.2 Isochronous Modulus Versus Temperature Behavior
82(3)
3.4.3 Isochronous Stress-Strain Behavior: Linearity
85(2)
3.5 Phenomenological Mechanical Models
87(11)
3.5.1 Differential Stress-Strain Relations and Solutions for a Maxwell Fluid
90(5)
3.5.2 Differential Stress-Strain Relations and Solutions for a Kelvin Solid
95(2)
3.5.3 Creep of a Three Parameter Solid and a Four Parameter Fluid
97(1)
3.6 Review Questions
98(1)
3.7 Problems
99(2)
4 Polymerization and Classification
101(68)
4.1 Polymer Bonding
101(4)
4.2 Polymerization
105(4)
4.3 Classification by Bonding Structure Between Chains and Morphology of Chains
109(3)
4.4 Molecular Configurations
112(8)
4.4.1 Isomers
112(3)
4.4.2 Copolymers
115(2)
4.4.3 Molecular Conformations
117(3)
4.5 Random Walk Analysis of Chain End-to-End Distance
120(4)
4.6 Morphology
124(9)
4.7 Molecular Weight
133(8)
4.8 Methods for the Measurement of Molecular Weight
141(7)
4.9 Polymer Synthesis Methods
148(6)
4.10 Spectrography
154(3)
4.11 Microscopes/Microscopy
157(8)
4.12 Review Questions
165(1)
4.13 Problems
166(3)
5 Differential Constitutive Equations
169(42)
5.1 Methods for the Development of Differential Equations for Mechanical Models
170(5)
5.2 A Note on Realistic Creep and Relaxation Testing
175(3)
5.3 Generalized Maxwell and Kelvin Models
178(12)
5.3.1 A Caution on the Use of Generalized Differential Equations
186(1)
5.3.2 Description of Parameters for Various Elementary Mechanical Models
187(3)
5.4 Alfrey's Correspondence Principle
190(1)
5.5 Dynamic Properties: Steady State Oscillation Testing
191(17)
5.5.1 Examples of Storage and Loss Moduli and Damping Ratios
201(4)
5.5.2 Molecular Mechanisms Associated with Dynamic Properties
205(2)
5.5.3 Other Instruments to Determine Dynamic Properties
207(1)
5.6 Review Questions
208(1)
5.7 Problems
209(2)
6 Hereditary Integral Representations of Stress and Strain
211(20)
6.1 Boltzmann Superposition Principle
211(7)
6.2 Linearity
218(1)
6.3 Spectral Representation of Viscoelastic Materials
219(3)
6.4 Interrelations Among Various Viscoelastic Properties
222(7)
6.5 Review Questions
229(1)
6.6 Problems
229(2)
7 Time and Temperature Behavior of Polymers
231(56)
7.1 Effect of Temperature on Viscoelastic Properties of Amorphous Polymers
232(3)
7.2 Development of Time Temperature-Superposition-Principle (TTSP) Master Curves
235(17)
7.2.1 Kinetic Theory of Polymers
238(3)
7.2.2 WLF Equation for the Shift Factor
241(4)
7.2.3 Mathematical Development of the TTSP
245(7)
7.2.4 Potential Error for Lack of Vertical Shift
252(1)
7.3 Exponential Series Representation of Master Curves
252(13)
7.3.1 Numerical Approach to Prony Series Representation
256(5)
7.3.2 Determination of the Relaxation Modulus from a Relaxation Spectrum
261(4)
7.4 Constitutive Law with Effective Time
265(2)
7.5 Molecular Mechanisms Associated with Viscoelastic Response
267(1)
7.6 Entropy Effects and Rubber Elasticity
268(7)
7.7 Physical and Chemical Aging
275(7)
7.8 Review Questions
282(1)
7.9 Problems
282(5)
8 Elementary Viscoelastic Stress Analysis for Bars and Beams
287(24)
8.1 Fundamental Concepts
287(2)
8.2 Analysis of Axially Loaded Bars
289(5)
8.3 Analysis of Circular Cylinder Bars in Torsion
294(2)
8.4 Analysis of Prismatic Beams in Pure Bending
296(5)
8.4.1 Stress Analysis of Beams in Bending
296(1)
8.4.2 Deformation Analysis of Beams in Bending
297(4)
8.5 Stresses and Deformation in Beams for Conditions Other Than Pure Bending
301(8)
8.6 Shear Stresses and Deflections in Beams
309(1)
8.7 Review Questions
309(1)
8.8 Problems
310(1)
9 Viscoelastic Stress Analysis in Two and Three Dimensions
311(28)
9.1 Elastic Stress-Strain Equations
311(2)
9.2 Viscoelastic Stress-Strain Relations
313(2)
9.3 Relationship Between Viscoelastic Moduli (Compliances)
315(1)
9.4 Frequently Encountered Assumptions in Viscoelastic Stress Analysis
316(2)
9.5 General Viscoelastic Correspondence Principle
318(5)
9.5.1 Governing Equations and Solutions for Linear Elasticity
318(2)
9.5.2 Governing Equations and Solutions for Linear Viscoelasticity
320(3)
9.6 Thick Wall Cylinder and Other Problems
323(11)
9.6.1 Elasticity Solution of a Thick Wall Cylinder
323(3)
9.6.2 Elasticity Solution for a Reinforced Thick Wall Cylinder (Solid Propellant Rocket Problem)
326(2)
9.6.3 Viscoelasticity Solution for a Reinforced Thick Wall Cylinder (Solid Propellant Rocket Problem)
328(6)
9.7 Solutions Using Broadband Bulk, Shear and Poisson's Ratio Measured Functions
334(2)
9.8 Review Questions
336(1)
9.9 Problems
336(3)
10 Nonlinear Viscoelasticity
339(40)
10.1 Types of Nonlinearities
339(5)
10.2 Approaches to Nonlinear Viscoelastic Behavior
344(6)
10.3 The Schapery Single-Integral Nonlinear Model
350(20)
10.3.1 Preliminary Considerations
350(3)
10.3.2 The Schapery Equation
353(8)
10.3.3 Determining Material Parameters from a Creep and Creep Recovery Test
361(9)
10.4 Empirical Approach To Time-Stress-Superposition (TSSP)
370(5)
10.5 Review Questions
375(1)
10.6 Problems
376(3)
11 Rate and Time-Dependent Failure: Mechanisms and Predictive Models
379(50)
11.1 Failure Mechanisms in Polymers
380(9)
11.1.1 Atomic Bond Separation Mechanisms
381(3)
11.1.2 Shear Bands
384(3)
11.1.3 Crazing
387(2)
11.2 Rate Dependent Yielding
389(6)
11.3 Delayed or Time Dependent Failure of Polymers
395(32)
11.3.1 A Mathematical Model for Viscoelastic-Plastic Behavior
398(9)
11.3.2 Analytical Approaches to Creep Rupture
407(20)
11.4 Review Questions
427(1)
11.5 Problems
427(2)
Appendix A Step and Singularity Functions 429(4)
Appendix B Transforms 433(4)
Appendix C Durability and Accelerated Life Predictions of Structural Polymers 437(12)
Appendix D Herbert Leaderman: A Master of Polymer Physics and Mechanics 449(6)
References 455(18)
Author Index 473(6)
Subject Index 479
Dr. Hal F. Brinson is Professor Emeritus in the Department of Mechanical Engineering at the University of Houston. Dr. L Catherine Brinson is Professor and Chair of the Department of Mechanical Engineering at Northwestern University.