New legislation will force synthetic chemists to design syntheses that are fast and highly selective. This book aims to show them how best to exploit the enormous synthetic potential of solid-state reactions. The text is designed as a companion to Dunitz and Buergi's "Structure Correlation". The material is presented in a coherent and didactically sound fashion, making the text useful as an introduction to the field. In addition, owing to the large number of references to the original literature, this book should be a useful reference for the practice-oriented organic chemist.
Part 1 THEORETICAL APPROACH: Potential Energy Calculations of Crystals,
E. Osawa; A Novel Molecular-Dynamics Method to Predict Molecular Crystal
Structures, N. Tajima and T. Hirano. Part 2 PHYSICO-CHEMICAL APPROACH:
Development of a New X-ray Diffractometer (IPDWAS) for Rapid Measurement, N.
Kamiya, I.Tanabe and H. Iwasaki; Reaction Process in Solid State Studies by
High Resolution Electron Spectroscopy, T. Kobayashi, S. Isoda and H. Kurata;
Analysis of Charge Transfer Complex Formation in the Solid State by Penning
Ionization Electron Spectroscopy, S. Masuda; Analysis of Reactive Species by
Time Resolved Infrared Reflection Absorption Spectroscopy, J. Inukai and M.
Ito; Molecular Motion in Clathrate Crystals Analyzed by Solid-state NMR
Method, F. lmashiro; Asymmetric Structure Analysis for Reaction Centres of a
Molecular Crystal and on a Crystal Surface by EXAFS Spectroscopy, K. Asakura,
M. Shirai and Y. Iwasawa; Excitation Energy Transfer Between Metal Complexes
in Solids, T. Otsuka and Y. Kaizu. Part 3 CRYSTALLINE STATE REACTION: Dynamic
Structure Analysis of Crystalline State Reaction, Y. Ohashi, A. Uchida and A.
Sekine; Reversible Intercalation of Guest Molecules in Crystals of Cholic
Acid, M. Miyata and K. Miki; How can Crystalline Environment Provide
Outstanding Chemistry for Diaryl-carbenes or Arylnitrenes, T. Sugawara. Part
4 SOLID-TO-SOLID ORGANIC REACTIONS, F. Toda Part 5 STEREOSELECTIVE SOLID
STATE PHOTOREACTION: Determining Factors of Molecular Arrangement and
Reaction Course in the Crystalline-state Photoreaction of Unsymmetrically
Substituted Diolefins, K. Saigo and M. Hasegawa; Stereoselectivity in
Reactions of Clathrate Crystals, T. Fujiwara; Solid-state Photochromism of
Tetraphenyldihydro-1,3,5-triazine and Related Heterocycles, K. Maeda;
Solid-state Photoracemization and Photoisomerization of Alkyl Cobalt
Complexes, Y. Ohgo and Y. Arai. Part 6 REACTIVITY AND CRYSTAL STRUCTURE:
Packing Effect in Solid-state Polymerization of Diethynylbenzene Derivatives
by Radiation, Y. Kai; High Selective Reaction Deduced by Tunneling Effect in
the Crystalline Environment, T. Miyazaki; Formation of Bimolecular Films and
Crystal Structure, K. Okuyama; Reactivity and Reaction Pathway of the Sulfur
Compounds, F. Iwasaki; Stereoselectivity and Molecular Recognition in Double
Macrocyclic Inclusion Crystals, T. Higuchi and K. Hirotsu; Index.
