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xix | |
Preface |
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xxiii | |
Acknowledgments |
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xxv | |
About the Companion Website |
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xxvii | |
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SECTION I BIOENERGY FUNDAMENTALS |
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1 | (106) |
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1 Introduction to Bioenergy |
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3 | (16) |
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3 | (2) |
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5 | (5) |
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10 | (1) |
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1.4 Why Renewable Energy? |
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11 | (2) |
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11 | (1) |
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1.4.2 Depletion of Energy Resources Reserves |
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12 | (1) |
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1.4.3 Concern about Climate Change |
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13 | (1) |
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13 | (6) |
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1.5.1 Current Status of Bioenergy Production |
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14 | (1) |
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1.5.2 Merits of Bioenergy |
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15 | (1) |
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1.5.3 Demerits of Bioenergy |
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16 | (1) |
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17 | (1) |
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18 | (1) |
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19 | (14) |
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19 | (1) |
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19 | (2) |
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2.3 Useful Units and Conversions |
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21 | (4) |
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25 | (4) |
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26 | (1) |
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27 | (1) |
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28 | (1) |
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2.5 Volume-Mass Relationship |
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29 | (1) |
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29 | (1) |
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30 | (3) |
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References and Further Reading |
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32 | (1) |
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32 | (1) |
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3 Mass and Energy Balances |
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33 | (9) |
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33 | (1) |
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33 | (2) |
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35 | (1) |
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36 | (6) |
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References and Further Reading |
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39 | (1) |
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39 | (3) |
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4 Thermodynamics and Kinetics of Basic Chemical Reactions |
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42 | (8) |
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42 | (1) |
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4.2 Reaction Thermodynamics |
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43 | (3) |
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46 | (4) |
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References and Further Reading |
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48 | (1) |
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48 | (2) |
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5 Organic and Carbohydrate Chemistry |
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50 | (21) |
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50 | (1) |
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5.2 Structural Formulas and Classification of Organic Compounds |
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51 | (1) |
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52 | (9) |
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5.3.1 Alkanes and Cycloalkanes |
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52 | (2) |
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5.3.2 Alkenes and Alkynes |
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54 | (2) |
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5.3.3 Alcohols and Ethers |
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56 | (1) |
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5.3.4 Aldehydes and Ketones |
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57 | (1) |
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5.3.5 Carboxylic Acids and Derivatives |
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58 | (3) |
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5.3.6 Other Aliphatic Compounds |
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61 | (1) |
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61 | (1) |
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5.5 Heterocyclic Compounds |
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62 | (1) |
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63 | (3) |
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63 | (2) |
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65 | (1) |
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65 | (1) |
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66 | (5) |
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66 | (2) |
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68 | (1) |
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References and Further Reading |
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69 | (1) |
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70 | (1) |
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6 Plant Structural Chemistry |
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71 | (17) |
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71 | (1) |
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6.2 Carbohydrates and Their Classification |
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72 | (1) |
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72 | (1) |
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73 | (1) |
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73 | (1) |
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6.3 Main Constituents of Plant Biomass |
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73 | (7) |
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6.3.1 Structural Carbohydrates |
