Introduction |
|
1 | (1) |
|
|
2 | (3) |
|
Physical Limits and Search for New Materials |
|
|
5 | (1) |
|
|
6 | (1) |
|
|
7 | (8) |
|
Why Copper (Cu) Interconnects? |
|
|
7 | (8) |
|
|
15 | (4) |
|
Multilayer Metal Architecture |
|
|
15 | (1) |
|
|
16 | (3) |
|
An Alternate Technology for Interconnects |
|
|
19 | (2) |
|
Materials Used in Modern Integrated Circuits |
|
|
21 | (6) |
|
|
23 | (1) |
|
|
24 | (1) |
|
|
25 | (2) |
|
|
27 | (1) |
|
Low-K Dielectric Materials |
|
|
28 | (2) |
|
|
30 | (3) |
|
|
33 | (2) |
|
|
33 | (2) |
|
Challenges and Accomplishments |
|
|
35 | (3) |
|
|
35 | (1) |
|
|
35 | (3) |
|
Technologies of the 21st Century, and the Plan to Meet the Challenges |
|
|
38 | (2) |
|
Ultra-Shallow Junction (USJ) |
|
|
40 | (1) |
|
Circuit Design and Architecture Improvements |
|
|
41 | (1) |
|
Performance and Leakage in Low Standby Power (LSTP) Systems |
|
|
42 | (1) |
|
Introduction of New Materials and Integration Processes |
|
|
43 | (10) |
|
|
44 | (1) |
|
|
45 | (2) |
|
|
47 | (6) |
|
|
53 | (14) |
|
|
55 | (12) |
|
|
67 | (44) |
|
|
67 | (4) |
|
Interlayer Dielectric (ILD) |
|
|
71 | (26) |
|
|
71 | (3) |
|
|
74 | (2) |
|
Selection Criteria for an Ideal Low-K Material |
|
|
76 | (2) |
|
Search for an Ideal Low-K Material |
|
|
78 | (5) |
|
|
83 | (9) |
|
Impact of Low-K ILD Materials on the Cu-Damascene Process |
|
|
92 | (3) |
|
|
95 | (2) |
|
High-K Dielectric Materials |
|
|
97 | (14) |
|
|
97 | (1) |
|
Impact on Scaling and Requirements |
|
|
98 | (1) |
|
Search for a Suitable High-K Dielectric Material |
|
|
99 | (3) |
|
Deposition Technology for High-K Materials |
|
|
102 | (1) |
|
|
102 | (1) |
|
|
103 | (8) |
|
Diffusion and Barrier Layers |
|
|
111 | (50) |
|
|
111 | (14) |
|
|
111 | (2) |
|
|
113 | (1) |
|
Mathematical Modeling of Diffusion in Cu-Interconnects |
|
|
114 | (4) |
|
Grain Boundary (GB) Diffusion |
|
|
118 | (2) |
|
|
120 | (1) |
|
|
121 | (1) |
|
|
122 | (1) |
|
Diffusion of Copper and Its Consequences |
|
|
122 | (2) |
|
|
124 | (1) |
|
Barrier Layer for Cu-Interconnects |
|
|
125 | (25) |
|
|
125 | (1) |
|
|
126 | (1) |
|
Barrier Layer Architecture |
|
|
126 | (2) |
|
|
128 | (4) |
|
Influence of the Barrier Layer Properties on the Reliability of Cu-Interconnects |
|
|
132 | (3) |
|
Low-K Dielectric-Barrier Layer |
|
|
135 | (1) |
|
|
135 | (4) |
|
Influence of the Barrier Layer on the Electrical Conductivity of Cu-Lines |
|
|
139 | (2) |
|
Influence of Barrier Layer Thermal Conductivity on Cu-Line |
|
|
141 | (3) |
|
Classification of Barrier Layer |
|
|
144 | (1) |
|
Properties of Different Barrier Layer Materials |
|
|
145 | (3) |
|
Cap-Layer, Its Properties and Functions |
|
|
148 | (2) |
|
|
150 | (11) |
|
|
151 | (10) |
|
|
161 | (62) |
