Preface |
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xvii | |
1 Bioelectrocatalysis for Biofuel Cells |
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1 | (52) |
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1.1 Introduction: Generalities of the Bioelectrocatalysis |
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2 | (1) |
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1.2 Reactions of Interest in Bioelectrocatalysis |
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3 | (6) |
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1.2.1 Enzyme Catalyzed Reactions |
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3 | (5) |
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1.2.2 Reactions Catalyzed by Microorganisms |
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8 | (1) |
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1.3 Immobilization of Biocatalyst |
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9 | (8) |
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1.3.1 Immobilization of Enzymes on Electrodes |
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9 | (6) |
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1.3.2 Preparation of Microbial Bioelectrodes |
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15 | (2) |
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1.4 Supports for Immobilization of Enzymes and Microorganisms for Biofuel Cells |
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17 | (8) |
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1.4.1 Buckypaper Bioelectrodes for BFCs |
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20 | (1) |
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1.4.2 Carbon Paper Bioelectrodes for BFCs |
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21 | (1) |
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1.4.3 Nitrogen-Doped Carbonaceous Materials as Bioelectrodes for BFCs |
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22 | (1) |
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1.4.4 Metal-Organic Framework (MOF)-Based Carbonaceous Materials as Bioelectrodes for BFCs |
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23 | (1) |
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1.4.5 Flexible Bioelectrodes for Flexible BFCs |
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24 | (1) |
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1.5 Electron Transfer Phenomena |
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25 | (9) |
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1.5.1 Enzyme-Electrode Electron Transfer |
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25 | (6) |
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1.5.2 Microorganism-Electrode Electron Transfer |
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31 | (3) |
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1.6 Bioelectrocatalysis Control |
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34 | (2) |
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1.6.1 Control of Enzymatic Bioelectrocatalysis |
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34 | (1) |
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1.6.2 Microbiological Catalysis Control |
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35 | (1) |
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1.7 Recent Applications of Bioelectrocatalysis |
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36 | (3) |
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36 | (1) |
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1.7.2 Microbial Catalyzed CO2 Reduction |
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37 | (2) |
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39 | (14) |
2 Novel Innovations in Biofuel Cells |
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53 | (16) |
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2.1 Introduction to Biological Fuel Cells |
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53 | (10) |
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55 | (4) |
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59 | (4) |
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2.2 Conclusions and Future Perspectives |
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63 | (1) |
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64 | (1) |
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64 | (5) |
3 Implantable Biofuel Cells for Biomedical Applications |
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69 | (28) |
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70 | (2) |
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72 | (3) |
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3.2.1 Microbial Biofuel Cells |
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72 | (3) |
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3.2.1.1 Design and Configuration |
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73 | (2) |
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3.3 Enzymatic Biofuel Cells |
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75 | (5) |
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3.3.1 Design and Configurations |
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75 | (2) |
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77 | (3) |
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3.4 Mechanism of Electron Transfer |
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80 | (1) |
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3.5 Energy Sources in the Human Body |
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81 | (2) |
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3.6 Biomedical Applications |
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83 | (4) |
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3.6.1 Glucose-Based Biofuels Cells |
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84 | (1) |
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85 | (1) |
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3.6.3 Implanted Brain-Machine Interface |
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86 | (1) |
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87 | (1) |
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87 | (1) |
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3.8 Conclusion and Future Perspectives |
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88 | (1) |
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88 | (7) |
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95 | (2) |
4 Enzymatic Biofuel Cells |
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97 | (26) |
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98 | (1) |
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99 | (4) |
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4.3 Enzyme Immobilization Materials |
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103 | (8) |
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4.3.1 Physical Adsorption Onto a Solid Surface |
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105 | (1) |
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4.3.2 Entrapment in a Matrix |
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106 | (1) |
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106 | (1) |
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4.3.4 Nanomaterials as Matrices for Enzyme Immobilization |
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107 | (2) |