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75 | (2) |
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77 | (3) |
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6.4 Plant Cell Wall Architecture |
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80 | (8) |
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80 | (4) |
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6.4.2 Secondary Cell Wall |
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84 | (1) |
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85 | (1) |
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86 | (2) |
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88 | (19) |
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88 | (1) |
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89 | (4) |
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93 | (14) |
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7.3.1 Microbial Growth in Batch Culture |
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93 | (2) |
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7.3.2 Monod Equation for Microbial Growth |
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95 | (1) |
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7.3.3 Inhibition and Multiple Substrate Models |
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96 | (1) |
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7.3.4 Monod-Based Kinetic Model in Batch Bioreactors |
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97 | (3) |
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7.3.5 Monod Model Coupled with Mass Transfer |
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100 | (1) |
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7.3.6 Mass Balances and Reactions in Fed-Batch and Continuous-Stirred Tank Bioreactors |
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101 | (1) |
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7.3.7 Elemental Balance and Stoichiometric Models |
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102 | (2) |
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104 | (1) |
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105 | (1) |
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Appendix 7.1 Code Useful for Example 7.2 |
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105 | (2) |
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SECTION II BIOENERGY FEEDSTOCKS |
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107 | (92) |
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8 Starch-Based Feedstocks |
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109 | (18) |
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109 | (1) |
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110 | (6) |
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8.2.1 Growth and Development of Corn |
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110 | (1) |
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8.2.2 Growing Degree Days for Corn Growth |
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111 | (1) |
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8.2.3 Cultivation Practices in Corn Production |
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112 | (2) |
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8.2.4 Harvesting and Storage of Corn |
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114 | (2) |
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116 | (4) |
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8.3.1 Growth and Development of Sweet Potato |
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117 | (1) |
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8.3.2 Cultivation Practices in Sweet Potato Production |
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117 | (2) |
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8.3.3 Harvesting and Storage of Sweet Potato |
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119 | (1) |
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120 | (4) |
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8.4.1 Growth and Development of Cassava |
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120 | (1) |
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8.4.2 Cultivation Practices in Cassava Production |
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121 | (2) |
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8.4.3 Harvesting and Storage of Cassava |
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123 | (1) |
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8.5 Comparison of Composition, Yield, and Energy Potential of Corn, Sweet Potato, and Cassava |
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124 | (3) |
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125 | (1) |
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126 | (1) |
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9 Oilseed-Based Feedstocks |
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127 | (16) |
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127 | (1) |
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128 | (4) |
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9.2.1 Feedstock Production and Handling |
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128 | (3) |
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9.2.2 Nutrient and Water Use |
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131 | (1) |
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132 | (3) |
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9.3.1 Feedstock Production and Handling |
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132 | (2) |
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9.3.2 Nutrient and Water Use |
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134 | (1) |
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135 | (1) |
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9.4.1 Feedstock Production and Handling |
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135 | (1) |
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9.4.2 Nutrient and Water Use |
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136 | (1) |
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136 | (2) |
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9.5.1 Feedstock Production and Handling |
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136 | (1) |
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9.5.2 Nutrient and Water Use |
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137 | (1) |
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138 | (1) |
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9.6.1 Feedstock Production and Handling |
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138 | (1) |
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9.6.2 Nutrient and Water Use |
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139 | (1) |
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9.7 Yield and Oil Content of Major Oilseed Feedstocks |
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139 | (4) |
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140 | (2) |
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142 | (1) |
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10 Lignocellulose-Based Feedstocks |
