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Trace Chemical Sensing of Explosives [Kõva köide]

  • Formaat: Hardback, 392 pages, kõrgus x laius x paksus: 241x163x25 mm, kaal: 699 g
  • Ilmumisaeg: 12-Jan-2007
  • Kirjastus: Wiley-Interscience
  • ISBN-10: 0471738395
  • ISBN-13: 9780471738398
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  • Formaat: Hardback, 392 pages, kõrgus x laius x paksus: 241x163x25 mm, kaal: 699 g
  • Ilmumisaeg: 12-Jan-2007
  • Kirjastus: Wiley-Interscience
  • ISBN-10: 0471738395
  • ISBN-13: 9780471738398
Teised raamatud teemal:
Woodfin (a retired system engineer of Sandia National Laboratories) and colleagues describe some of the representative electronic technologies being developed to allow for chemical sensing of explosives molecules (for rather obvious applications). Opening chapters examine some of the technical problems and issues involved with finding and identifying small quantities of explosive materials within a given environment. Three chapters describe field experiences in the detection of trace explosive signature in the marine environment, using ultrasensitive electronic vapor sensors, and in mine hunting by aroma sensing. Remaining chapters describe particular technologies, including explosives detection based on amplifying fluorescence polymers, ion mobility spectrometry, mass spectrometry for security screening of explosives, explosive vapor detection using microcantilever sensors, lab-on-a-chip detection of explosives, nanoscale sensing assemblies using quantum dot-protein bioconjugates, and remote sensing of explosive materials using differential reflection spectrometry. Appendices list organizations involved in searching for hidden explosives and explain acronyms, symbols, and abbreviations. Annotation ©2007 Book News, Inc., Portland, OR (booknews.com)

This timely book covers the most recent developments in the chemical detection of explosives in a variety of environments. Beginning with a broad view of the need for and the potential applications of chemical sensing, the book considers the issue of how to effectively include chemical sensing into systems designed to find hidden explosives devices. Offering a firsthand look at the latest technologies direct from those who are actively developing them, the book features:
  • A look at the history of the field, including the contributions of recent programs
  • A brief explanation of the chemistry of various explosives and differences in the place where they may be detected
  • An introduction to the problems presented by trace element sensing
  • An overview and comparison of the technologies currently being used and developed
  • Case studies of field experiences with chemical sensors
  • A look at the emerging threat of non-traditional explosives

This book is an important reference for explosives engineers, systems engineers involved in the development of related devices, government agencies and NGOs involved in demining efforts, military and law enforcement specialists in mines and explosive ordinance disposal (EOD), as well as environmental scientists and chemists involved in explosives research.

In addition to providing field workers with knowledge that will help them decide where and how to search for explosives using chemical sensors. It will provide them with an understanding of the potential and the limitations of chemical sensing in their search for and identification of dangerous devices.