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109 | (1) |
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4.3.6 Cross-Linking With Bifunctional or Multifunctional Reagents |
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110 | (1) |
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4.4 Applications of EBFCs |
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111 | (3) |
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4.4.1 Self-Powered Biosensors |
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111 | (1) |
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4.4.2 EBFCs Into Implantable Bioelectronics |
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111 | (1) |
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4.4.3 EBFCs Powering Portable Devices |
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112 | (2) |
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114 | (2) |
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116 | (1) |
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116 | (7) |
5 Introduction to Microbial Fuel Cell (MFC): Waste Matter to Electricity |
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123 | (22) |
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124 | (1) |
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5.2 Operating Principles of MFC |
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125 | (1) |
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5.3 Main Components and Materials of MFCs |
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126 | (10) |
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126 | (8) |
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134 | (1) |
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5.3.3 Substrates or Fed-Stocks |
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135 | (1) |
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5.3.4 MFC Cell Configurations |
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135 | (1) |
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5.4 Current and Prospective Applications of MFC Technology |
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136 | (2) |
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5.5 Conclusion and Future Prospects |
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138 | (1) |
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138 | (1) |
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138 | (7) |
6 Flexible Biofuel Cells: An Overview |
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145 | (26) |
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145 | (4) |
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6.1.1 Working Principle of Fuel Cell |
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146 | (2) |
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6.1.2 Types of Fuel Cells |
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148 | (1) |
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149 | (4) |
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149 | (3) |
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6.2.1.1 Microbial Fuel Cell |
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150 | (1) |
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6.2.1.2 Photomicrobial Fuel Cell |
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151 | (1) |
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6.2.1.3 Enzymatic Fuel Cell |
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151 | (1) |
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6.2.2 Applications of Biofuel Cells |
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152 | (1) |
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6.3 Needs for Flexible Biofuel Cell |
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153 | (11) |
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153 | (1) |
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6.3.2 Materials for Flexible Biofuel Cells |
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154 | (2) |
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6.3.3 Fabrication of Bioelectrodes |
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156 | (1) |
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6.3.4 Recent Advances and New Progress for the Development of Flexible Biofuel Cell |
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156 | (6) |
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6.3.4.1 Carbon-Based Electrode Materials for Flexible Biofuel Cells |
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157 | (3) |
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6.3.4.2 Textile and Polymer-Based Electrode Materials for Flexible Biofuel Cells |
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160 | (2) |
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6.3.4.3 Metal-Based Electrode Materials |
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162 | (1) |
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6.3.5 Challenges Faced by Flexible Biofuel Cell |
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162 | (2) |
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164 | (1) |
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164 | (7) |
7 Carbon Nanomaterials for Biofuel Cells |
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171 | (48) |
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172 | (1) |
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173 | (1) |
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7.2 Types of Biofuel Cells |
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174 | (2) |
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7.2.1 Enzyme-Based Biofuel Cell (EBFC) |
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175 | (1) |
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7.2.2 Microbial-Based Biofuel Cells (MBFCs) |
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176 | (1) |
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7.3 Carbon-Based Materials for Biofuel Cells |
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176 | (17) |
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7.3.1 Cellulose-Based Biomass Fuel Cells |
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176 | (1) |
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7.3.2 Starch and Glucose-Based Fuel Cells |
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177 | (1) |
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7.3.3 Carbon Nanoparticles (NPs) |
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178 | (1) |
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179 | (1) |
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179 | (3) |
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182 | (1) |
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182 | (7) |
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187 | (1) |
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188 | (1) |
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189 | (1) |
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7.3.6.4 Biphenylated CNTs |
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189 | (1) |
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189 | (1) |
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190 | (1) |
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191 | (1) |
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191 | (1) |
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192 | (1) |
