Preface |
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xvii | |
Acknowledgments |
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xix | |
Authors |
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xxi | |
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1 | (18) |
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1 | (3) |
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1.1.1 General Composition |
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1 | (3) |
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4 | (1) |
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4 | (6) |
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5 | (1) |
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1.2.2 Terrestrial Thermal Radiation |
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6 | (1) |
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6 | (1) |
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1.2.4 Surface Temperatures |
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7 | (1) |
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1.2.5 Vertical Temperature Gradients |
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7 | (2) |
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9 | (1) |
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1.2.7 Atmospheric Density |
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9 | (1) |
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1.2.8 Atmospheric Pressure |
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9 | (1) |
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10 | (5) |
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11 | (1) |
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1.3.2 Pressure Gradient Force |
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11 | (1) |
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11 | (1) |
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12 | (1) |
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1.3.5 Cyclones and Anticyclones |
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12 | (2) |
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1.3.6 General Circulation of the Atmosphere |
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14 | (1) |
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1.4 Evolution of the Atmosphere |
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15 | (4) |
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17 | (1) |
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17 | (2) |
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Chapter 2 Atmospheric Pollution and Pollutants |
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19 | (44) |
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2.1 Natural Air Pollution |
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19 | (1) |
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2.2 Anthropogenic Air Pollution |
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20 | (7) |
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22 | (1) |
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23 | (1) |
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2.2.3 Nontraditional Air Pollutants |
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23 | (1) |
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2.2.4 Gases and Particles |
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24 | (1) |
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24 | (1) |
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2.2.4.2 National Emission Estimates |
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24 | (2) |
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2.2.4.3 National Emissions Picture |
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26 | (1) |
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27 | (24) |
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28 | (1) |
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28 | (3) |
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31 | (3) |
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34 | (1) |
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34 | (1) |
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2.3.2.2 Reduced Sulfur Compounds |
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35 | (1) |
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36 | (1) |
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36 | (1) |
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37 | (1) |
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37 | (1) |
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38 | (1) |
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39 | (1) |
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39 | (1) |
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2.3.3.7 Organic Nitrate Compounds |
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39 | (1) |
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2.3.4 Hydrocarbon Compounds |
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40 | (1) |
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2.3.4.1 Hydrocarbon Chemistry |
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40 | (1) |
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41 | (1) |
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2.3.4.3 Nonmethane Hydrocarbons |
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42 | (3) |
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45 | (1) |
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2.3.4.5 Halogenated Hydrocarbons |
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46 | (1) |
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2.3.5 Photochemical Oxidants |
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47 | (2) |
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2.3.5.1 Tropospheric Ozone Concentrations |
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49 | (1) |
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50 | (1) |
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2.4 Atmospheric Particles |
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51 | (12) |
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2.4.1 Classes and Sources |
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51 | (1) |
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51 | (3) |
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54 | (1) |
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2.4.4 Chemical Composition |
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54 | (3) |
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2.4.5 Source Apportionment |
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57 | (1) |
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57 | (1) |
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58 | (1) |
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2.4.8 Long-Range Transport from Sources outside the United States |
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59 | (1) |
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60 | (1) |
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60 | (1) |
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61 | (2) |
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Chapter 3 Atmospheric Dispersion, Transport, and Deposition |
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63 | (18) |
