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E-book: Properties of Gases and Liquids, Sixth Edition

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  • Format: PDF+DRM
  • Pub. Date: 10-Feb-2023
  • Publisher: McGraw-Hill Education
  • Language: eng
  • ISBN-13: 9781260116359
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Properties of Gases and Liquids, Sixth EditionLarger Image
  • Format: PDF+DRM
  • Pub. Date: 10-Feb-2023
  • Publisher: McGraw-Hill Education
  • Language: eng
  • ISBN-13: 9781260116359
Other books in subject:

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A thoroughly revised edition of the “must have” chemical engineering reference

This go-to chemical engineering guide provides you with a single source for up-to-date physical data, chemical data, and predictive methods. Fully updated for the latest advances, the book contains hands-on estimation methods for extrapolating and interpolating. New content includes advanced EOSs with correlated and predicted parameters (e.g. SAFT implementations), advanced computational methods, (e.g. molecular simulation), quantum density functional theory (e.g. LCC) and semi-empirical combinations (e.g. COSMO-RS implementations and SPEADMD). This broad review and objective evaluation of wide-ranging methods is essential to progress in the field of thermophysical property prediction and to advancing the fundamentals of chemical process and product design.

The Properties of Gases and Liquids, Sixth Edition provides the latest curated data on over 480 compounds and includes a special section devoted to the interpretation of uncertainty in physical property estimation. Supplemental materials and compilation methods are less committed to hand calculations than in previous editions. Chapter-by-chapter sample calculations are provided throughout.

  • Refreshed throughout to include the latest data and methods
  • Includes computer codes that reproduce the computations in the book
  • Written by a team of recognized chemical engineering experts