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7.3.12 Reticulated Vitreous Carbon (RVC) |
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192 | (1) |
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192 | (1) |
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7.4 Applications of Biofuel Cells Using Carbon-Based Nanomaterials |
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193 | (4) |
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7.4.1 Living Batteries/Implantable Fuel Cells |
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193 | (4) |
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7.4.1.1 Animal In Vivo Implantation |
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194 | (1) |
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7.4.1.2 Energy Extraction From Body Fluids |
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195 | (2) |
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7.4.2 Energy Extraction From Fruits |
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197 | (1) |
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197 | (1) |
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198 | (21) |
8 Glucose Biofuel Cells |
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219 | (10) |
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219 | (1) |
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8.2 Merits of BFC Over FC |
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220 | (1) |
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8.3 Glucose Oxidize (GOs) as Enzyme Catalyst in Glucose Biofuel Cells |
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221 | (1) |
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8.4 General Experimental Technique for Fabrication of Enzyme GOs Immobilized Electrodes for Glucose Oxidation |
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222 | (1) |
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8.5 General Method of Characterization of Fabricated Enzyme Immobilized Working Electrode |
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223 | (1) |
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8.6 Determination of Electron Transfer Rate Constant (ks) |
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224 | (1) |
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8.7 Denaturation of Enzymes |
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225 | (1) |
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225 | (1) |
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226 | (1) |
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226 | (3) |
9 Photochemical Biofuel Cells |
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229 | (32) |
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230 | (3) |
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9.1.1 Various Configuration of PBEC-FC |
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231 | (2) |
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9.2 Photosynthetic Biofuel Cell (PS-BFC) |
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233 | (5) |
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9.2.1 Various Configurations of PS-BFC |
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234 | (4) |
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9.3 Photovoltaic-Biofuel Cell (PV-BFC) |
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238 | (2) |
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9.4 Photoelectrode Integrated-Biofuel Cell (PE-BFC) |
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240 | (7) |
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9.4.1 The Basic Mechanism of Photoelectrochemical (PEC) Reaction |
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241 | (1) |
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9.4.2 Photoelectrode-Integrated BFC |
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242 | (1) |
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9.4.3 Various Configuration of PE-BFC |
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243 | (2) |
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9.4.4 Materials Used in PE-BFC |
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245 | (2) |
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9.5 Potential Fuels Generation and Their Performance From PEC-BFC |
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247 | (5) |
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9.5.1 Hydrogen Generation |
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247 | (2) |
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9.5.2 Contaminants Removal and Waste Remediation |
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249 | (2) |
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9.5.3 Sustainable Power Generation |
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251 | (1) |
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252 | (1) |
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253 | (8) |
10 Engineering Architectures for Biofuel Cells |
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261 | (38) |
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261 | (2) |
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263 | (1) |
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263 | (1) |
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10.1.2 General Configuration of a Biofuel Cell |
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263 | (1) |
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10.2 Role as Miniaturized Ones |
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264 | (2) |
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266 | (4) |
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10.3.1 Biological Sensors |
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266 | (1) |
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10.3.2 Implantable Medical Devices |
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267 | (2) |
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268 | (1) |
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269 | (1) |
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269 | (1) |
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10.3.4 Building Materials |
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270 | (1) |
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270 | (12) |
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10.4.1 Fabrication and Design |
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270 | (5) |
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271 | (1) |
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10.4.1.2 Sol-Gel Encapsulation |
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272 | (1) |
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10.4.1.3 3D Electrode Architecture |
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272 | (1) |
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10.4.1.4 Multi-Enzyme Systems (Enzyme Cascades) |
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273 | (1) |
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273 | (1) |
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274 | (1) |
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10.4.1.7 Parallel Cascades |
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274 | (1) |
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10.4.1.8 Artificial Neural Networks (ANNs) |
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274 | (1) |