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143 | (27) |
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143 | (1) |
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10.2 Feedstock Availability and Production |
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144 | (7) |
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144 | (3) |
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10.2.2 Dedicated Energy Crops |
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147 | (2) |
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149 | (2) |
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151 | (19) |
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10.3.1 Harvesting and Collection of Crop Residues and Energy Crops |
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151 | (9) |
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10.3.2 Harvesting of Forest Biomass |
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160 | (4) |
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164 | (1) |
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165 | (2) |
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167 | (1) |
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168 | (2) |
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11 Algae-Based Feedstocks |
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170 | (29) |
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170 | (1) |
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11.2 Algae Classification, Cell Structure, and Characteristics |
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171 | (1) |
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11.3 Mechanism of Algal Growth |
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172 | (2) |
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11.4 Algal Growth Conditions |
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174 | (2) |
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174 | (1) |
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175 | (1) |
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11.4.3 Temperature, pH, and Salinity |
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175 | (1) |
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176 | (1) |
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11.5 Steps in Algal-Biodiesel Production |
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176 | (23) |
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178 | (5) |
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183 | (7) |
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190 | (2) |
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192 | (3) |
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195 | (1) |
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196 | (3) |
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SECTION III BIOLOGICAL CONVERSION TECHNOLOGIES |
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199 | (186) |
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12 Pretreatment of Lignocellulosic Feedstocks |
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201 | (23) |
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201 | (1) |
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12.2 What Does Pretreatment Do? |
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202 | (3) |
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12.3 Physical Pretreatment |
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205 | (2) |
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12.4 Thermochemical Pretreatment |
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207 | (9) |
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207 | (2) |
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12.4.2 Alkaline Pretreatment |
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209 | (4) |
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12.4.3 Organosolv Pretreatment |
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213 | (1) |
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12.4.4 Sulfite-Based Pretreatment |
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213 | (2) |
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12.4.5 The Combined Severity (CS) Factor |
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215 | (1) |
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216 | (3) |
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12.5.1 Cellulose Solvent-Based Pretreatment |
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216 | (1) |
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12.5.2 Biological Pretreatment |
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217 | (1) |
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12.5.3 Ultrasonic Pretreatment |
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218 | (1) |
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12.5.4 Microwave Pretreatment |
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218 | (1) |
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12.6 Co-products from Lignocellulosic Feedstock Pretreatment |
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219 | (5) |
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12.6.1 Hemicellulosic Sugars |
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219 | (1) |
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12.6.2 Furans (Furfural and HMF) |
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219 | (1) |
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220 | (1) |
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220 | (1) |
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221 | (3) |
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224 | (26) |
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224 | (1) |
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13.2 Nomenclature and Classification of Hydrolases |
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225 | (1) |
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226 | (14) |
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13.3.1 Fundamentals of Reaction Rate: Transition State Theory |
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227 | (1) |
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13.3.2 Reaction Rate and Reaction Orders |
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227 | (5) |
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13.3.3 Michaelis--Menten Kinetics |
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232 | (7) |
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239 | (1) |
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13.4 Enzymatic Hydrolysis of Carbohydrates |
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240 | (10) |
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13.4.1 Carbohydrate Structure |
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240 | (1) |
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13.4.2 Starch Depolymerization |
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241 | (2) |
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13.4.3 Cellulose Hydrolysis |
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243 | (2) |
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13.4.4 Hemicellulose Hydrolysis |
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245 | (1) |