Foreword xi
Preface xiii
1 Introduction
1(10)
1.1 Scope
1(1)
1.2 Estimation of Physical Properties
1(1)
1.3 Traditional Estimation Methods
2(3)
1.4 Nontraditional Estimation Methods
5(2)
1.5 Database Development and Method Evaluation
7(2)
1.6 Organization of the Book
9(1)
1.7 References
9(2)
2 Uncertainty
11(24)
2.1 Scope
11(1)
2.2 Introduction: Why Are Uncertainties Important?
11(2)
2.3 Historical Background
13(1)
2.4 Key Documents: The GUM, NIST 1297, and VIM
13(1)
2.5 Uncertainty Assessment for Thermophysical Properties: The GUM Approach
14(2)
2.6 The Uncertainty Budget
16(1)
2.7 Reference Materials and Standard Reference Materials
16(1)
2.8 Challenges for the User of Experimental Data from the Literature
17(2)
2.9 Examples of Common Problems in Articles Reporting Thermophysical Properties
19(3)
2.10 Modern Uncertainty Assessment Procedures (Critical Evaluation)
22(9)
2.11 Summary
31(1)
2.12 Disclaimer
31(1)
2.13 References
31(4)
3 Pure-Component Constants
35(62)
3.1 Scope
35(1)
3.2 Vapor-Liquid Critical Properties
36(30)
3.3 Acentric Factor
66(1)
3.4 Melting and Boiling Points
66(19)
3.5 Discussion of Estimation Methods for Pure Component Constants
85(7)
3.6 Dipole Moments
92(1)
3.7 Availability of Data and Computer Programs
93(1)
3.8 Notation
93(1)
3.9 References
94(3)
4 Thermodynamic Properties of Ideal Gases
97(50)
4.1 Scope and Definitions
97(4)
4.2 Estimation Methods for the Ideal Gas Standard State
101(1)
4.3 Method of Benson
102(5)
4.4 Method of Domalski and Hearing
107(5)
4.5 Modified Joback Method for Ideal Gas Heat Capacity
112(2)
4.6 Quantum Mechanical Methods
114(17)
4.7 Standard State Enthalpy of Formation and Enthalpy of Combustion
131(2)
4.8 Discussion and Recommendations
133(8)
4.9 Notation
141(3)
4.10 References
144(3)
5 Pure Fluid Thermodynamic Properties of the Single Variable Temperature
147(70)
5.1 Scope
147(1)
5.2 Saturated Liquid Density
147(9)
5.3 Theory of Liquid Vapor Pressure and Enthalpy of Vaporization
156(1)
5.4 Theory of Liquid Heat Capacity
157(1)
5.5 Correlating Vapor-Pressure, Enthalpy of Vaporization, and Liquid Heat Capacity Data
158(7)
5.6 Reliable Extrapolation of Vapor Pressure and Thermodynamic Consistency between Vapor Pressure, Enthalpy of Vaporization, and Liquid Heat Capacity
165(3)
5.7 Prediction of Vapor Pressure
168(6)
5.8 Extrapolation and Prediction of Enthalpy of Vaporization of Pure Compounds and Recommendations
174(1)
5.9 Prediction of Liquid Heat Capacity
175(3)
5.10 Discussion and Recommendations for Vapor-Pressure, Enthalpy of Vaporization, and Liquid Heat Capacity Estimation and Correlation
178(2)
5.11 Enthalpy of Melting
180(16)
5.12 Enthalpy of Sublimation
196(3)
5.13 Solid Vapor Pressure (Sublimation Pressure)
199(2)
5.14 Correlation and Estimation of Virial Coefficients
201(7)
5.15 Notation
208(4)
5.16 References
212(5)
6 Thermodynamic Properties of Pure Gases and Liquids
217(70)
6.1 Scope
217(1)
6.2 Introduction to Equations of State
218(1)
6.3 Theory of Equations of State
219(11)
6.4 Fundamental Thermodynamic Relationships for Pure Compounds
230(4)
6.5 Virial Equations of State
234(1)
6.6 Cubic Equations of State
235(4)
6.7 Multiparameter Equations of State
239(4)
6.8 Perturbation Models with Customized Parameters
243(13)
6.9 Perturbation Models with Transferable Parameters
256(11)
6.10 Chemical Theory EOSs
267(3)
6.11 Molecular Simulation Models
270(2)
6.12 Residual Functions for Evaluated Models
272(1)
6.13 Evaluations of Equations of State
273(8)
6.14 Notation
281(1)
6.15 References
282(5)
7 Thermodynamic Properties of Mixtures
287(46)
7.1 Scope
287(1)
7.2 Mixture Properties---General Discussion
288(3)
7.3 Theory of Mixture Modeling
291(3)
7.4 Perturbation Models
294(17)
7.5 Excess Gibbs Energy Mixing Rules
311(4)
7.6 Mixing Rules for Multiparameter EOS
315(3)
7.7 Virial Equations of State for Mixtures
318(4)
7.8 Residual Functions for Evaluated Models
322(2)
7.9 Empirical Correlations for Mixture Properties
324(1)
7.10 Evaluations and Recommendations
324(4)
7.11 Notation
328(2)
7.12 References
330(3)
8 Vapor-Liquid Equilibria in Mixtures