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10.4.2 Single Compartment Layout |
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275 | (1) |
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10.4.3 Two-Compartment Layout |
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275 | (1) |
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275 | (2) |
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10.4.4.1 Direct Electron Transfer |
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275 | (1) |
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10.4.4.2 Mediated Electron Transfer |
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276 | (1) |
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277 | (2) |
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10.4.5.1 Carbon Nanomaterials |
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277 | (1) |
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10.4.5.2 H2/O2 Biofuel Cells |
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277 | (1) |
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278 | (1) |
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10.4.5.4 Fungal Cellulases |
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279 | (1) |
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279 | (1) |
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10.4.6.1 Scanning Electron Microscopy (SEM) |
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279 | (1) |
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10.4.6.2 Atomic Force Microscopy (AFM) |
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279 | (1) |
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10.4.6.3 X-Ray Photoelectron Spectroscopy (XPS) |
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280 | (1) |
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10.4.6.4 Fluorescence Microscopy |
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280 | (1) |
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10.4.7 Metagenomic Techniques |
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280 | (2) |
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10.4.7.1 Pre-Treatment of Environmental Samples |
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281 | (1) |
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10.4.7.2 Nucleic Acid Extraction |
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281 | (1) |
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10.4.8 Integrated Devices |
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282 | (1) |
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10.5 Issues and Perspectives |
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282 | (1) |
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10.6 Future Challenges in the Architectural Engineering |
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283 | (1) |
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283 | (1) |
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284 | (15) |
11 Biofuel Cells for Commercial Applications |
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299 | (18) |
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Sathish Kumar Palaniappan |
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299 | (1) |
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300 | (3) |
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11.1.1 History of Biofuel Cell |
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300 | (3) |
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11.2 Classification of Electrochemical Devices Based on Fuel Confinement |
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303 | (4) |
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11.2.1 Process of Electron Shift From Response Site to Electrode |
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303 | (1) |
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11.2.2 Bioelectrochemical Cells Including an Entire Organism |
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303 | (1) |
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11.2.3 Entire Organism Product Biofuel Cells Producing Hydrogen Gas |
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304 | (1) |
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11.2.4 Entire Organism Non-Diffusive Biofuel Cells |
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305 | (2) |
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11.3 Application of Biofuel Cells |
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307 | (5) |
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11.3.1 Micro- and Nanotechnology |
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308 | (1) |
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11.3.2 Self-Powered Biofuel Sensor |
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309 | (1) |
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11.3.3 Switchable Biofuel Cells and Logic Gates |
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310 | (1) |
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11.3.4 Microbial Energy Production |
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310 | (1) |
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11.3.5 Transport and Energy Generation |
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311 | (1) |
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11.3.6 Infixable Power Sources |
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312 | (1) |
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312 | (1) |
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312 | (1) |
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312 | (1) |
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313 | (4) |
12 Development of Suitable Cathode Catalyst for Biofuel Cells |
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317 | (28) |
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317 | (4) |
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12.2 Kinetics and Mechanism of Oxygen Reduction Reaction |
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321 | (1) |
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12.3 Techniques for Evaluating ORR Catalyst |
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322 | (4) |
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12.4 Cathode Catalyst in BFCs |
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326 | (1) |
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327 | (5) |
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12.5.1 Metals-Based Catalyst |
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327 | (4) |
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12.5.1.1 Metals and Alloys |
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327 | (1) |
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328 | (3) |
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331 | (1) |
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332 | (1) |
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12.7 Enzymatic Catalyst for Biofuel Cell |
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333 | (1) |
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334 | (1) |
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335 | (1) |
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335 | (10) |
13 Biofuel Cells for Water Desalination |
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345 | (32) |
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345 | (2) |
