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E-raamat: Chemistry on Modified Oxide and Phosphate Surfaces: Fundamentals and Applications

(Chemistry Institute, Universidade Federal do Rio Grande do Norte, Natal, Brazil)
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This title in the authoritative Interface Science and Technology Series presents the key features and applications of modified oxide and phosphate surfaces.

* Examines both basic and applied aspects
* Incorporates examples from recent publications
Preface ix
Oxides and Phosphates
1(2)
Surfaces and Modified Surfaces
3(2)
Chemistry on Organofunctionalized Amorphous Oxides Surfaces
5(28)
Introduction
5(3)
Modified amorphous oxide surfaces as metal cation sequesting agents
8(1)
Organofunctionalized metal-modified surfaces for chromatographic applications
8(1)
Modified amorphous oxides for luminescent devices
9(11)
A 3-trimethoxypropylthioethylamine-modified surface
9(3)
In situ synthesis of luminescent complexes on amorphous modified silica surfaces
12(8)
Modified amorphous oxide surfaces as electrochemical sensors
20(4)
Metal cation electrochemical sensors
20(2)
Paracetamol sensors
22(2)
Chemically modified oxide surfaces capable of molecular recognition
24(1)
The influence of magnesium trisilicate and silicon dioxide on the thermal degradation of ascorbic acid
24(9)
References
31(2)
Chemistry on Organofunctionalized Nanostructured Oxides' Surfaces
33(18)
Introduction
33(1)
Inorganic---organic hybrids
34(1)
Sol-gel lamellar silica
34(4)
Eu(II)-doped lamellar silica
35(3)
Titania foam and thiol-functionalized nanoporous titania-silica
38(3)
Thiol-functionalized nanoporous titania-silica
38(2)
Titania foam
40(1)
The effects of nanostructure on adsorption features: metal chemisorption on hexagonal templated zirconia obtained thorough sol-gel process
41(4)
Surface modifications promoted by not bonded species
45(3)
Effects of metal salts, DMF, and DMSO on the anatase-rutile transitions in sol-gel-synthesized TiO2
45(3)
Hexagonal mesoporous silica
48(3)
References
49(2)
Chemistry on Conducting Polymer-Modified Oxide Surfaces
51(6)
Introduction
51(1)
Synthetic approach
51(1)
Effects of adsorbed conducting polymer on the oxide properties
52(1)
Effects of the oxide on the adsorbed polymer properties
52(5)
References
56(1)
Chemistry on Modified Layered Oxides
57(22)
Introduction
57(1)
Titanates and niobates
57(1)
Tungstates and molybdates
58(4)
Molybdenum oxide as a molecular sieve
62(10)
MOO3 intercalation compounds with nic and hmta
62(6)
Adsorption of caffeine, dimethylglyoxime, and rodamin-B on lamellar molybdenum oxide
68(4)
Sol-gel modified molybdenum oxide
72(5)
Graphite oxide
77(2)
References
78(1)
Chemistry on Modified Phosphates
79(12)
Introduction
79(1)
Titanium and zirconium phosphates
79(1)
Vanadyl phosphate
80(4)
Synthesis and characterization of a VOPO4-NH3 hybrid
80(3)
More vanadyl phosphate compounds
83(1)
Barium and calcium phosphate
84(1)
Adsorption of glycine on ``animal'' (bone) phosphate
84(5)
Introduction
84(1)
Experimental
84(1)
Results and discussion
85(4)
A final example
89(2)
References
89(2)
Chemistry on Modified Clay Surfaces
91(18)
Introduction
91(1)
Vermiculite surface modified with carnauba wax for oil cleaning
91(4)
Water as a surface modifier: the hydrophobicity of vermiculite
95(3)
The effect of surface chemical composition on the acid corrosion of pedra sabao (soapstone)
98(5)
Thermal degradation of vegetable oils on clays (biodiesel production)
103(3)
Introduction
103(3)
Miscellaneous examples
106(3)
References
107(2)
Zeolites
109(4)
Introduction
109(1)
Some examples and applications
110(3)
References
112(1)
Further Reading 113(86)
Subject Index 199
Robson Fernandes de Farias was a graduate at Licenciatura Plena Em Química from Universidade Federal do Rio Grande do Norte (1991), master's at Chemistry from Universidade Federal do Rio Grande do Norte (1993) and received his Ph.D. in Chemistry from Universidade Estadual de Campinas (2000), Brazil. He has research interests in the following chemistry subjects: inorganic-organic hybrids, natural gas, gas desulfurization, chemistry history and teaching.