333(84)
8.1 Scope
333(5)
8.2 A Note about the Modeling of Temperature Effects
338(1)
8.3 Thermodynamics of Vapor-Liquid Equilibria
338(1)
8.4 Fugacity of a Pure Liquid
339(1)
8.5 Simplifications in the Vapor-Liquid Equilibrium Relation
340(1)
8.6 Activity Coefficients; Gibbs-Duhem Equation, and Excess Gibbs Energy
341(3)
8.7 Theory of Activity Models
344(19)
8.8 Correlating Low-Pressure Binary Vapor-Liquid Equilibria
363(6)
8.9 Effect of Temperature on Low-Pressure Vapor-Liquid Equilibria
369(1)
8.10 Multicomponent Vapor-Liquid Equilibria at Low Pressure
370(4)
8.11 Predicting Activity Coefficients
374(16)
8.12 Phase Equilibrium with Henry's Law
390(6)
8.13 Vapor-Liquid Equilibria with Equations of State
396(8)
8.14 Evaluations
404(4)
8.15 Concluding Remarks
408(1)
8.16 Acronyms
409(1)
8.17 Notation
410(2)
8.18 References
412(5)
9 Specialized Phase Behavior in Mixtures
417(38)
9.1 Scope
417(1)
9.2 Infinite Dilution Activity Coefficients
418(9)
9.3 Liquid-Liquid Equilibria
427(9)
9.4 Solubilities of Solids in Liquids
436(7)
9.5 Evaluations
443(7)
9.6 Concluding Remarks
450(1)
9.7 Notation New to
Chapter 9
451(1)
9.8 References
452(3)
10 Viscosity
455(90)
10.1 Scope
455(1)
10.2 Definitions of Units of Viscosity
455(1)
10.3 Theory of Gas Transport Properties
456(1)
10.4 Estimation of Low-Pressure Gas Viscosity
457(10)
10.5 Viscosities of Gas Mixtures at Low Pressures
467(12)
10.6 Effect of Pressure on the Viscosity of Pure Gases
479(16)
10.7 Viscosity of Gas Mixtures at High Pressures
495(4)
10.8 Liquid Viscosity
499(3)
10.9 Effect of High Pressure on Liquid Viscosity
502(3)
10.10 Effect of Temperature on Liquid Viscosity
505(1)
10.11 Estimation of Low-Temperature Liquid Viscosity
506(12)
10.12 Estimation of Liquid Viscosity at High Temperatures
518(2)
10.13 Liquid Mixture Viscosity
520(12)
10.14 Notation
532(6)
10.15 References
538(7)
11 Thermal Conductivity
545(60)
11.1 Scope
545(1)
11.2 Theory of Thermal Conductivity
545(2)
11.3 Thermal Conductivities of Polyatomic Gases
547(6)
11.4 Effect of Temperature on the Low-Pressure Thermal Conductivities of Gases
553(1)
11.5 Effect of Pressure on the Thermal Conductivities of Gases
553(9)
11.6 Thermal Conductivities of Low-Pressure Gas Mixtures
562(5)
11.7 Thermal Conductivities of Gas Mixtures at High Pressures
567(7)
11.8 Thermal Conductivities of Liquids
574(1)
11.9 Estimation of the Thermal Conductivities of Pure Liquids
575(8)
11.10 Effect of Temperature on the Thermal Conductivities of Liquids
583(2)
11.11 Effect of Pressure on the Thermal Conductivities of Liquids
585(3)
11.12 Thermal Conductivities of Liquid Mixtures
588(8)
11.13 Notation
596(4)
11.14 References
600(5)
12 Diffusion
605(54)
12.1 Scope
605(1)
12.2 Basic Concepts and Definitions
605(3)
12.3 Progress in Self-Diffusivity Correlation
608(5)
12.4 Diffusion Coefficients for Binary Gas Systems at Low Pressures: Prediction from Theory
613(5)
12.5 Diffusion Coefficients for Binary Gas Systems at Low Pressures: Empirical Correlations
618(2)
12.6 The Effect of Pressure on the Binary Diffusion Coefficients of Gases
620(6)
12.7 The Effect of Temperature on Diffusion in Gases
626(1)
12.8 Diffusion in Multicomponent Gas Mixtures
627(1)
12.9 Diffusion in Liquids: Theory
628(1)
12.10 Estimation of Binary Liquid Diffusion Coefficients at Infinite Dilution
629(10)
12.11 Concentration Dependence of Binary Liquid Diffusion Coefficients
639(5)
12.12 The Effects of Temperature and Pressure on Diffusion in Liquids
644(1)
12.13 Diffusion in Multicomponent Liquid Mixtures
645(3)
12.14 Diffusion in Electrolyte Solutions
648(4)
12.15 Notation
652(2)
12.16 References
654(5)
13 Surface Tension
659(28)
13.1 Scope
659(1)
13.2 Introduction
659(1)
13.3 Estimation of Pure-Liquid Surface Tension
660(9)
13.4 Temperature Dependence of Pure-Liquid Surface Tension
669(2)
13.5 Surface Tensions of Mixtures
671(11)
13.6 Notation
682(3)
13.7 References
685(2)
Appendix A Property Data Bank 687(62)
Appendix B Lennard-Jones Potentials as Determined from Viscosity Data 749(4)
Index 753
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