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3.1 Dispersion and Transport |
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63 | (13) |
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64 | (1) |
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65 | (1) |
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3.1.3 Atmospheric Stability |
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66 | (1) |
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67 | (1) |
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3.1.4.1 Radiational Inversions |
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68 | (1) |
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3.1.4.2 Subsidence Inversions |
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69 | (1) |
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70 | (1) |
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71 | (1) |
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3.1.7 Pollutant Dispersion from Point Sources |
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71 | (1) |
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3.1.7.1 Pollutants and Diffusion |
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72 | (1) |
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3.1.7.2 Plume Rise and Transport |
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72 | (1) |
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3.1.7.3 Plume Characteristics |
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73 | (1) |
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3.1.8 Large-Scale Transport and Dispersion |
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74 | (1) |
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3.1.8.1 Long-Range Transport |
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74 | (1) |
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74 | (1) |
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3.1.8.3 Planetary Transport |
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74 | (1) |
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3.1.9 Stratosphere-Troposphere Exchange |
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74 | (1) |
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3.1.10 Stratospheric Circulation |
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75 | (1) |
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3.2 Atmospheric Removal and Deposition Processes |
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76 | (1) |
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3.2.1 Atmospheric Lifetimes |
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76 | (1) |
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3.2.2 Deposition Processes |
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77 | (1) |
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3.3 Meteorological Applications: Air Pollution Control |
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77 | (4) |
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78 | (1) |
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3.3.2 Air Quality Modeling |
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78 | (1) |
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78 | (1) |
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79 | (2) |
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Chapter 4 Atmospheric Effects |
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81 | (42) |
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81 | (8) |
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4.1.1 Natural Visibility Reduction |
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81 | (1) |
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4.1.2 Visibility Concerns Associated with Human Activities |
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82 | (1) |
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82 | (1) |
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82 | (1) |
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82 | (1) |
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83 | (1) |
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83 | (1) |
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4.1.3 Factors Affecting Visibility Reduction |
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84 | (2) |
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4.1.4 Meteorological Effects |
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86 | (1) |
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4.1.5 Visibility Measurements |
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87 | (1) |
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4.1.6 Visibility Patterns and Trends |
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88 | (1) |
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89 | (1) |
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4.3 Thermal Air Pollution |
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89 | (2) |
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4.4 Effects on Precipitation and Precipitation Processes |
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91 | (1) |
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4.5 Atmospheric Deposition |
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91 | (7) |
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92 | (1) |
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4.5.1.1 Characteristics of the Phenomenon |
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92 | (2) |
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4.5.1.2 Environmental Impacts |
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94 | (1) |
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4.5.1.3 Trends in Sulfate and Acidic Deposition |
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95 | (1) |
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4.5.2 Nitrogen Deposition |
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95 | (1) |
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96 | (1) |
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4.5.4 Deposition of Pesticides, PCBs, Dioxins, and Furans |
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97 | (1) |
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4.6 Stratospheric Ozone Depletion |
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98 | (10) |
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4.6.1 Ozone Depletion Concerns |
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98 | (1) |
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4.6.2 Ozone Layer Dynamics |
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99 | (1) |
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4.6.3 Role of Nitrogen Oxides |
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99 | (1) |
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4.6.4 Role of Chlorofluorocarbons and Other Halogenated Hydrocarbons |
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100 | (2) |
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4.6.5 Antarctic Ozone Hole |
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102 | (3) |
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4.6.6 Ozone Depletion in the Arctic |
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105 | (1) |
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105 | (1) |
