Foreword |
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xxi | |
Preface |
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xxiii | |
List of Contributors |
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xxvii | |
List of Figures |
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xxxiii | |
List of Tables |
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xliii | |
List of Abbreviations |
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xlvii | |
Module 1 Sustainable Developments |
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1 Reuse and Recycling: An Approach for Sustainable Waste Management |
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3 | (12) |
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4 | (2) |
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1.1.1 Biomass as Feedstock Source |
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4 | (2) |
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1.2 Applications of Nanotechnology in Waste Management |
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6 | (1) |
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1.3 Waste Recycling in India |
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6 | (2) |
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1.4 Advantages of Recycling |
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8 | (3) |
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1.4.1 Briquetting: A Suitable Option for Waste Management |
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10 | (1) |
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11 | (1) |
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11 | (4) |
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2 Sustainability of WEEE Recycling in India |
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15 | (18) |
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16 | (2) |
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18 | (1) |
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2.3 WEEE Lifecycle and Management in India |
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19 | (2) |
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2.3.1 Lifecycle of WEEE in India |
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19 | (1) |
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2.3.2 WEEE Recycling Practices in India |
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20 | (1) |
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2.4 Security Threats from WEEE in India |
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21 | (1) |
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2.5 WEEE Supply Chain in India |
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22 | (1) |
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23 | (1) |
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23 | (1) |
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24 | (1) |
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2.7 Sustainability of WEEE Management System in India |
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24 | (4) |
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2.7.1 Generalized Discussion on Environmental Sustainability |
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25 | (1) |
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2.7.2 Generalized Discussion on Economic Sustainability |
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26 | (1) |
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2.7.3 Generalized Discussion on Social Sustainability |
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27 | (1) |
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28 | (1) |
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29 | (4) |
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3 Autogenous Self-healing in Municipal Waste Incorporated Concretes |
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33 | (24) |
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33 | (3) |
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36 | (4) |
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3.2.1 Materials and Mixture Proportions |
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36 | (3) |
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3.2.2 Specimen Preparation and Initial Pre-loading |
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39 | (1) |
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3.2.3 Methods for Self-healing Evaluation |
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39 | (1) |
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3.3 Results and Discussions |
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40 | (9) |
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3.3.1 Compressive Strength |
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40 | (1) |
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40 | (1) |
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42 | (2) |
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44 | (1) |
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3.3.3 Characterization of the Concrete Specimens |
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45 | (1) |
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45 | (1) |
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47 | (2) |
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49 | (1) |
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50 | (7) |
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4 Burning the Crop Residues: A Major Environmental Problem in Delhi NCR |
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57 | (32) |
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57 | (2) |
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59 | (1) |
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4.3 Crop Residues Burning in North-Western States of India |
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59 | (11) |
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4.4 The Factors Responsible for Burning of the Crop Residues |
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70 | (1) |
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4.5 Consequences of Crop Residues Burning |
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71 | (2) |
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4.6 Alternative Uses of Crop Residues |
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73 | (4) |
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4.7 Government Initiatives and Legislative Policy to Stop Paddy and Wheat Straw Burning |
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77 | (1) |
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78 | (1) |
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79 | (10) |
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5 Waste Electrical and Electronic Equipments, Where Do We Stand and Where to Go: An Indian Scenario |
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89 | (36) |
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90 | (1) |
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91 | (2) |
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5.3 Global Trends in Generation of WEEE |
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93 | (3) |
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5.4 The Digital Revolution and Growth of EEE in India |
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96 | (17) |
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5.4.1 WEEE Generation-An Indian Scenario |
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98 | (4) |
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5.4.2 How much of WEEE Importing into India? |
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102 | (1) |
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5.4.3 Producers of WEEE in India |
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103 | (1) |
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5.4.3.1 First level: primary WEEE producers |
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103 | (1) |
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5.4.3.2 Second level: secondary WEEE producers |
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103 | (1) |
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5.4.3.3 Third level: tertiary WEEE producers |
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105 | (1) |