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347 | (3) |
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347 | (1) |
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13.2.2 Types of Biofuel Cells |
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348 | (2) |
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13.2.2.1 Enzymatic Fuel Cell |
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349 | (1) |
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13.2.2.2 Microbial Fuel Cell |
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349 | (1) |
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13.3 Biofuel Cells for Desalination: Microbial Desalination Cell |
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350 | (16) |
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351 | (2) |
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13.3.2 Microbial Desalination Cell Configurations |
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353 | (13) |
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353 | (1) |
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354 | (1) |
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13.3.2.3 Stacked MDC (sMDC) |
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355 | (2) |
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13.3.2.4 Recirculation MDC (rMDC) |
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357 | (1) |
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13.3.2.5 Microbial Electrolysis Desalination and Chemical Production Cell (MEDCC) |
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358 | (1) |
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13.3.2.6 Capacitive MDC (cMDC) |
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359 | (1) |
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13.3.2.7 Upflow MDC (UMDC) |
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360 | (1) |
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13.3.2.8 Osmotic MDC (OMDC) |
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361 | (1) |
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13.3.2.9 Bipolar Membrane Microbial Desalination Cell |
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362 | (1) |
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363 | (1) |
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13.3.2.11 Separator Coupled Stacked Circulation MDC (c-SMDC-S) |
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364 | (1) |
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13.3.2.12 Ion-Exchange Resin Coupled Microbial Desalination Cell |
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365 | (1) |
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13.4 Factors Affecting the Performance and Efficiency of Desalination Cells |
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366 | (4) |
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13.4.1 Effect of External Resistance |
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366 | (1) |
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13.4.2 Effect of Internal Resistance |
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367 | (1) |
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367 | (1) |
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13.4.4 Effect of Microorganisms |
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368 | (1) |
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13.4.5 Effect of Operating Conditions |
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369 | (1) |
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13.4.6 Effect of Membrane Scaling and Fouling |
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370 | (1) |
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13.4.7 Effect of Desalinated Water Contamination |
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370 | (1) |
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13.5 Current Challenges and Further Prospects |
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370 | (1) |
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371 | (1) |
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372 | (5) |
14 Conventional Fuel Cells vs Biofuel Cells |
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377 | (46) |
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14.1 Bioelectrochemical Cell |
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378 | (1) |
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378 | (17) |
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378 | (6) |
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14.2.1.1 Conventional Fuel Cell (FC) |
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378 | (1) |
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378 | (2) |
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380 | (1) |
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14.2.1.4 Construction/Designs |
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380 | (3) |
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14.2.1.5 Stacking of Fuel Cell |
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383 | (1) |
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14.2.1.6 Importance of Conventional FC |
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384 | (1) |
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384 | (10) |
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14.2.2.1 Molten Carbonate Fuel Cell (MCFC) |
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385 | (1) |
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14.2.2.2 Proton Exchange Membrane Fuel Cell (PEMFC) |
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386 | (2) |
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14.2.2.3 Direct Methanol Fuel Cell (DMFC) |
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388 | (1) |
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14.2.2.4 Solid Oxide Fuel Cell (SOFC) |
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389 | (1) |
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14.2.2.5 Alkaline FC (AFC) |
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390 | (1) |
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14.2.2.6 Phosphoric Acid Fuel Cell (PAFC) |
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391 | (3) |
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14.2.3 Advantages of Fuel Cells |
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394 | (1) |
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394 | (1) |
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394 | (1) |
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394 | (1) |
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394 | (1) |
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395 | (4) |
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395 | (1) |
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14.3.2 Categories of Biofuel |
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395 | (4) |
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14.3.2.1 First-Generation Biofuel |
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395 | (4) |
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14.3.2.2 Second-Generation Biofuel |
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399 | (1) |
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14.3.2.3 Third-Generation Biofuel |
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399 | (1) |
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14.3.2.4 Fourth-Generation Biofuel |