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4.6.8 Changes in Surface UV Light Radiation |
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106 | (1) |
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4.6.9 Ozone Depletion Effects on Human Health |
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106 | (1) |
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4.6.10 Recovery of the Ozone Layer |
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107 | (1) |
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108 | (15) |
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4.7.1 Climate and Global Climate |
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108 | (1) |
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4.7.1.1 Orbital Changes and Climatic Variation |
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108 | (2) |
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4.7.1.2 Variations in Solar Radiation |
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110 | (1) |
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4.7.2 Greenhouse Effect and Global Warming |
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110 | (1) |
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111 | (1) |
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111 | (2) |
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4.7.5 Evidence of Climate Change |
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113 | (3) |
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4.7.6 Linking Climate Change to Anthropogenic Influences |
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116 | (1) |
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4.7.7 Projections of the Earth's Future Climate |
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116 | (1) |
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4.7.8 Global Warming Uncertainties |
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117 | (1) |
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4.7.9 Environmental Impacts |
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118 | (1) |
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4.7.10 Stratospheric Gases and Atmospheric Temperature Changes |
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118 | (1) |
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118 | (1) |
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119 | (1) |
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120 | (3) |
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123 | (34) |
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5.1 Air Pollution Episodes |
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123 | (1) |
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5.2 Pollutant Exposures and Cause-Effect Relationships |
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123 | (6) |
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5.2.1 Epidemiological Studies |
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124 | (1) |
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5.2.1.1 Confounding Factors |
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124 | (1) |
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5.2.1.2 Interaction Effects |
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125 | (1) |
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5.2.1.3 Exposure Assessment |
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126 | (1) |
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5.2.1.4 Population Susceptibility |
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126 | (1) |
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5.2.2 Toxicological Studies |
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127 | (1) |
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127 | (1) |
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128 | (1) |
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5.2.3 Occupational Exposure Studies |
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128 | (1) |
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5.3 Effect of Pollutants on the Human Body |
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129 | (5) |
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129 | (1) |
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5.3.2 Effects on the Cardiovascular System |
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129 | (1) |
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5.3.3 Effects on the Respiratory System |
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130 | (1) |
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5.3.3.1 Un its of the Respiratory System |
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130 | (1) |
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5.3.3.2 Defense Mechanisms of the Respiratory System |
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131 | (1) |
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5.3.3.3 Air Pollution and Respiratory Disease |
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132 | (2) |
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5.4 Health Effects of Regulated Air Pollutants |
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134 | (16) |
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135 | (2) |
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137 | (1) |
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137 | (1) |
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138 | (1) |
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139 | (3) |
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142 | (1) |
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143 | (1) |
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144 | (3) |
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147 | (3) |
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5.4.8 Hazardous Air Pollutants |
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150 | (1) |
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5.5 Personal Air Pollution |
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150 | (1) |
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5.6 Risk Assessment and Management |
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151 | (6) |
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154 | (1) |
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155 | (2) |
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Chapter 6 Wei fare Effect |
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157 | (26) |
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6.1 Effects on Agricultural Crops, Ornamental Plants, and Trees |
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157 | (9) |
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158 | (1) |
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159 | (1) |
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159 | (1) |
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6.1.1.3 Peroxyacyl Nitrate |
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160 | (1) |
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161 | (1) |
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161 | (1) |
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6.1.1.6 Acidic Deposition |
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162 | (1) |
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6.1.1.7 Interaction Effects |