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13.4.5 Key Factors Affecting the Enzymatic Hydrolysis of Lignocellulosic Feedstocks |
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245 | (1) |
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246 | (1) |
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247 | (3) |
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250 | (27) |
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250 | (2) |
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252 | (11) |
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14.2.1 Hexose Fermentation |
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253 | (7) |
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14.2.2 Pentose Fermentation |
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260 | (3) |
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14.3 Byproducts Formation during Ethanol Fermentation |
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263 | (1) |
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264 | (3) |
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14.4.1 Yeast Culture for Hexose Fermentation |
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265 | (1) |
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14.4.2 Microbial Culture for Pentose Fermentation |
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266 | (1) |
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14.5 Environmental Factors Affecting Ethanol Fermentation |
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267 | (1) |
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267 | (1) |
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267 | (1) |
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268 | (1) |
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268 | (1) |
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14.6 Industrial Fuel-Grade Ethanol Production |
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268 | (9) |
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14.6.1 Seed Culture Preparation |
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269 | (1) |
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14.6.2 Industrial Ethanol Fermentation |
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270 | (2) |
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272 | (2) |
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274 | (1) |
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275 | (2) |
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277 | (19) |
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Thaddeus Chukwuemeka Ezeji |
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277 | (2) |
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15.2 Butanol Fermentation |
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279 | (6) |
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15.2.1 Acetone-Butanol-Ethanol (ABE) Fermentation |
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279 | (1) |
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15.2.2 Biochemical Pathway |
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280 | (2) |
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15.2.3 Stoichiometry and Product Yield |
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282 | (2) |
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284 | (1) |
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15.3 Factors Affecting Butanol Fermentation |
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285 | (2) |
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285 | (1) |
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15.3.2 Availability of Co-factors (NADH) |
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285 | (1) |
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15.3.3 Medium Composition |
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286 | (1) |
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15.3.4 Product Inhibition |
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287 | (1) |
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15.4 Substrates for Butanol Fermentation |
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287 | (1) |
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15.5 Advanced Butanol Fermentation Techniques and Downstream Processing |
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288 | (8) |
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288 | (1) |
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15.5.2 Vacuum Fermentation |
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289 | (1) |
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15.5.3 Liquid-Liquid Extraction |
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290 | (1) |
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291 | (1) |
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292 | (2) |
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294 | (2) |
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296 | (17) |
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296 | (1) |
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297 | (1) |
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16.3 Syngas-Fermenting Bacteria |
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298 | (5) |
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16.3.1 Biochemical Pathway |
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299 | (1) |
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16.3.2 Genetic Transformation of Syngas-Fermenting Bacteria |
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300 | (1) |
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16.3.3 Microbial Kinetics |
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301 | (2) |
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16.4 Factors Affecting Syngas Fermentation |
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303 | (5) |
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16.4.1 Medium Composition |
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303 | (1) |
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303 | (1) |
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303 | (1) |
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304 | (2) |
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16.4.5 Bioreactor Configurations |
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306 | (2) |
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308 | (5) |
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309 | (2) |
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311 | (2) |
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17 Fundamentals of Anaerobic Digestion |
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313 | (25) |
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313 | (2) |
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17.2 Organic Conversion in an Anaerobic Process |
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315 | (5) |
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17.3 Stoichiometry of Methane Production |
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320 | (3) |
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17.4 Important Considerations in Anaerobic Digestion |
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323 | (8) |
