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Thermodynamics [Pehme köide]

  • Formaat: Paperback / softback, 230 pages, kõrgus x laius: 254x178 mm, kaal: 476 g
  • Ilmumisaeg: 30-Jun-2020
  • Kirjastus: CRC Press
  • ISBN-10: 0367571994
  • ISBN-13: 9780367571993
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  • Formaat: Paperback / softback, 230 pages, kõrgus x laius: 254x178 mm, kaal: 476 g
  • Ilmumisaeg: 30-Jun-2020
  • Kirjastus: CRC Press
  • ISBN-10: 0367571994
  • ISBN-13: 9780367571993
This book provides an accessible yet thorough introduction to thermodynamics, crafted and class-tested over many years of teaching. Suitable for advanced undergraduate and graduate students, this book delivers clear descriptions of how to think about the mathematics and physics involved. The content has been carefully developed in consultation with a large number of instructors, teaching courses worldwide, to ensure wide applicability to modules on thermodynamics. Modern applications of thermodynamics (in physics and related areas) are included throughoutsomething not offered to the same degree by existing texts in the field.





Features:















A sophisticated approach to the subject that is suitable for advanced undergraduate students and above





Modern applications of thermodynamics included throughout





To be followed by volumes on statistical mechanics, which can be used in conjunction with this book on courses which cover both thermodynamics and statistical mechanics

Arvustused

"Hoorah! Professor Luscombe has done a wonderful service to graduate students and younger physicists who find themselves clueless when they encounter a subtlety of thermodynamics because their undergraduate course in "Thermal Physics" raced through thermodynamics to get to statistical mechanics." Prof. Andrew Zangwill, Georgia Institue of Technology

"The subject of thermodynamics is a difficult topic to grasp even by those who use it frequently. This upper-level treatment, Thermodynamics, helps fill in the details that many introductory textbooks do not, and should not, provide. Oftentimes in this subject, as students especially, one is required to press the "I believe" button in order to avoid a lengthy and scattered search required for piecing together the fundamental question in physics, "Why?", regarding the thermodynamic question at hand. This book, on the contrary, compiles many of those answers together in a step-by-step fashion and explains them in modern vernacular. While by no means is this a complete description of thermodynamics, nor does it claim to be, it provides a theoretical background and framework from which thermodynamics originates. For anyone looking to find a textbook that will fill in the gaps of prior teachings and provide the tools for understanding the fundamentals of thermodynamics, this textbook is a phenomenal resource to have available." Blake McCracken, Experimental Physicist

"Luscombes Thermodynamics is an exciting addition to the field. The first thing you notice when opening the book is the engaging writing style. This is a textbook that does not read like a textbook. It makes you feel that the author is speaking with you directly, either one-to-one or in a small seminar. The structure of the book is sound. Its approach is to give equal weight and importance to thermodynamics and statistical mechanics, or put another way, to the macroscopic and microscopic. (As an example of Luscombes engaging style, he refers to this as "the many and the few.") The overarching concept that ties the two together is entropy, and Luscombe makes understanding entropy his central theme. In the process the book covers all that I would find essential in either a thermodynamics or statistical mechanics book. Although Luscombes Thermodynamics is correctly described as "a science of matter that presupposes no knowledge of the constitution of matter," it is not for the faint-hearted. It is placed correctly as an advanced undergraduate or graduate-level textbook. For students in the former category, parts of it will be challenging. However, to his credit Luscombe has included a number of helpful "just in time" mathematical sections to ease the transition to upper-level math. One outstanding feature of Thermodynamics is that it includes additional topics in applied statistics and thermodynamics (in Section II). That is, these topics are not normally covered in a standard textbook in either field (statistical mechanics or thermodynamics), except perhaps in a brief or cursory way. In this section Luscombe has chosen some important topics of current interest, including superconductivity and superfluidity, non-equilibrium thermodynamics, and information theory. It may be asking a bit much to cover all these in a one-semester course, but an instructor can surely pick and choose some topics that are most interesting to students. This is an outstanding bookwell-structured and thorough in its analysis, yet a pleasure to read." Andrew Rex, Professor of Physics, University of Puget Sound

"A refreshing explanation of thermodynamics with many modern developments." Harvey Gould, Research Professor of Physics, Clark University