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162 | (1) |
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163 | (1) |
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164 | (1) |
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164 | (1) |
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6.1.3.2 Eastern White Pine |
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164 | (1) |
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6.1.3.3 Red Spruce and Fraser Fir |
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164 | (1) |
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6.1.3.4 Pines in the Southeast |
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165 | (1) |
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6.1.3.5 Hardwoods in the Northeast |
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165 | (1) |
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6.1.3.6 Declines in Central Europe |
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165 | (1) |
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6.2 Effects on Domesticated Animals |
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166 | (1) |
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166 | (1) |
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167 | (1) |
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6.2.3 Other Toxic Exposures |
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167 | (1) |
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167 | (8) |
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6.3.1 Phytotoxic Pollutants |
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168 | (1) |
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6.3.2 Atmospheric Deposition |
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168 | (1) |
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6.3.2.1 Acidic Deposition |
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168 | (2) |
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170 | (1) |
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6.3.2.3 Mercury and Other Trace Metals |
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171 | (1) |
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6.3.2.4 Organochlorine Compounds |
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172 | (1) |
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6.3.3 Stratospheric Ozone Depletion |
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173 | (1) |
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173 | (1) |
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173 | (1) |
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174 | (1) |
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6.3.4.3 Plant and Animal Communities |
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174 | (1) |
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175 | (4) |
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175 | (1) |
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176 | (1) |
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177 | (1) |
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6.4.4 Textiles and Textile Dyes |
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178 | (1) |
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178 | (1) |
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178 | (1) |
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179 | (1) |
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179 | (1) |
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179 | (4) |
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179 | (2) |
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181 | (1) |
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181 | (1) |
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181 | (1) |
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182 | (1) |
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Chapter 7 Air Quality and Emissions Assessment |
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183 | (34) |
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7.1 Air Quality Monitoring |
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183 | (18) |
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7.1.1 Monitoring Considerations |
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184 | (1) |
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184 | (1) |
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184 | (1) |
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7.1.1.3 Sampling Techniques |
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185 | (3) |
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7.1.2 Reporting Pollutant Concentrations |
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188 | (2) |
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7.1.2.1 Accuracy, Precision, and Bias |
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190 | (2) |
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192 | (1) |
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7.1.3 Federal Monitoring Requirements |
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193 | (1) |
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7.1.3.1 Air Quality Monitoring Networks |
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193 | (1) |
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7.1.3.2 Federal Reference Methods |
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194 | (3) |
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7.1.3.3 Quality Assurance Programs |
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197 | (1) |
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7.1.3.4 Data Summarization and Characterization |
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197 | (3) |
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7.1.3.5 Air Quality Index |
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200 | (1) |
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201 | (5) |
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7.2.1 Source Sampling and Monitoring |
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202 | (1) |
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203 | (1) |
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203 | (3) |
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206 | (11) |
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207 | (5) |
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7.3.2 Photochemical Models |
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212 | (1) |
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213 | (1) |
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214 | (1) |
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214 | (3) |
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Chapter 8 Regulation and Public Policy |
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217 | (42) |
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8.1 Nonregulatory Legal Remedies |
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217 | (1) |
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218 | (1) |
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218 | (1) |
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8.2 Regulatory Strategies and Tactics |
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218 | (5) |
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218 | (1) |