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5.4.4 Disposal and Recycling Practices of WEEE Products Adopted in India |
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105 | (1) |
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5.4.4.1 Informal recycling and formal recycling |
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106 | (2) |
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5.4.5 Environmental Aspects of WEEE Recycling and Disposal |
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108 | (1) |
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5.4.6 Recycling-based Research Initiated in India and its Major Outcomes |
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109 | (4) |
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5.5 Conclusion and Future Perspectives |
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113 | (1) |
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114 | (11) |
Module 2 Water-Recycle and Reuse |
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6 A Critical Review on Wastewater Treatment Techniques for Reuse of Water in Industries |
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125 | (16) |
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Shanmugasundaram O. Lakshmanan |
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125 | (2) |
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6.2 Importance of Wastewater Treatment |
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127 | (1) |
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6.3 Conventional Wastewater Treatment Techniques and its Drawbacks |
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128 | (1) |
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6.4 Advanced Wastewater Treatment Methods for Water Reuse |
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129 | (3) |
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6.5 Causes and Remedies of Advanced Methods |
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132 | (1) |
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132 | (1) |
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133 | (8) |
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7 Effect of Local Industrial Waste Additives on the Arsenic (V) Removal and Strength of Clay Ceramics for Use in Water Filtration |
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141 | (12) |
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142 | (1) |
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143 | (1) |
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143 | (1) |
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7.2.2 Materials and Fabrication |
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143 | (1) |
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7.2.3 Adsorption Experiment |
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144 | (1) |
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7.3 Result and Discussion |
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144 | (5) |
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7.3.1 Effect of Contact Time |
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144 | (1) |
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7.3.2 Surface Morphology of Ceramics |
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145 | (1) |
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7.3.2.1 Before filtration |
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145 | (1) |
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7.3.2.2 After gravity-based percolation |
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146 | (1) |
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146 | (1) |
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7.3.4 Adsorption Isotherm |
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147 | (1) |
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147 | (2) |
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149 | (1) |
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149 | (4) |
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8 Treatment of Whey Water from Food Processing Units Using Hybrid Methods |
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153 | (20) |
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154 | (1) |
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8.2 Materials and Methods |
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155 | (3) |
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8.2.1 Whey Water Sample Collection and Characterization |
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155 | (1) |
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8.2.2 Treatment of Whey Water using Fenton's Oxidation Method and its Analysis using Ion Chromatography |
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155 | (1) |
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8.2.3 Treatment using Green Algae |
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156 | (1) |
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8.2.3.1 Treatment of whey water using green algae at various nitrate concentrations after Fenton's oxidation |
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156 | (1) |
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8.2.3.2 Estimation of bio-molecules content of spent green algal biomass and its FTIR spectroscopy analysis |
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157 | (1) |
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8.2.4 Treatment of Whey Water using Bacillus Subtilis at Various pH After Fenton's Oxidation |
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157 | (1) |
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8.3 ResultS and Discussion |
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158 | (11) |
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8.3.1 Whey Water Sample Collection and Characterization |
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158 | (1) |
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8.3.2 Treatment of Whey Water using Fenton's Oxidation Method and its Analysis using Ion Chromatography |
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158 | (2) |
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8.3.3 Treatment Using Green Algae |
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160 | (1) |
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8.3.3.1 Treatment of whey water using green algae at various nitrate concentrations after Fenton's oxidation |
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160 | (1) |
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8.3.3.2 Estimation of bio-molecules content of spent green algal biomass and its FTIR spectroscopy analysis |
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162 | (5) |
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8.3.4 Treatment of Whey Water using Bacillus Subtilis After Fenton's Oxidation |
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167 | (2) |
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169 | (1) |
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169 | (4) |
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9 Bioremediation of High-strength Post-methanated Distillery Wastewater at Lab Scale by Using Constructed Wetland Technology |
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173 | (10) |
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174 | (1) |
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9.2 Materials and Methods |
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175 | (1) |
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9.3 Results and Discussion |
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176 | (4) |
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9.3.1 Changes in Quality of PMDW after Treatment in Different CW Microcosms |
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176 | (2) |
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9.3.2 Changes in Leaf Chlorophyll Content of Plants After Treatment in Different CW Microcosms |
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178 | (1) |
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9.3.3 Changes in Fresh Plant Biomass After Treatment in Different CW Microcosms |
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179 | (1) |