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323 | (2) |
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325 | (2) |
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327 | (1) |
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17.4.4 Toxic Materials and Inhibition |
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328 | (1) |
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17.4.5 Total Solids Content |
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329 | (1) |
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17.4.6 Volumetric Organic Loading Rate (VOLR) |
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330 | (1) |
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17.4.7 Hydraulic Retention Time (HRT) and Solids Retention Time (SRT) |
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330 | (1) |
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331 | (1) |
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17.5 Anaerobic Digestion Model No. 1 (ADM1) |
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331 | (7) |
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334 | (2) |
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336 | (2) |
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18 Biogas Production and Applications |
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338 | (23) |
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338 | (1) |
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18.2 Anaerobic Digestion Systems |
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338 | (16) |
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18.2.1 Suspended Growth System |
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339 | (7) |
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18.2.2 Attached Growth System |
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346 | (3) |
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18.2.3 Solid-State Anaerobic Digestion System |
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349 | (2) |
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18.2.4 Household Digester |
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351 | (3) |
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18.3 Biogas Cleaning and Upgrading |
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354 | (3) |
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354 | (1) |
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355 | (1) |
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18.3.3 Biological Methods |
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356 | (1) |
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357 | (1) |
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358 | (3) |
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358 | (1) |
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359 | (2) |
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361 | (24) |
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Venkataramana Gadhamshetty |
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361 | (2) |
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19.2 How Does a Microbial Fuel Cell (MFC) Work? |
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363 | (2) |
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19.3 Electron Transfer Processes |
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365 | (5) |
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19.3.1 Mediated Electron Transfer |
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366 | (1) |
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19.3.2 Direct Electron Transfer (DET) |
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367 | (1) |
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19.3.3 Bacterial Nanowires |
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368 | (1) |
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19.3.4 Long-Range Extracellular Electron Transfer |
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369 | (1) |
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19.4 Electrical Power and Energy Generation |
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370 | (7) |
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19.4.1 Redox Reaction and Electrode Potential |
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370 | (2) |
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19.4.2 Electromotive Force and Cell Potential |
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372 | (1) |
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373 | (2) |
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19.4.4 Coulombic and Energy Efficiency |
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375 | (2) |
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19.5 Design and Operation of an MFC |
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377 | (8) |
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19.5.1 MFC Configurations |
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377 | (2) |
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379 | (1) |
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19.5.3 Anode Materials and Catalysts |
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380 | (1) |
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19.5.4 Cathode Materials and Catalysts |
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380 | (1) |
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381 | (1) |
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381 | (1) |
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382 | (3) |
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SECTION IV THERMAL CONVERSION TECHNOLOGIES |
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|
385 | (54) |
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20 Combustion for Heat and Power |
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387 | (20) |
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387 | (2) |
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20.2 Fundamentals of Biomass Combustion |
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389 | (4) |
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20.2.1 Biomass Combustion Phases |
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389 | (1) |
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20.2.2 Biomass Combustion Reaction and Stoichiometry |
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390 | (3) |
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20.3 Biomass Properties and Preprocessing |
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393 | (2) |
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20.3.1 Biomass Properties |
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393 | (1) |
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20.3.2 Biomass Preprocessing |
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394 | (1) |
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395 | (2) |
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20.4.1 Fixed-Bed Furnaces |
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395 | (1) |
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20.4.2 Fluidized-Bed Furnaces |
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396 | (1) |
