Carbon Based Nanofillers and their Rubber Nanocomposites: Fundamentals and Applications provides the synthetic routes, characterization, structural properties and effect of nano fillers on rubber nanocomposites. The synthesis and characterization of all carbon-based fillers is discussed, along with their morphological, thermal, mechanical, dynamic mechanical, and rheological properties. The book also covers the theory, modeling, and simulation aspects of these nanocomposites and their various applications. Users will find a valuable reference source for graduates and post graduates, engineers, research scholars, polymer engineers, polymer technologists, and those working in the biomedical field.
- Reviews rubber nanocomposites, specifically carbon-associated nanomaterials (nanocarbon black, graphite, graphene, carbon nanotubes, fullerenes, diamond)
- Presents the synthesis and characterization of carbon based nanocomposites
- Relates the structure of these nanocomposites to their function as rubber additives and their many applications
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xi | |
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1 Nanostructures and Compatibility in Rubber Nanocomposites Containing Carbon Nanofillers |
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1 | (26) |
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1.1 Rubber Composites and Nanocomposites |
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1 | (1) |
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1.2 Learning From Natural Rubber |
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2 | (2) |
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1.3 Carbon Particle Morphology and Surface Properties |
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4 | (8) |
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1.4 Rubber---Particle Mixing and Compatibility |
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12 | (1) |
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1.5 Rubber---Particle Interfaces and Compatibility |
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13 | (8) |
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1.6 Conclusion and Perspectives |
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21 | (1) |
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22 | (4) |
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26 | (1) |
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2 Fabrication Methods of Carbon-Based Rubber Nanocomposites |
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27 | (22) |
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Aleksandra Ivanoska-Dacikj |
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27 | (2) |
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2.2 General Methods for the Fabrication of Carbon-Based Rubber Nanocomposites |
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29 | (12) |
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2.3 Other Methods of Fabrication |
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41 | (2) |
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43 | (1) |
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43 | (6) |
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3 Fabrication Methods of Carbon-Based Rubber Nanocomposites and Their Applications |
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49 | (16) |
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49 | (1) |
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3.2 Ultrasonic Solution-Mixing Method |
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50 | (3) |
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3.3 Latex-Mixing Method and Casting |
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53 | (2) |
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3.4 Melt Method by Roll Milling |
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55 | (3) |
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3.5 Hot Melt Extrusion Method |
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58 | (4) |
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62 | (3) |
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4 Statistical and Perturbation-Based Analysis of Unidirectional Stretch of Rubber-Like Materials |
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65 | (10) |
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65 | (2) |
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67 | (2) |
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4.3 Computational Experiments |
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69 | (3) |
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72 | (1) |
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72 | (1) |
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/3 | |
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73 | (2) |
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5 Functionalization, Modification, and Characterization of Carbon Nanofibers |
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75 | (64) |
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5.1 Modification of Carbon Nanofibers |
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75 | (17) |
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5.2 Characterization of Carbon Nanofibers |
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92 | (38) |
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130 | (1) |
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131 | (8) |
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6 Multilayer Graphene/Elastomer Nanocomposites |
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139 | (62) |
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140 | (1) |
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6.2 Materials and Experimental |
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141 | (5) |
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6.3 Multilayer Graphene-Based Nanocomposites of Different Rubbers |
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146 | (17) |
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6.4 Chlorine---Isobutylene---Isoprene Rubber/Multilayer Graphene Nanocomposites: The Effect of Multilayer Graphene Concentration |
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163 | (10) |
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6.5 Chlorine---Isobutylene---Isoprene Rubber/Multilayer Graphene Nanocomposites: The Effect of Dispersion |
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173 | (7) |