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180 | (1) |
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181 | (2) |
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10 Reuse of Magnetite (Fe3O4) Nanoparticles in De-Emulsification of Emulsion Effluents of Steel-rolling Mills |
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183 | (6) |
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184 | (1) |
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184 | (2) |
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10.2.1 Synthesis of Uncoated Fe3O4 Nanoparticles by Co-precipitation Method at Room Temperature |
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184 | (1) |
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10.2.2 Treatment of Emulsion Effluents |
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185 | (1) |
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10.3 Results and Discussion |
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186 | (1) |
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10.3.1 Characterization of Fe3O4 Nanoparticles |
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186 | (1) |
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10.3.2 Total Mass Balance of Oil and Fe3O4 Nanoparticles |
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186 | (1) |
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187 | (1) |
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188 | (1) |
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11 Application of Agro-Residues-Based Activated Carbon as Adsorbents for Phenol Sequestration from Aqueous Streams: A Review |
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189 | (36) |
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190 | (2) |
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11.2 Methods Available for Removal of Phenol |
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192 | (1) |
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11.3 Adsorption as a Cost-Effective Method for Removal of Phenol |
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192 | (2) |
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11.3.1 Quantification of Phenol Adsorbed |
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194 | (1) |
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11.4 Agro-residues as Adsorbents for Phenol |
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194 | (5) |
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194 | (1) |
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195 | (1) |
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195 | (1) |
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196 | (1) |
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11.4.5 Date Stones and Date Pits |
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196 | (1) |
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11.4.6 Oil Palm Empty Fruit Bunches |
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196 | (1) |
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197 | (1) |
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197 | (1) |
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197 | (1) |
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11.4.10 Orange Peel Waste |
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197 | (1) |
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11.4.11 Pistacia Mutica Shells |
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198 | (1) |
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198 | (1) |
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11.4.13 Acacia nilotica Branches |
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198 | (1) |
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11.5 Characterization of Agro-residues-based Adsorbents for Phenol |
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199 | (1) |
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11.6 Thermo-chemical Treatment to Agro-residues to Improve Its Adsorption Characteristics |
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199 | (6) |
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201 | (1) |
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201 | (1) |
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202 | (1) |
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202 | (1) |
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203 | (1) |
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203 | (1) |
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203 | (1) |
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204 | (1) |
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11.6.9 Root Residue of Hemidesmus Indicus |
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204 | (1) |
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11.6.10 Acacia nilotica Branches |
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204 | (1) |
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11.7 Effects of Various Parameters on Adsorption of Phenol |
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205 | (2) |
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11.7.1 Effect of Adsorbent Dosage |
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205 | (1) |
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205 | (1) |
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11.7.3 Effect of Temperature |
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206 | (1) |
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11.7.4 Effect of Initial Phenol Concentration |
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206 | (1) |
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11.7.5 Effect of Contact Time |
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206 | (1) |
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11.8 Mathematical Models for Adsorption Equilibrium Studies |
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207 | (3) |
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11.8.1 Langmuir Isotherm Model |
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207 | (1) |
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11.8.2 Freundlich Isotherm Model |
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208 | (1) |
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11.8.3 Temkin Isotherm Model |
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209 | (1) |
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11.8.4 Dubinin-Radushkevich Isotherm Model |
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209 | (1) |
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11.9 Mathematical Models for the Kinetics of Adsorption |
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210 | (1) |
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11.9.1 Pseudo-first-order Kinetic Model |
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210 | (1) |
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11.9.2 Pseudo-second-order Kinetic Model |
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210 | (1) |
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11.10 Thermodynamics of the Adsorption Process |
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210 | (1) |
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11.11 Regeneration of Adsorbents |
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211 | (1) |
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212 | (1) |
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213 | (12) |
Module 3 Solid Waste Management - New Breakthrough |
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12 Photocatalytic Degradation of Plastic Polymer: A Review |
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225 | (26) |
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225 | (4) |
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12.2 Degradation of Plastic Polymers Using Various Photocatalytic Materials |
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229 | (2) |
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12.3 Solid-Phase Photocatalytic Degradation of Plastic Polymers-Photocatalyst Composites |
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231 | (8) |
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12.3.1 Degradation of PE-Photocatalyst Composites |
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231 | (2) |