Foreword xv
Preface xvii
List of Contributors
xxiii
PART I FUNDAMENTAL CONSIDERATIONS
1(130)
Chemical Sensing
3(32)
Ronald L. Woodfin
What Is Chemical Sensing?
3(1)
Types of Sensing Systems
3(1)
Sensing Possibilities
4(2)
Bulk Sensors
4(1)
Trace Sensors
5(1)
Aromas
6(9)
Biosensors
6(4)
Electronic Sensors
10(2)
Other Indirect Methods (Switch of Molecules)
12(1)
Target Possibilities
12(1)
Sensitivity and the Problem of False Positives
13(2)
Configuring an Electronic Trace Sensor
15(3)
Required Elements
16(2)
Integration and Packaging
18(1)
Issue of Concentration
18(17)
Nomenclature
18(5)
Source to Sample
23(1)
Catch, Count, and Release Cycle
23(1)
Sensor Sensitivity Versus Sampling Time
23(3)
The Concentration Gap
26(1)
Sensitivity Comparison
27(5)
References
32(3)
What to Detect?
35(8)
Jimmie C. Oxley
References
41(2)
Dangerous Innovations
43(26)
Kirk Yeager
Introduction
43(1)
Theory of Improvised Explosives
43(2)
History and the Anarchist Literature
45(6)
Fertilizer-Based IEs
51(4)
Ammonium Nitrate IEs
51(3)
Urea Nitrate
54(1)
Peroxide Explosives
55(8)
The Next Wave
63(6)
Improvised Detonators
63(1)
Peroxide Main Charges
64(1)
Fringe Mixtures
65(1)
On the Horizon
66(1)
References
67(2)
Where Should We Look for Explosive Molecules?
69(40)
Ronald L. Woodfin
Introduction
69(2)
Where Did the Molecules Come from and How Did They Get Here?
69(1)
Objects Other Than Buried Landmines
70(1)
Questions That Beg for Answers
70(1)
Source of the Molecules
71(5)
How the Molecules Diffuse or Leak from a Munition
71(2)
Example of Landmines
73(3)
Other Munitions
76(1)
Transport of the Molecules
76(23)
Buried Sources
77(17)
Concentration Estimates from Buried Sources
94(2)
Other Environments
96(1)
Odor Plumes
97(2)
EF&T Implications for Search and Sampling Strategies
99(2)
Sources Buried on Land
99(1)
Sources Producing Plumes
99(2)
Open Questions and Fruitful Areas for Future Research
101(1)
Objects Buried in the Sea Bottom
102(1)
Sampling Plant Material
102(1)
Role of Computer Modeling
102(2)
Soil Transport Models
103(1)
Plume Transport Models
104(1)
Plume Search Models
104(1)
Conclusions
104(5)
References
105(4)
Structure of Turbulent Chemical Plumes
109(22)
Donald R. Webster
Turbulent Mixing
109(2)
Instantaneous Structure
111(4)
Time-Averaged Characteristics
115(3)
Information for Tracking Chemical Odor Plumes
118(7)
Variation of the Plume Structure
125(6)
Acknowledgments
127(1)
References
127(4)
PART II FIELD EXPERIENCE
131(62)
Detection of Trace Explosive Signatures in the Marine Environment
133(18)
Mark Fisher
Matthew Dock
Introduction
133(1)
Overview of Fate and Transport of Explosives Released from UUXO
134(1)
Sampling and Sensing Methodology
135(2)
SeaDog Sensor Configurations
137(6)
Prototype Integrated with a Robotic Crawler Platform
137(2)
Diver-Deployed SeaDog and Initial Integration with the REMUS
139(3)
SeaDog Miniaturization: The SeaPup
142(1)
Results of Sensor Tests Conducted in the Marine Environment
143(5)
Tests of the Sensor Prototype on a Crawler Vehicle
143(2)
Tests of the Diver-Deployed SeaDog Sensor and Initial Integration to the REMUS
145(1)
Tests of the SeaPup Sensor Integrated on the REMUS
146(2)
Conclusions
148(3)
Acknowledgments
149(1)
References
149(2)
Explosives Detection Using Ultrasensitive Electronic Vapor Sensors: Field Experience
151(26)
Mark Fisher
Introduction
151(2)
Relevance of Field Testing To Sensor Development
153(1)
Overview of the Vapor Signatures of Explosives
154(4)
Landmine Detection
158(12)
Introduction to the Mine Problem
158(1)
Discussion of Landmine Chemical Vapor Signatures
159(5)
Landmine Detection Field Test Results
164(6)
Comparison of Fido with Canines Using High-Volume Sampling Methods (REST)
170(2)
Conclusions
172(5)
Acknowledgments
172(1)
References
172(5)
Reflections on Hunting Mines by Aroma Sensing
177(16)
Vernon Joynt
Editor's Note
177(1)
Interview
177(16)
References
192(1)
PART III EXAMPLE SENSING TECHNOLOGIES
193(118)
Explosives Detection Based on Amplifying Fluorescence Polymers
195(16)
Colin Cumming
Introduction
195(6)
AFP Principle of Operation
196(1)
AFP Technology
197(4)
History of AFP and Fido®