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6.6 Chlorine---Isobutylene---Isoprene Rubber/Multilayer Graphene Nanocomposites: Comparison of Multilayer Graphene, Carbon Black, and a Combination of Both |
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180 | (14) |
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194 | (1) |
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195 | (1) |
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196 | (5) |
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7 Preparation of Noble Metal/Graphene Nanocomposites Using Various Excited Reaction Sites in an Aqueous System |
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201 | (24) |
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201 | (2) |
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7.2 Ultrasound Irradiation to Generate Acoustic Cavitation |
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203 | (6) |
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7.3 Bottom-Up Method of Nanoparticle Deposition on Graphene by Gamma Ray or Electron Beam Irradiation to Water |
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209 | (5) |
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7.4 Nanoparticle Deposition on Graphene by Plasma Generated in the Aqueous Phase |
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214 | (6) |
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220 | (5) |
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8 Microscopic Analysis and Characterization of Natural Rubber Containing Carbon Fillers |
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225 | (28) |
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226 | (1) |
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8.2 Characterization of Natural Rubber Containing Carbon Fillers |
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227 | (9) |
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8.3 Properties of Natural Rubber Containing Carbon Fillers |
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236 | (11) |
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247 | (1) |
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248 | (1) |
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248 | (3) |
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251 | (2) |
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9 Barrier, Diffusion, and Transport Properties of Rubber Nanocomposites Containing Carbon Nanofillers |
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253 | (34) |
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Maryam Ahmadzadeh Tofighy |
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253 | (2) |
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255 | (8) |
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9.3 Graphene-Based Rubber Nanocomposites |
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263 | (3) |
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9.4 Experimental Studies About Graphene-Based Rubber Nanocomposites |
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266 | (12) |
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278 | (1) |
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279 | (6) |
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285 | (2) |
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10 Thermal Properties of Rubber Nanocomposites Based on Carbon Nanofillers |
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287 | (38) |
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288 | (1) |
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10.2 Preparative Methods of Rubber Nanocomposites |
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289 | (1) |
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10.3 Thermogravimetric Analysis of Carbon Nanofiller Incorporated Rubber Nanocomposites |
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290 | (18) |
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10.4 Differential Scanning Calorimetry of Carbon Filler-Incorporated Rubber Nanocomposites |
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308 | (11) |
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319 | (1) |
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319 | (6) |
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11 Thermal Properties (DSC, TMA, TGA, DTA) of Rubber Nanocomposites Containing Carbon Nanofillers |
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325 | (42) |
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326 | (3) |
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11.2 Differential Scanning Calorimetry |
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329 | (3) |
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11.3 Differential Thermal Analysis |
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332 | (1) |
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11.4 Differential Scanning Calorimetry Analysis of Carbon Nanofillers Incorporated Rubber Nanocomposites |
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333 | (6) |
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11.5 Thermomechanical Analysis |
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339 | (3) |
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11.6 Thermomechanical Analysis of Carbon Nanofiller-Incorporated Rubber Nanocomposites |
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342 | (2) |
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11.7 Thermal Gravimetric Analysis |
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344 | (3) |
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11.8 Thermal Gravimetric Analysis of Carbon Nanofiller-Incorporated Rubber Nanocomposites |
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347 | (12) |
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359 | (1) |
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360 | (7) |
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12 Mechanical Properties of Rubber Nanocomposites Containing Carbon Nanofillers |
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367 | (58) |
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368 | (3) |
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12.2 The Processing Method of Rubber Nanocomposites Containing Carbon Nanofillers |
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371 | (5) |
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12.3 Mechanical Properties of Rubber Nanocomposites Containing Carbon Nanofillers |
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376 | (10) |