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8.2.1.1 Air Quality Management |
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218 | (1) |
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8.2.1.2 Emission Standards |
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219 | (1) |
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8.2.1.3 Economics-Based Approaches |
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220 | (3) |
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223 | (1) |
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8.3 Federal Legislative History |
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223 | (2) |
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8.3.1 1955 Clean Air Legislation |
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223 | (1) |
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223 | (1) |
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8.3.3 Motor Vehicle Air Pollution Control Act |
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224 | (1) |
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8.3.4 Air Quality Act of 1967 |
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224 | (1) |
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8.3.5 1970 Clean Air Act Amendments |
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224 | (1) |
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8.3.6 1977 Clean Air Act Amendments |
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225 | (1) |
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8.3.7 1990 Clean Air Act Amendments |
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225 | (1) |
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225 | (1) |
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8.4 Air Pollution Control under the 1970, 1977, and 1990 CAA Amendments |
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225 | (22) |
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8.4.1 Air Quality Standards |
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225 | (1) |
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8.4.2 Air Quality Criteria |
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226 | (1) |
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8.4.3 Air Quality Control Regions |
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226 | (1) |
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8.4.4 State Implementation Plans |
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226 | (2) |
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228 | (1) |
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228 | (1) |
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8.4.4.3 State Implementation Plan Approval |
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228 | (1) |
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8.4.5 Nonattainment of Air Quality Standards |
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229 | (1) |
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8.4.6 New Source Performance Standards |
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229 | (3) |
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8.4.7 Prevention of Significant Deterioration |
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232 | (1) |
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8.4.8 Hazardous and Toxic Air Pollutants |
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233 | (2) |
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8.4.9 Stratospheric Ozone Depletion |
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235 | (1) |
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235 | (1) |
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8.4.11 Motor Vehicle Emission Control |
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236 | (1) |
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8.4.11.1 Vehicle Emissions |
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236 | (1) |
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8.4.11.2 Regulatory History |
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237 | (1) |
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8.4.11.3 Exhaust Gas Standards |
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238 | (3) |
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8.4.11.4 Fuel Additives and Cleaner Fuels |
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241 | (1) |
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8.4.11.5 Emission Test Cycles |
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242 | (1) |
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8.4.11.6 Inspection and Maintenance |
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243 | (1) |
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8.4.11.7 Tampering Prohibitions |
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243 | (1) |
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8.4.11.8 Evaporative Controls and Onboard Vapor Recovery Systems |
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243 | (1) |
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8.4.11.9 Clean-Fuel Vehicles |
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244 | (1) |
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244 | (1) |
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245 | (1) |
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8.4.13 Permit Requirements |
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245 | (1) |
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246 | (1) |
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8.4.15 Pollution Prevention |
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246 | (1) |
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8.5 State and Local Air Pollution Control Functions |
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247 | (1) |
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8.5.1 Boards and Agencies |
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247 | (1) |
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8.5.2 Effectiveness of State and Local Programs |
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248 | (1) |
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248 | (11) |
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248 | (1) |
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8.6.2 Global Climate Change, the Kyoto Protocol, and the Paris Agreement |
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249 | (2) |
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8.6.3 CAFE and Greenhouse Gas Emission Standards |
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251 | (3) |
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254 | (2) |
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256 | (3) |
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Chapter 9 Control of Motor Vehicle Emissions |
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259 | (18) |
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9.1 Motor Vehicle Engines |
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260 | (10) |
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9.1.1 Otto Cycle Spark Ignition Engines |
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260 | (1) |
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9.1.1.1 Engine Characteristics |