201(1)
Fido Sensitivity
201(1)
Fido Performance
202(1)
Performance Limitations
202(1)
Physical Parameters
203(1)
Latest Implementations
203(5)
Maturity of the Fido Technology
208(1)
Funding
208(3)
References
209(2)
Ion Mobility Spectrometry
211(8)
Ronald L. Woodfin
Introduction
211(1)
Brief Description of Principle of Operation
211(3)
Some Recent Developments
214(2)
Some IMS Manufacturers
216(3)
Acknowledgment
217(1)
References
218(1)
Mass Spectrometry for Security Screening of Explosives
219(26)
Jack A. Syage
Karl A. Hanold
Introduction
219(1)
Detection Methods
220(3)
Explosives Trace Detection
220(2)
Sampling Methods
222(1)
Quantitative vs. Screening Analysis
222(1)
Mass Spectrometry
223(8)
Primer
223(3)
QitTOF Mass Spectrometry
226(2)
Mass Spectrometry Versus Ion Mobility Spectrometry
228(2)
Other MS Analyzers Used for Explosives Detection
230(1)
Results
231(3)
Mass Spectral Signatures
231(1)
MS/MS Analysis
232(1)
Limits of Detection
233(1)
Detection Accuracy---A Model
234(6)
False-Positive Analysis
234(2)
Receiver Operator Characteristics (ROC)
236(1)
MS vs. IMS Accuracy
236(4)
Applications
240(2)
Personnel Screening
240(2)
Other Applications
242(1)
Summary and Conclusion
242(3)
Acknowledgments
242(1)
References
243(2)
Explosive Vapor Detection Using Microcantilever Sensors
245(16)
Thomas Thundat
Introduction
245(2)
Modes of Operation and Theory
247(3)
Resonance Frequency
248(1)
Thermal Motions of a Cantilever
249(1)
Thermal Effects---Deflagration
250(1)
Apparatus
250(4)
Cantilevers
250(1)
Excitation Techniques
250(1)
Readout Techniques
250(2)
Selectivity
252(2)
Results and Discussion
254(2)
Deflagration
256(3)
Conclusions
259(2)
Acknowledgments
259(1)
References
259(2)
Lab-On-A-Chip Detection of Explosives
261(24)
Greg E. Collins
Joseph Wang
Christopher A. Tipple
Introduction
261(4)
Lab-on-a-Chip Explosives Detection by Electrochemical Detection
265(6)
Amperometry for Explosives Detection
266(2)
Contactless Conductivity Detection
268(2)
Dual Amperometric/Conductivity Detection for Simultaneous Monitoring of Ionic and Organic Explosives
270(1)
Lab-on-a-Chip Explosives Detection Utilizing Optical Methods
271(6)
Lab-on-a-chip Sampling of Explosives
277(4)
Conclusions
281(4)
Acknowledgments
281(1)
References
281(4)
Nanoscale Sensing Assemblies Using Quantum Dot-Protein Bioconjugates
285(18)
Hedi Mattoussi
Aaron R. Clapp
Igor L. Medintz
Introduction
285(1)
Quantum Dot--Protein Bioconjugates
286(1)
Forster Formalism and Quantum Dots as Energy Donors
287(3)
Quantum Dots as FRET Donors
290(4)
Quantum-Dot-Based FRET Nanosensors
294(2)
Surface-Attached QD--FRET Nanoassemblies
296(4)
Conclusions
300(3)
Acknowledgments
300(1)
References
300(3)
Remote Sensing of Explosive Materials Using Differential Reflection Spectroscopy
303(8)
Rolf E. Hummel
Anna M. Fuller
Claus Schollhorn
Paul H. Holloway
Introduction
303(1)
Differential Reflectometry
304(1)
Results
305(4)
Conclusions
309(2)
Acknowledgments
310(1)
References
310(1)
PART IV SUPPLEMENTARY MATERIAL
311(2)
APPENDIX: ORGANIZATIONS INVOLVED IN SEARCHING FOR HIDDEN EXPLOSIVES
313(12)
Charles O. Schmidt
International and Nongovernmental Organizations
313(2)
Commercial Demining
315(2)
Governments
317(1)
Military Systems
318(1)
Equipment
319(2)
University Research
321(1)
Information/Data Bases and Links
322(1)
Emeritus
323(2)
DEFINITIONS, SYMBOLS AND ABBREVIATIONS
325(6)
Acronyms
325(5)
Symbols and Abbreviations
330(1)
Explosives Definitions 331(2)
Bibliography 333(18)
Index 351


Ronald L. Woodfin, PHD, is a retired systems engineer of Sandia National Laboratories, where he held the title principal member of the technical staff. With special interests in techniques related to mine warfare and humanitarian demining, Woodfin has served on several National Research Council Committees, including the Committee on Review and Evaluation of the Army Non-Stockpile Chemical Material Disposal Program and the Committee for Mine Warfare Assessment of the Naval Studies Board. He also chaired the chemical sensing sessions in the Fifth, Sixth, and Seventh International Symposia on Technology and the Mine Problem.