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12.3.2 Photocatalytic Degradation of PP-photocatalyst Composites |
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233 | (1) |
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12.3.3 Photocatalytic Degradation of PS-photocatalyst Composites |
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233 | (2) |
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12.3.4 Photocatalytic Degradation of PVC-photocatalyst Composites |
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235 | (1) |
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12.3.5 Photocatalytic Degradation of PAM-photocatalysts Composites |
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236 | (1) |
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12.3.6 Photocatalytic Degradation of other Plastic Polymers |
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237 | (1) |
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12.3.7 Photocatalytic Degradation of Plastic Polymers Using Different Photocatalyst Suspension in Water |
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238 | (1) |
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12.4 Mechanism of Photocatalytic Degradation of Polymers |
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239 | (2) |
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241 | (1) |
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241 | (10) |
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13 Thermo-Mechanical Process Using for Recycling Polystyrene Waste |
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251 | (12) |
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252 | (1) |
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13.2 Plastic Waste Management |
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252 | (1) |
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13.3 Sustainable Manufacturing Process |
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253 | (1) |
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13.4 Thermo-Mechanical Process |
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254 | (1) |
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255 | (1) |
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255 | (1) |
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13.5.2 Production Procedure |
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255 | (1) |
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256 | (4) |
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256 | (1) |
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257 | (1) |
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257 | (1) |
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258 | (1) |
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259 | (1) |
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260 | (1) |
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260 | (3) |
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14 Hydrogen and Methane Production Under Conditions of Dark Fermentation Process with Low Oxygen Concentration |
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263 | (14) |
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263 | (2) |
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14.2 Materials and Methods |
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265 | (1) |
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14.3 Results and Discussion |
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265 | (6) |
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271 | (1) |
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272 | (5) |
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15 Oxidation of Lignin from Wood Dust to Vanillin Using Ionic Liquid Medium and Study of Its Antioxidant Activity |
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277 | (20) |
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278 | (2) |
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280 | (6) |
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280 | (1) |
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15.2.2 Preparation of Ionic Liquid |
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280 | (1) |
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15.2.3 Isolation of Lignin from Wood Dust |
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281 | (1) |
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15.2.4 Oxidation of Isolated Lignin to Vanillin |
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281 | (1) |
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15.2.5 Determination of Antioxidant Activity |
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282 | (1) |
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15.2.5.1 Measurement of DPPH radical scavenging |
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282 | (1) |
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15.2.5.2 Measurement of ABTS radical scavenging |
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283 | (1) |
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15.2.5.3 Measurement of hydroxyl radical scavenging |
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284 | (1) |
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15.2.5.4 Calculation of percentage inhibition |
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286 | (1) |
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15.2.6 Recyclability Test |
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286 | (1) |
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15.3 Results and Discussion |
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286 | (6) |
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15.3.1 Optimum Condition for Isolation of Lignin |
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286 | (1) |
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15.3.2 Optimum Conditions for Oxidation of Lignin to Vanillin |
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287 | (1) |
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15.3.3 Characterization of Vanillin |
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288 | (1) |
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15.3.3.1 Infrared spectrum |
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288 | (1) |
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289 | (1) |
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290 | (1) |
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15.3.4 Determination of Antioxidant Activity |
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290 | (2) |
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292 | (1) |
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293 | (4) |
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16 Thermochemical Recycling of Carbon-Based Solid Waste |
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297 | (16) |
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298 | (1) |
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16.2 Raw Materials and Their Characterization |
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299 | (4) |
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16.2.1 Proximate and Elemental Composition |
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299 | (1) |
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16.2.2 Thermogravimetric Analysis and Kinetics of Thermal Decomposition |
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300 | (2) |
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302 | (1) |
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16.3 Laboratory Scale Pyrolysis and Gasification Units |
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303 | (1) |
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16.4 Catalysts and Their Characterization |
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304 | (1) |
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16.5 Pyrolysis Yields and Products Composition |
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305 | (2) |
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16.6 Gasification Products and Their Composition |
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307 | (1) |
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16.7 Computer-Aided Modeling of Waste Pyrolysis and Gasification |