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399 | (1) |
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14.3.3 Advantages of Biofuels |
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399 | (1) |
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14.4 Types of Biofuel Cells |
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399 | (14) |
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14.4.1 Microbial Fuel Cell |
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399 | (8) |
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14.4.1.1 Basic Principles of MFC |
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401 | (2) |
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403 | (1) |
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14.4.1.3 Mechanism of Electron Transfer |
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404 | (1) |
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405 | (1) |
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14.4.1.5 Advantages of MFCs |
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406 | (1) |
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14.4.1.6 Disadvantage of MFCs |
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|
407 | (1) |
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14.4.2 Enzymatic Biofuel Cells (EBCs) |
|
|
407 | (2) |
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14.4.2.1 Principle/Mechanism |
|
|
407 | (1) |
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|
407 | (1) |
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14.4.2.3 Immobilization of an Enzyme |
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|
408 | (1) |
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14.4.3 Glucose Biofuel Cells (GBFCs) |
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|
409 | (2) |
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14.4.4 Photochemical Biofuel Cell |
|
|
411 | (1) |
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14.4.5 Flexible or Stretchable Biofuel Cell |
|
|
412 | (1) |
|
|
413 | (1) |
|
|
413 | (10) |
15 State-of-the-Art and Prospective in Biofuel Cells: A Roadmap Towards Sustainability |
|
423 | (26) |
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|
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|
423 | (2) |
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15.2 Membrane-Based and Membrane-Less Biofuel Cells |
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|
425 | (4) |
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15.3 Enzymatic Biofuel Cells |
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|
429 | (3) |
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15.4 Wearable Biofuel Cells |
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|
432 | (2) |
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15.5 Fuels for Biofuel Cells |
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|
434 | (1) |
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15.6 Roadmap to Sustainability |
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|
434 | (4) |
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15.7 Conclusion and Future Direction |
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|
438 | (1) |
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|
439 | (1) |
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|
439 | (10) |
16 Anodes for Biofuel Cells |
|
449 | (16) |
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|
450 | (1) |
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16.2 Anode Material Properties |
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|
451 | (1) |
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|
452 | (1) |
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16.3.1 Non-Carbon Anode Materials |
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|
452 | (1) |
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16.3.2 Carbon Anode Materials |
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|
453 | (1) |
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453 | (3) |
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16.4.1 Anode Modification With Carbon Nanotube (CNT) |
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|
453 | (1) |
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16.4.2 Graphite-Based Material for Anode Electrode Modification |
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|
454 | (1) |
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16.4.3 Anode Modification With Nanocomposite of Metal Oxides |
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|
454 | (1) |
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16.4.4 Anode Modification With Conducting Polymer |
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|
455 | (1) |
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16.4.5 Chemical and Electrochemical Anode Modifications |
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|
456 | (1) |
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16.5 Challenge and Future Perspectives |
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|
456 | (1) |
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|
457 | (1) |
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|
457 | (1) |
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|
457 | (8) |
17 Applications of Biofuel Cells |
|
465 | (18) |
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|
465 | (2) |
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467 | (1) |
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|
468 | (5) |
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17.3.1 Microbial Biofuel Cell |
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|
469 | (2) |
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17.3.1.1 At Anode Chamber |
|
|
470 | (1) |
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17.3.1.2 At Cathode Chamber |
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|
471 | (1) |
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17.3.2 Enzymatic Biofuel Cell |
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|
471 | (1) |
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17.3.3 Mammalian Biofuel Cell |
|
|
472 | (1) |
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17.4 Implantable Devices Powered by Using Biofuel Cell |
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|
473 | (3) |
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17.4.1 Implantable Biofuel Cell for Pacemakers or Artificial Urinary Sphincter |
|
|
473 | (1) |
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17.4.2 Implantable Medical Devices Powered by Mammalian Biofuel Cells |
|
|
474 | (1) |
|
17.4.3 Medical Devices Using PEM Fuel Cell |
|
|
475 | (1) |
|
17.4.4 Implantable Brain Machine Interface Using Glucose Fuel Cell |
|
|
475 | (1) |
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17.5 Single Compartment EBFCs |
|
|
476 | (1) |
|
17.6 Extracting Energy from Human Perspiration Through Epidermal Biofuel Cell |
|
|
476 | (1) |
|
17.7 Mammalian Body Fluid as an Energy Source |
|
|
477 | (1) |
|
17.8 Implantation of Enzymatic Biofuel Cell in Living Lobsters |
|
|
477 | (1) |
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17.9 Biofuel Cell Implanted in Snail |
|
|
477 | (1) |
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17.10 Application of Biofuel Cell |
|
|
478 | (1) |
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|
479 | (1) |
|
|
479 | (4) |
Index |
|
483 | |