"The author presents a book gathering the bases of thermodynamics and applications to some physical situations. The book is divided in two main sections and fifteen chapters. It is completed with a reasonable list of references...Each chapter of the book ends with a summary of the main notions which are presented and of the results which are obtained. Each chapter is illustrated with many figures which help the reader to understand the notions which are presented. The book gathers the basic notions of thermodynamics with applications to interesting applications." Alain Brillard, Riedisheim, in Zentralblatt MATH 1400

Preface ix
Section I Thermodynamics Basics (for Advanced Students)
Chapter 1 Concepts of thermodynamics: Equilibrium, energy, and irreversibility
3(22)
1.1 THE MANY AND THE FEW
3(1)
1.2 EQUILIBRIUM AND TIMELESSNESS
4(2)
1.3 EXACT DIFFERENTIALS*
6(1)
1.4 INTERNAL ENERGY: WORK, HEAT, AND BOUNDARIES
7(4)
1.5 EMPIRICAL TEMPERATURE
11(2)
1.6 EQUATION OF STATE FOR GASES
13(1)
1.7 IRREVERSIBILITY: TIME REARS ITS HEAD
14(2)
1.8 CONSTRAINTS AND STATE VARIABLES
16(1)
1.9 THE MANY FACES OF WORK
17(1)
1.10 CYCLIC RELATION*
18(1)
1.1 RESPONSE FUNCTIONS
19(6)
Chapter 2 Second law of thermodynamics: Direction of heat flow
25(8)
2.1 THERMODYNAMICS OF CYCLES: SYSTEM AS A BLACK BOX
25(1)
2.2 CLAUSIUS AND KELVIN STATEMENTS OF THE SECOND LAW
26(2)
2.3 CARNOT THEOREM: UNIQUENESS OF ADIABATS
28(1)
2.4 ABSOLUTE TEMPERATURE
29(4)
Chapter 3 Entropy
33(20)
3.1 CLAUSIUS INEQUALITY
33(1)
3.2 THE BIRTH OF ENTROPY
34(1)
3.3 ENTROPY, IRREVERSIBILITY, AND DISORGANIZATION
35(3)
3.4 OPENING THE BLACK BOX: GIBBSIAN THERMODYNAMICS
38(1)
3.5 CHEMICAL POTENTIAL AND OPEN SYSTEMS
39(1)
3.6 HOMOGENEOUS FUNCTIONS*
39(1)
3.7 EXTENSIVITY OF ENTROPY
40(2)
3.8 GIBBS-DUHEM EQUATION
42(1)
3.9 QUADRATIC FORMS*
43(1)
3.10 STABILITY OF THE EQUILIBRIUM STATE: FLUCTUATIONS
43(6)
3.1 DIRECTION OF FLOW IN THERMODYNAMIC PROCESSES
49(1)
3.12 JACOBIAN DETERMINANTS*
49(4)
Chapter 4 Thermodynamic potentials: The four ways to say energy
53(14)
4.1 CRITERIA FOR EQUILIBRIUM
53(1)
4.2 LEGENDRE TRANSFORMATION*
54(1)
4.3 THE FOUR THERMODYNAMIC POTENTIALS
55(1)
4.4 PHYSICAL INTERPRETATION OF THE POTENTIALS
56(2)
4.5 MAXWELL RELATIONS
58(1)
4.6 GIBBS ENERGY CHEMICAL POTENTIAL, AND OTHER WORK
58(1)
4.7 FREE ENERGY AND DISSIPATED ENERGY
59(1)
4.8 HEAT DEATH OF THE UNIVERSE?
60(2)
4.9 FREE EXPANSION AND THROTTLING
62(5)
Chapter 5 "Thermodynamics of radiation
67(14)
5.1 KIRCHHOFF LAW OF THERMAL RADIATION
67(2)
5.2 THERMODYNAMICS OF BLACK-BODY RADIATION
69(4)
5.3 WIEN'S DISPLACEMENT LAW
73(6)
5.4 COSMIC MICROWAVE BACKGROUND
79(2)
Chapter 6 Phase and chemical equilibrium
81(16)
6.1 LAGRANGE MULTIPLIERS*
81(1)
6.2 PHASE COEXISTENCE
82(5)
6.3 THERMODYNAMICS OF MIXTURES: IDEAL SOLUTIONS
87(2)
6.4 LAW OF MASS ACTION
89(1)
6.5 ELECTROCHEMICAL CELLS
90(2)