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308 | (2) |
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310 | (1) |
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310 | (3) |
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17 Fabrication and Characterization of Hair Keratin-Chitosan-Based Porous Scaffolds for Biomedical Application |
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313 | (14) |
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314 | (1) |
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17.2 Materials and Methods |
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315 | (3) |
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315 | (1) |
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17.2.2 Extraction of Human Hair Keratin |
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315 | (1) |
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17.2.3 Preparation of Chitosan-Keratin Blend |
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316 | (1) |
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17.2.4 Characterization of Chitosan-Keratin Scaffolds |
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317 | (1) |
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317 | (1) |
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317 | (1) |
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317 | (1) |
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17.2.4.4 Water solubility test |
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317 | (1) |
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17.2.4.5 Swelling properties test |
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318 | (1) |
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17.2.4.6 Biodegradability assay |
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318 | (1) |
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17.3 Results and Discussion |
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318 | (5) |
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318 | (2) |
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320 | (1) |
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321 | (1) |
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17.3.4 Physical Characterization of Keratin-Chitosan Scaffolds |
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322 | (1) |
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323 | (1) |
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324 | (3) |
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18 Waste Paper: A Potential Source for Cellulose Nanofiber and Bio-nanocomposite Applications |
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327 | (18) |
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328 | (2) |
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330 | (4) |
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18.2.1 Conversion of CNF from Waste Paper |
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330 | (1) |
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18.2.2 NCC from Native and Waste Paper |
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331 | (1) |
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18.2.3 TOCNF from Native and Waste Paper |
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332 | (1) |
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18.2.4 NFC from Native and Waste Paper |
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333 | (1) |
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18.3 Results and Discussion |
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334 | (5) |
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18.3.1 Morphology by TEM, SEM, and AFM |
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334 | (1) |
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18.3.2 Thermal Degradation Properties of Cellulose (TGA, TG-DTA) |
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335 | (2) |
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18.3.3 Crystallinity Index (XRD) |
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337 | (1) |
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18.3.4 Potential Applications of CNFs and NCC from Waste Paper |
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337 | (2) |
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339 | (1) |
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340 | (5) |
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19 Field Evaluation of Plastic Mulch Film for Changes in Its Mechanical Properties and Retrieval Mechanism for Its Reuse Under Onion Crop |
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345 | (12) |
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346 | (1) |
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347 | (2) |
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19.2.1 Development of Manual Mulch Laying and Retrieving Machine |
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347 | (1) |
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19.2.2 Constructional Details of the Machine |
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348 | (1) |
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349 | (1) |
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19.3 Results and Discussion |
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349 | (5) |
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19.3.1 Mechanical Properties of Plastic Mulch with Duration in Field |
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349 | (5) |
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354 | (1) |
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355 | (2) |
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20 Fluoropolymer-Based Tunable Materials for Emerging Applications |
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357 | (42) |
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358 | (1) |
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20.2 Fluoropolymer Based Tunable Materials: Design, Synthesis and Applications |
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359 | (26) |
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20.2.1 Fundamentals and Developments of Controlled Radical (co)Polymerization |
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359 | (2) |
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20.2.2 Controlled Radical Polymerization of Fluoroalkenes |
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361 | (1) |
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20.2.2.1 ITP of fluoroalkenes |
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361 | (1) |
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20.2.2.2 Reversible addition-fragmentation chain transfer/macromolecular design via the interchange of xanthates polymerization of fluoroalkenes |
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361 | (1) |
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20.2.2.3 ATRP of fluoroalkenes |
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362 | (1) |
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20.2.3 Synthesis of 2-(Trifluoromethyl) Acrylic Acid (MAF) and Alkyl 2-(Trifluoromethyl)Acrylates (MAF-Esters) |
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363 | (1) |
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20.2.3.1 Commercial grade MAF and MAF-esters |
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363 | (1) |
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20.2.3.2 Synthesis of non-commercial grade 2-trifluoromethacrylate monomers from MAF and MAF-esters |
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363 | (1) |
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20.2.3.2.1 Mono 2-trifluoromethacrylate monomers |
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363 | (2) |
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20.2.3.3 Synthesis of Bis(2-trifluoromethacrylate) monomers |
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365 | (1) |
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20.2.4 MAF and MAF Derivatives as Precursors of Organic Chemicals |
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365 | (1) |
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20.2.5 Polymerization of MAF and MAF-Esters |
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365 | (1) |
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365 | (1) |