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12.4 Influence Factor for Determining the Mechanical Properties |
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386 | (12) |
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12.5 Payne Effect and Mullins Effect of Rubber Nanocomposites Containing Carbon Nanofillers |
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398 | (10) |
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12.6 Summary and Conclusions |
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408 | (2) |
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410 | (15) |
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13 Development of Carbon Nanomaterials and Their Composites for Various Catalytic Applications |
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425 | (16) |
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425 | (1) |
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426 | (9) |
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13.3 Current and Future Prospects |
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435 | (1) |
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435 | (1) |
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436 | (5) |
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14 Applications of Carbon-Based Nanofiller-Incorporated Rubber Composites in the Fields of Tire Engineering, Flexible Electronics and EMI Shielding |
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441 | (32) |
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441 | (5) |
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14.2 Different Kinds of Carbon-Based Nanofillers |
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446 | (2) |
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14.3 Properties of Rubber-Based Composites Containing Carbon-Based Nanofillers |
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448 | (6) |
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14.4 Different Theoretical Models Available for Reinforced Rubber Composites |
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454 | (2) |
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14.5 Applications of Rubber-Based Composites Containing Carbon-Based Nanofillers |
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456 | (6) |
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462 | (1) |
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463 | (1) |
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463 | (10) |
Index |
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473 | |
Mr. Srinivasarao Yaragalla is a Senior Research Scholar at the International and Inter University Centre for Nanoscience and Nanotechnology at Mahatma Gandhi University, Kottayam, Kerala, India. He is engaged in doctoral studies in the area of graphene-based polymer nanocomposites. He has also conducted research work at the Universiti Teknologi MARA in Malaysia. In 2010, Mr. Yaragalla received a prestigious research fellowship administered jointly by the Council of Scientific and Industrial Research and University Grants Commission of the Government of India. He has published 6 international papers, two book chapters and edited one book to his credit. Raghvendra Kumar Mishra is a Materials Scientist in the Chemical Engineering Department at IIT Delhi, India, and he has previously held research positions at Cranfield University (United Kingdom), Madrid Institute of Advanced Studies (Spain), and Mahatma Gandhi University (India). His research interests focus on nanomaterials and polymer composites, including new applications of nanomaterials, developing nanomaterials-based systems for diverse functionalities, creating biopolymer-based composites, and utilizing advanced fabrication techniques such as electrospinning and 3D printing.
Dr. Sabu Thomas (Ph.D.) is the Director of the School of Energy Materials, School of Nanoscience and Nanotechnology of Mahatma Gandhi University, India. He received his Ph. D. in 1987 in Polymer Engineering from the Indian Institute of Technology (IIT), Kharagpur, India. He is a fellow of the Royal Society of Chemistry, London, and a member of the American Chemical Society. He has been ranked no.1 in India about the number of publications (most productive scientists). Prof. Thomass research group specialized areas of polymers which includes Polymer blends, Fiber filled polymer composites, Particulate-filled polymer composites and their morphological characterization, Ageing and degradation, Pervaporation phenomena, sorption and diffusion, Interpenetrating polymer systems, Recyclability and reuse of waste plastics and rubbers, Elastomer cross-linking, Dual porous nanocomposite scaffolds for tissue engineering, etc. Prof. Thomass research group has extensive exchange programs with different industries, research, and academic institutions all over the world and is performing world-class collaborative research in various fields. Professors Centre is equipped with various sophisticated instruments and has established state-of-the-art experimental facilities which cater to the needs of researchers within the country and abroad. His H Index- 133, Google Citations- 86424, Number of Publications- 1300, and Books-160.
Dr. Nandakumar Kalarikkal is an Associate Professor at the School of Pure and Applied Physics and Joint Director of the International and Inter University Centre for Nanoscience and Nanotechnology of Mahatma Gandhi University, Kottayam, Kerala, India. His research activities involve applications of nanostructured materials, laser plasma, and phase transitions. He is the recipient of research fellowships and associateships from prestigious government organizations such as the Department of Science and Technology and Council of Scientific and Industrial Research of the Government of India. He has active collaborations with national and international scientific institutions in India, South Africa, Slovenia, Canada, France, Germany, Malaysia, Australia, and the United States. He has more than 130 publications in peer-reviewed journals. He also co-edited nine books of scientific interest and co-authored many book chapters. Hanna J. Maria is a Senior Researcher at the School of Energy Materials and the International and Inter University Centre for Nanoscience and Nanotechnology, Mahatma Gandhi University, India. Her research focusses on natural rubber composites and their blends, thermoplastic composites, lignin, nanocellulose, bionanocomposites, nanocellulose, rubber-based composites and nanocomposites.