6.6 GIBBS-HELMHOLTZ EQUATIONS
92(5)
Chapter 7 Statistical entropy: From micro to macro
97(24)
7.1 ENTROPY AND PROBABILITY
97(3)
7.2 COMBINATORICS: LEARNING TO COUNT*
100(3)
7.3 COARSE-GRAINED DESCRIPTIONS OF A CLASSICAL GAS
103(5)
7.4 SACKUR-TETRODE EQUATION
108(3)
7.5 VOLUME OF A HYPERSPHERE*
111(1)
7.6 LEARNING TO COUNT WITH PHYSICS
111(2)
7.7 GIBBS'S PARADOX, NOT
113(2)
7.8 SUBTLETIES OF ENTROPY
115(6)
Chapter 8 The third law: You can't get to T = 0
121(14)
8.1 ADIABATIC DEMAGNETIZATION
121(3)
8.2 NERNST HEAT THEOREM
124(1)
8.3 OTHER VERSIONS OF THE THIRD LAW
125(2)
8.4 CONSEQUENCES OF THE THIRD LAW
127(1)
8.5 UNATTAINABILITY OF ABSOLUTE ZERO TEMPERATURE
127(2)
8.6 RESIDUAL ENTROPY OF ICE
129(6)
Chapter 9 To this point
135(14)
Section II Additional Topics in Thermodynamics
Chapter 10 Caratheodory formulation of the second law
149(14)
10.1 INTEGRABILITY CONDITIONS AND THERMODYNAMICS
149(8)
10.2 CARATHEODORY THEOREM
157(1)
10.3 CARATHEODORY'S PRINCIPLE AND THE SECOND LAW
158(5)
Chapter 11 Negative absolute temperature
163(8)
11.1 IS NEGATIVE ABSOLUTE TEMPERATURE POSSIBLE?
163(3)
11.2 NEGATIVE ABSOLUTE IS HOTTER THAN POSITIVE ABSOLUTE
166(1)
11.3 NEGATIVE-TEMPERATURE THERMODYNAMICS
167(4)
Chapter 12 Thermodynamics of information
171(16)
12.1 ENTROPY AS MISSING INFORMATION
171(1)
12.2 MAXWELL'S DEMON: A WAY TO BEAT THE SECOND LAW?
172(2)
12.3 DEMISE OF THE DEMON: FLUCTUATIONS AND INFORMATION
174(4)
12.4 IS ENTROPY INFORMATION?
178(5)
12.5 INFORMATION IS PHYSICAL
183(4)
Chapter 13 Black hole thermodynamics
187(8)
13.1 BLACK HOLES AND THERMODYNAMICS
187(2)
13.2 HAWKING RADIATION
189(1)
13.3 ENTROPY AND MISSING INFORMATION
190(2)
13.4 LAWS OF BLACK HOLE THERMODYNAMICS
192(1)
13.5 IS GRAVITY THERMODYNAMICS?
193(2)
Chapter 14 Non-equilibrium thermodynamics
195(14)
14.1 NON-EQUILIBRIUM PROCESSES
196(1)
14.2 ONSAGER THEORY
197(2)
14.3 ENTROPY BALANCE EQUATION
199(6)
14.4 ENTROPY FLOW AND ENTROPY CREATION
205(1)
14.5 THERMOELECTRICITY
206(3)
Chapter 15 Superconductors and superfluids
209(8)
15.1 LONDON THEORY
209(3)
15.2 ROTATING SUPERCONDUCTOR, LONDON MOMENT
212(1)
15.3 TWO-FLUID MODEL
213(2)
15.4 FOUNTAIN EFFECT
215(2)
Epilogue: Where to now? 217(2)
Bibliography 219(6)
Index 225
James H. Luscombe is Professor of Physics at the Naval Postgraduate School in Monterey, California. He received his PhD in Physics from the University of Chicago in 1983. After post-doctoral positions at the University of Toronto and Iowa State University, he joined the Research Laboratory of Texas Instruments, where he worked on the development of nanoelectronic devices, before joining the Naval Postgraduate School in 1994. He was Chair of the Department of Physics between 2003 and 2009. He teaches a wide variety of topics, including general relativity, statistical mechanics, mathematical methods, and quantum computation.