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20.2.5.2 Copolymerizations of MAF and MAF-esters |
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367 | (1) |
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20.2.5.2.1 Radical copolymerization with hydrogenated monomers |
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367 | (1) |
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20.2.5.2.2 Radical copolymerization of MAF and MAF-esters with a-olefins |
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368 | (1) |
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20.2.5.2.3 Radical copolymerization of MAF and MAF-esters with NB |
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368 | (1) |
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20.2.5.2.4 Radical copolymerization of MAF and MAF-esters with VEs |
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368 | (1) |
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20.2.5.2.5 Radical copolymerization of MAF and MAF-esters with MMA |
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369 | (1) |
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20.2.5.2.6 Radical copolymerization of MAF with MAA |
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369 | (1) |
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20.2.5.2.7 Radical copolymerization of VAc and MAF-TBE |
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369 | (1) |
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20.2.5.2.8 Radical copolymerization of fluorinated monomers with MAF and MAF-esters |
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s373 | |
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20.2.5.2.9 Terpolymerization of MAF and MAF-esters with fluorinated monomers |
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378 | (1) |
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20.2.6 Application of Copolymers Containing MAF and MAF-Esters |
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379 | (1) |
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20.2.6.1 Microlithography |
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379 | (1) |
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20.2.6.2 Molecularity imprinted polymers |
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380 | (1) |
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20.2.6.3 Proton exchange membranes for fuel cells |
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380 | (1) |
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20.2.6.4 Polymeric electrolytes for lithium-ion batteries |
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381 | (1) |
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20.2.6.5 Fluoropolymers/silica nanocomposites |
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383 | (1) |
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20.2.6.6 Multi-compartment micelles |
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383 | (1) |
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20.2.6.7 Self-healing network |
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384 | (1) |
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20.2.6.8 Functional coating |
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384 | (1) |
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385 | (1) |
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386 | (13) |
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21 Recycling and Reuse of Metal Catalyst: Silica Immobilized Palladium Complex for C-C Coupling Reaction |
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399 | (14) |
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399 | (2) |
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401 | (1) |
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21.3 Results and Discussion |
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402 | (5) |
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21.3.1 Pd-NHC Complex Catalyzed Suzuki-Miyaura Reaction |
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405 | (1) |
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21.3.1.1 Catalyst screening and base-solvent optimization |
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405 | (2) |
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407 | (1) |
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408 | (5) |
Module 4 RRR Strategy and Atmosphere |
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22 Investigation on Sound Absorber Performance, Insulation Property, and Dielectric Constant of Sugarcane Bagasse |
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413 | (10) |
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414 | (1) |
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22.2 Materials and Methods |
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414 | (2) |
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22.3 Experimental Arrangements |
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416 | (1) |
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22.3.1 Sound Absorption Measurement |
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416 | (1) |
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22.3.2 Measurement of Insulation Property |
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416 | (1) |
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22.3.3 Dielectric Measurement |
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416 | (1) |
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22.4 Results and Discussion |
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417 | (3) |
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420 | (1) |
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421 | (2) |
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23 Synthesis and Characterization of Microwave Absorbed Material from Agricultural Wastes |
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423 | (6) |
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424 | (1) |
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23.2 Theory for Computational Parameter |
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424 | (1) |
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425 | (1) |
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23.3.1 Characterization of the Coconut Fiber and its Composite |
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425 | (1) |
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23.4 Results and Discussion |
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426 | (1) |
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427 | (1) |
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428 | (1) |
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24 Recycling/Purification of Atmospheric Air-CFD Analysis of Flow Through Filters |
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429 | (18) |
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430 | (2) |
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432 | (3) |
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24.3 Results and Discussion |
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435 | (8) |
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24.3.1 Single Filter-Effect of Porosity and Flow Velocity |
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435 | (3) |
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24.3.2 Three-filter Chamber |
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438 | (1) |
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24.3.3 Three-filter Chamber with Divergence |
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439 | (1) |
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24.3.4 Chamber with Fan on Both Sides |
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440 | (1) |
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24.3.5 Three-filter Chamber with Convergence |
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441 | (2) |
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443 | |
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441 | (6) |
Index |
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447 | (4) |
About the Authors |
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451 | (18) |
About the Editors |
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469 | |