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260 | (2) |
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262 | (1) |
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9.1.1.3 Formation of Combustion Pollutants |
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262 | (2) |
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9.1.1.4 Emission Control Techniques and Systems |
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264 | (5) |
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9.1.2 Compression Ignition Engines |
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269 | (1) |
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270 | (3) |
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270 | (1) |
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271 | (1) |
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9.2.1.2 Gasoline Composition and Emissions |
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271 | (1) |
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272 | (1) |
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272 | (1) |
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9.2.2.2 Compressed and Liquefied Gases |
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272 | (1) |
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9.3 Low-Emission and Zero-Emission Vehicles |
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273 | (4) |
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9.3.1 Low-Emission Vehicles |
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273 | (1) |
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9.3.2 Hybrid Electric Vehicles |
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273 | (2) |
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275 | (1) |
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275 | (1) |
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276 | (1) |
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Chapter 10 Control of Emissions from Stationary Sources |
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277 | (30) |
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277 | (4) |
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277 | (1) |
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277 | (2) |
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10.1.3 Fugitive Emissions |
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279 | (1) |
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10.1.4 Pollution Prevention |
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279 | (1) |
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279 | (1) |
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10.1.4.2 Process Equipment Changes |
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280 | (1) |
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10.1.4.3 Plant Operating Practices |
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280 | (1) |
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280 | (1) |
|
|
280 | (1) |
|
10.1.4.6 Energy Conservation |
|
|
280 | (1) |
|
10.2 Gas Cleaning Technology |
|
|
281 | (2) |
|
10.2.1 System Performance |
|
|
281 | (1) |
|
10.2.2 Particle Collection Efficiency |
|
|
281 | (1) |
|
10.2.3 Gas-Phase Contaminant Collection Efficiency |
|
|
282 | (1) |
|
10.3 Control of Particulate-Phase Pollutants |
|
|
283 | (6) |
|
10.3.1 Cyclonic Collectors |
|
|
283 | (1) |
|
10.3.2 Electrostatic Precipitation |
|
|
284 | (2) |
|
|
286 | (1) |
|
|
286 | (1) |
|
|
287 | (2) |
|
10.4 Control of Gas-Phase Pollutants |
|
|
289 | (18) |
|
|
289 | (1) |
|
|
289 | (1) |
|
10.4.1.2 Conventional Oxidizers |
|
|
290 | (1) |
|
10.4.1.3 Catalytic Oxidation |
|
|
290 | (1) |
|
10.4.1.4 Operating Considerations |
|
|
291 | (1) |
|
|
291 | (2) |
|
|
293 | (1) |
|
10.4.4 Control of Sulfur Oxides |
|
|
294 | (1) |
|
10.4.4.1 Coal Beneficiation |
|
|
295 | (1) |
|
10.4.4.2 Solvent Refining |
|
|
295 | (1) |
|
10.4.4.3 Coal Gasification |
|
|
295 | (1) |
|
10.4.4.4 Flue Gas Desulfurization |
|
|
296 | (2) |
|
10.4.5 Fluidized Beds and FBC |
|
|
298 | (1) |
|
10.4.6 Biological Treatment |
|
|
298 | (1) |
|
10.4.7 Control of Nitrogen Oxides |
|
|
299 | (2) |
|
10.4.8 Control of Carbon Dioxide |
|
|
301 | (1) |
|
10.4.8.1 Carbon Capture and Storage |
|
|
301 | (2) |
|
10.4.8.2 Other Carbon Dioxide Capture Technologies |
|
|
303 | (1) |
|
|
304 | (1) |
|
|
305 | (2) |
|
Chapter 11 Indoor Air Quality |
|
|
307 | (36) |
|
11.1 Personal, Indoor, and Outdoor Pollutant Relationships |
|
|
307 | (2) |
|
11.1.1 Personal Pollutant Exposures |
|
|
307 | (1) |
|
11.1.2 Indoor and Outdoor Pollutant Concentrations |
|
|
308 | (1) |
|
11.2 Indoor Air Quality Concerns |
|
|
309 | (1) |
|
11.3 Major Indoor Pollutants |
|
|
309 | (21) |
|
|
310 | (1) |
|
|
311 | (1) |
|
11.3.2.1 Concentrations and Sources |
|
|
311 | (1) |
|
11.3.2.2 Health Effects and Risks |
|
|
312 | (2) |
|
11.3.3 Combustion By-Products |
|
|
314 | (1) |
|
11.3.3.1 Unvented Combustion Systems |
|
|
314 | (3) |
|
11.3.3.2 Vented Combustion Systems |
|
|
317 | (1) |
|
11.3.3.3 Miscellaneous Sources |
|
|
318 | (3) |
|
|
321 | (1) |
|
|
322 | (1) |
|
|
323 | (1) |
|
|
323 | (1) |
|
11.3.5 Volatile and Semivolatile Organic Compounds |
|
|
323 | (1) |
|
11.3.5.1 Volatile Organic Compounds |
|
|
323 | (2) |
|
11.3.5.2 Semivolatile Organic Compounds |
|
|
325 | (2) |
|
11.3.6 Biological Contaminants |
|
|
327 | (1) |
|
11.3.6.1 Illness Syndromes |
|
|
327 | (2) |
|
11.3.6.2 Other Health Concerns |
|
|
329 | (1) |
|
|
330 | (3) |
|
11.4.1 Building-Related Illness |
|
|
330 | (1) |
|
11.4.2 Sick Building Syndrome |
|
|
330 | (1) |
|
11.4.3 Field Investigations and Systematic Building Studies |
|
|
331 | (1) |
|
|
331 | (2) |
|
11.5 Investigating Indoor Air Quality Problems |
|
|
333 | (2) |
|
11.6 Measurement of Indoor Contaminants |
|
|
335 | (1) |
|
11.7 Prevention and Control Measures |
|
|
335 | (4) |
|
|
335 | (1) |
|
|
335 | (1) |
|
|
335 | (1) |
|
11.7.1.3 Source Treatment |
|
|
336 | (1) |
|
11.7.2 Contaminant Control |
|
|
336 | (1) |
|
|
336 | (1) |
|
|
337 | (2) |
|
11.8 Indoor Air Quality and Public Policy |
|
|
339 | (4) |
|
|
339 | (1) |
|
|
340 | (1) |
|
|
340 | (3) |
|
Chapter 12 Environmental Noise |
|
|
343 | (20) |
|
12.1 Sound and Its Measurement |
|
|
343 | (5) |
|
|
343 | (3) |
|
|
346 | (1) |
|
12.1.2.1 Weighting Scales |
|
|
346 | (2) |
|
12.1.2.2 Meter Response and Instrument Accuracy |
|
|
348 | (1) |
|
12.1.2.3 Measurement of Impulse Sound |
|
|
348 | (1) |
|
12.1.2.4 Spectrum Analysis |
|
|
348 | (1) |
|
12.2 Sound Exposure Descriptors |
|
|
348 | (3) |
|
12.2.1 A-Weighted Sound Level |
|
|
349 | (1) |
|
12.2.2 A-Weighted Sound Exposure Level |
|
|
349 | (1) |
|
12.2.3 Equivalent Sound Level |
|
|
349 | (1) |
|
12.2.4 Day-Night Sound Level |
|
|
350 | (1) |
|
|
351 | (1) |
|
12.4 Effects of Environmental Noise Exposure |
|
|
352 | (5) |
|
12.4.1 Hearing Impairment |
|
|
352 | (2) |
|
12.4.2 Speech Communication |
|
|
354 | (2) |
|
|
356 | (1) |
|
12.4.4 Psychophysiological Effects |
|
|
356 | (1) |
|
|
357 | (1) |
|
12.4.6 Annoyance and Social Behavior |
|
|
357 | (1) |
|
12.5 Nonregulatory and Regulatory Control Approaches |
|
|
357 | (2) |
|
12.5.1 Community Exposure Guidelines |
|
|
357 | (1) |
|
12.5.2 Community Regulatory Efforts |
|
|
358 | (1) |
|
12.5.3 Federal Noise Control Programs |
|
|
359 | (1) |
|
|
359 | (4) |
|
|
360 | (1) |
|
|
360 | (3) |
Glossary |
|
363 | (18) |
Index |
|
381 | |