Do you need to design syntheses that are
* highly selective
* fast
* enantioselective with quantitative enantiomeric yield?
This book describes in detail how best to exploit the enormous synthetic potential of solid state reactions. Written by leading experts, it provides in-depth information on
* the theoretical and physico-chemical approach to solid state reactions
* solid-to-solid organic reactions
* stereoselective solid state photoreactions
* reactivity and crystal structure
An ideal companion to Dunitz and Burgi's 'Structure Correlation', this book will be highly useful to synthetic organic chemists, stereochemists, crystallographers, and solid-state chemists
Part 1 THEORETICAL APPROACH: Potential Energy Calculations of Crystals,
E. Osawa; A Novel Molecular-Dynamics Method to Predict Molecular Crystal
Structures, N. Tajima and T. Hirano. Part 2 PHYSICO-CHEMICAL APPROACH:
Development of a New X-ray Diffractometer (IPDWAS) for Rapid Measurement, N.
Kamiya, I.Tanabe and H. Iwasaki; Reaction Process in Solid State Studies by
High Resolution Electron Spectroscopy, T. Kobayashi, S. Isoda and H. Kurata;
Analysis of Charge Transfer Complex Formation in the Solid State by Penning
Ionization Electron Spectroscopy, S. Masuda; Analysis of Reactive Species by
Time Resolved Infrared Reflection Absorption Spectroscopy, J. Inukai and M.
Ito; Molecular Motion in Clathrate Crystals Analyzed by Solid-state NMR
Method, F. lmashiro; Asymmetric Structure Analysis for Reaction Centres of a
Molecular Crystal and on a Crystal Surface by EXAFS Spectroscopy, K. Asakura,
M. Shirai and Y. Iwasawa; Excitation Energy Transfer Between Metal Complexes
in Solids, T. Otsuka and Y. Kaizu. Part 3 CRYSTALLINE STATE REACTION: Dynamic
Structure Analysis of Crystalline State Reaction, Y. Ohashi, A. Uchida and A.
Sekine; Reversible Intercalation of Guest Molecules in Crystals of Cholic
Acid, M. Miyata and K. Miki; How can Crystalline Environment Provide
Outstanding Chemistry for Diaryl-carbenes or Arylnitrenes, T. Sugawara. Part
4 SOLID-TO-SOLID ORGANIC REACTIONS, F. Toda Part 5 STEREOSELECTIVE SOLID
STATE PHOTOREACTION: Determining Factors of Molecular Arrangement and
Reaction Course in the Crystalline-state Photoreaction of Unsymmetrically
Substituted Diolefins, K. Saigo and M. Hasegawa; Stereoselectivity in
Reactions of Clathrate Crystals, T. Fujiwara; Solid-state Photochromism of
Tetraphenyldihydro-1,3,5-triazine and Related Heterocycles, K. Maeda;
Solid-state Photoracemization and Photoisomerization of Alkyl Cobalt
Complexes, Y. Ohgo and Y. Arai. Part 6 REACTIVITY AND CRYSTAL STRUCTURE:
Packing Effect in Solid-state Polymerization of Diethynylbenzene Derivatives
by Radiation, Y. Kai; High Selective Reaction Deduced by Tunneling Effect in
the Crystalline Environment, T. Miyazaki; Formation of Bimolecular Films and
Crystal Structure, K. Okuyama; Reactivity and Reaction Pathway of the Sulfur
Compounds, F. Iwasaki; Stereoselectivity and Molecular Recognition in Double
Macrocyclic Inclusion Crystals, T. Higuchi and K. Hirotsu; Index.
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