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397 | (5) |
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398 | (1) |
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399 | (2) |
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20.5.3 The Air-Standard Brayton Cycle |
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401 | (1) |
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20.5.4 Combined Gas Turbine and Steam Turbine Power Cycles |
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402 | (1) |
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20.6 Biomass Co-firing with Coal |
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402 | (2) |
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20.7 Environmental Impact and Emissions of Biomass Combustion |
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404 | (3) |
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405 | (1) |
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405 | (2) |
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407 | (16) |
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407 | (1) |
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21.2 Fundamentals of Gasification |
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|
408 | (2) |
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|
408 | (1) |
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21.2.2 Gasification Reactions |
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|
409 | (1) |
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|
410 | (4) |
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21.3.1 Moving-Bed Gasifiers |
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|
410 | (1) |
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21.3.2 Fluidized-Bed Gasifiers |
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|
411 | (2) |
|
21.3.3 Entrained-Flow Gasifiers |
|
|
413 | (1) |
|
21.4 Feedstock Preparation and Characterization |
|
|
414 | (2) |
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21.4.1 Feedstock Preparation |
|
|
414 | (1) |
|
21.4.2 Feedstock Characterization |
|
|
415 | (1) |
|
21.5 Gasification Mass and Energy Balance |
|
|
416 | (3) |
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|
416 | (1) |
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|
417 | (2) |
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|
419 | (1) |
|
21.7 Applications of Biomass Gasification |
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|
419 | (4) |
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|
421 | (1) |
|
|
421 | (1) |
|
|
422 | (1) |
|
|
423 | (16) |
|
|
|
423 | (2) |
|
22.2 Slow vs. Fast Pyrolysis |
|
|
425 | (1) |
|
|
425 | (1) |
|
|
425 | (1) |
|
22.3 Pyrolysis Reactions and Mechanisms |
|
|
426 | (5) |
|
22.3.1 Pyrolysis Reactions |
|
|
426 | (2) |
|
22.3.2 Reaction Mechanisms |
|
|
428 | (3) |
|
22.4 Single-Particle Models |
|
|
431 | (1) |
|
|
432 | (2) |
|
|
434 | (1) |
|
|
434 | (5) |
|
|
437 | (1) |
|
|
438 | (1) |
|
SECTION V BIOBASED REFINERY |
|
|
439 | (66) |
|
23 Sugar-Based Biorefinery |
|
|
441 | (12) |
|
|
|
|
441 | (1) |
|
|
442 | (1) |
|
|
443 | (3) |
|
23.3.1 Ethanol Production Process |
|
|
443 | (1) |
|
23.3.2 Sugarcane-to-Ethanol Biorefinery |
|
|
444 | (2) |
|
23.4 Sweet Sorghum Ethanol |
|
|
446 | (1) |
|
|
447 | (1) |
|
23.6 Biochemicals and Biopolymers |
|
|
448 | (5) |
|
|
448 | (1) |
|
|
449 | (1) |
|
|
450 | (1) |
|
23.6.4 3-Hydroxypropionic Acid |
|
|
450 | (1) |
|
|
450 | (1) |
|
|
451 | (2) |
|
24 Starch-Based Biorefinery |
|
|
453 | (14) |
|
|
|
|
453 | (2) |
|
24.2 Stoichiometry of Starch to Ethanol |
|
|
455 | (9) |
|
24.2.1 Corn-Based Ethanol Biorefinery |
|
|
456 | (5) |
|
24.2.2 Corn-to-Ethanol Plants and Sorghum-to-Ethanol Plants |
|
|
461 | (1) |
|
24.2.3 Cassava-Based Ethanol Biorefinery |
|
|
461 | (3) |
|
24.3 Integrated Farm-Scale Biorefinery |
|
|
464 | (3) |
|
|
465 | (1) |
|
|
466 | (1) |
|
25 Lignocellulose-Based Biorefinery |
|
|
467 | (14) |
|
|
|
|
|
467 | (1) |
|
25.2 Cell Structure of Lignocellulosic Feedstocks |
|
|
468 | (1) |
|
25.3 Stoichiometry and Energy Content |
|
|
468 | (4) |
|
|
470 | (1) |
|
|
471 | (1) |
|
25.4 Lignocellulosic Biomass Conversion to Fuel |
|
|
472 | (1) |
|
25.5 Co-Products from Lignocellulose-Based Biorefinery |
|
|
473 | (3) |
|
25.5.1 Products from Lignin |
|
|
474 | (1) |
|
25.5.2 Products from Hemicellulose |
|
|
475 | (1) |
|
25.6 Industrial Lignocellulose-Based Biorefinery |
|
|
476 | (5) |
|
|
478 | (2) |
|
|
480 | (1) |
|
26 Lipid-Based Biorefinery |
|
|
481 | (24) |
|
|
|
|
|
|
481 | (2) |
|
26.2 Lipid-Based Feedstocks |
|
|
483 | (1) |
|
|
483 | (1) |
|
|
484 | (1) |
|
26.2.3 Waste Cooking Oils |
|
|
484 | (1) |
|
26.3 Chemical Properties of Lipids |
|
|
484 | (7) |
|
26.3.1 Chemical Composition of Lipids |
|
|
484 | (1) |
|
26.3.2 Average Molecular Weight of Triglycerides |
|
|
484 | (4) |
|
26.3.3 Seed Oil Extraction |
|
|
488 | (3) |
|
26.4 Biodiesel from Lipids |
|
|
491 | (7) |
|
26.4.1 Biodiesel Production via Transesterification |
|
|
491 | (4) |
|
26.4.2 Parameters Affecting Biodiesel Production |
|
|
495 | (2) |
|
26.4.3 Quality of Biodiesel |
|
|
497 | (1) |
|
26.5 Lipid-Based Biorefinery |
|
|
498 | (7) |
|
26.5.1 High-Value Biobased Products from Seed Oils |
|
|
498 | (1) |
|
26.5.2 Seed Meals and Their Applications |
|
|
499 | (1) |
|
26.5.3 Utilization of Glycerol from Biodiesel Production |
|
|
500 | (1) |
|
|
501 | (1) |
|
|
502 | (3) |
|
SECTION VI BIOENERGY SYSTEM ANALYSIS |
|
|
505 | (58) |
|
27 Techno-Economic Assessment |
|
|
507 | (14) |
|
|
|
507 | (1) |
|
27.2 What Is Techno-Economic Analysis? |
|
|
508 | (1) |
|
|
509 | (8) |
|
27.4 Tools, Software, and Data Sources for Performing TEA |
|
|
517 | (4) |
|
27.4.1 Tools Available for Performing TEA |
|
|
517 | (1) |
|
27.4.2 Procedure for TEA Using Commercial Software |
|
|
517 | (1) |
|
27.4.3 Data Sources for Performing TEA |
|
|
518 | (1) |
|
27.4.4 Process Optimization Using TEA |
|
|
518 | (1) |
|
|
518 | (1) |
|
|
518 | (3) |
|
|
521 | (23) |
|
|
|
521 | (1) |
|
28.2 What Is Life-Cycle Assessment (LCA)? |
|
|
522 | (2) |
|
|
524 | (9) |
|
28.3.1 Goal Definition and Scoping |
|
|
524 | (2) |
|
28.3.2 Life-Cycle Inventory |
|
|
526 | (4) |
|
28.3.3 Life-Cycle Impact Assessment |
|
|
530 | (2) |
|
28.3.4 Life-Cycle Interpretation |
|
|
532 | (1) |
|
28.4 Tools Available to Perform LCA |
|
|
533 | (1) |
|
|
533 | (11) |
|
28.5.1 Sensitivity Analysis |
|
|
533 | (1) |
|
28.5.2 Process Optimization Using LCA |
|
|
533 | (1) |
|
|
533 | (6) |
|
|
539 | (2) |
|
|
541 | (3) |
|
29 Government Policy and Standards For Bioenergy |
|
|
544 | (19) |
|
|
|
|
|
29.1 Overview of the Bioenergy Market |
|
|
544 | (2) |
|
29.2 Rationale for Government Intervention |
|
|
546 | (4) |
|
29.3 Government Intervention through Policy Tools |
|
|
550 | (1) |
|
29.4 Biofuels Policy Implementations: Existing Policy Instruments |
|
|
550 | (9) |
|
29.4.1 Tax Credit/Subsidy |
|
|
551 | (1) |
|
|
552 | (2) |
|
|
554 | (1) |
|
29.4.4 Biofuels Regulations and Standards |
|
|
555 | (1) |
|
29.4.5 Emissions Trading or "Cap-and-Trade" |
|
|
556 | (1) |
|
29.4.6 Flex-Fuel Vehicles |
|
|
557 | (1) |
|
|
557 | (1) |
|
|
558 | (1) |
|
29.4.9 Funding for Research and Development |
|
|
558 | (1) |
|
29.5 Implications of Biofuels Policies |
|
|
559 | (4) |
|
|
561 | (1) |
|
|
561 | (2) |
Index |
|
563 | |