|
|
161 | (36) |
|
|
161 | (3) |
|
Resolution Limits of Optical Lithography |
|
|
164 | (4) |
|
Deep Ultraviolet (DUV) Lithography |
|
|
168 | (5) |
|
|
173 | (2) |
|
Enhancement Techniques for Resolution |
|
|
175 | (4) |
|
|
179 | (4) |
|
Chemically Amplified Resist (CA) |
|
|
183 | (2) |
|
Extreme Ultraviolet (EUV) Lithography |
|
|
185 | (4) |
|
|
189 | (3) |
|
|
192 | (3) |
|
|
195 | (1) |
|
Step and Flash Imprint Lithography (SFIL) |
|
|
195 | (2) |
|
Etching and Cleaning of Damascene Structures |
|
|
197 | (17) |
|
|
197 | (13) |
|
|
210 | (4) |
|
|
214 | (9) |
|
|
216 | (7) |
|
Deposition Technologies of Materials for Cu-Interconnects |
|
|
223 | (44) |
|
|
223 | (1) |
|
|
224 | (1) |
|
|
224 | (1) |
|
Barrier Layer Requirements |
|
|
225 | (1) |
|
|
225 | (1) |
|
Thin Film Growth and Theory of Nucleation |
|
|
226 | (4) |
|
|
227 | (3) |
|
|
230 | (6) |
|
Physical Vapor Deposition |
|
|
230 | (1) |
|
|
231 | (3) |
|
Ionized Physical Vapor Deposition (IPVD) |
|
|
234 | (2) |
|
Chemical Vapor Deposition (CVD) |
|
|
236 | (4) |
|
Plasma Enhanced CVD (PECVD) System |
|
|
236 | (2) |
|
Metal-Organic Vapor Deposition (MOCVD) |
|
|
238 | (2) |
|
Low Temperature Thermal CVD (LTTCVD) System |
|
|
240 | (1) |
|
Atomic Layer Deposition (ALD) |
|
|
241 | (2) |
|
|
243 | (4) |
|
History of Electroplating and Printed Circuit Boards (PCBs) |
|
|
243 | (1) |
|
|
244 | (1) |
|
Electroplating of Copper Inside Damascene Architecture |
|
|
245 | (2) |
|
Process Chemistry for Superconformal Electrodeposition of Copper |
|
|
247 | (1) |
|
Electrochemical Mechanical Deposition (ECMD) |
|
|
248 | (1) |
|
Influence of the Seed Layer on Electroplating |
|
|
249 | (1) |
|
Electroless Deposition of Copper |
|
|
250 | (1) |
|
Stress in Cu-Interconnects |
|
|
251 | (2) |
|
|
253 | (14) |
|
|
254 | (13) |
|
The Copper Damascene Process and Chemical Mechanical Polishing |
|
|
267 | (34) |
|
The Copper Damascene Process |
|
|
267 | (11) |
|
|
267 | (3) |
|
Conventional Metallization Technology |
|
|
270 | (1) |
|
Cu-Damascene Metallization Technology |
|
|
271 | (5) |
|
General Objectives and Challenges |
|
|
276 | (2) |
|
Chemical Mechanical Polishing (CMP) and Planarization |
|
|
278 | (18) |
|
|
278 | (1) |
|
Chemical Mechanical Polishing (CMP)Technology |
|
|
279 | (6) |
|
|
285 | (1) |
|
|
286 | (1) |
|
Particle Size Inside the Slurry |
|
|
287 | (2) |
|
Relative Velocity of the Pad and Wafer |
|
|
289 | (1) |
|
|
289 | (1) |
|
|
289 | (1) |
|
|
289 | (1) |
|
Shallow Trench Isolation (STI) |
|
|
290 | (1) |
|
|
291 | (1) |
|
|
291 | (1) |
|
|
292 | (1) |
|
|
293 | (1) |
|
|
293 | (2) |
|
CMP Pattern Density Issues |
|
|
295 | (1) |
|
|
296 | (5) |
|
|
296 | (5) |
|
Conduction and Electromigration |
|
|
301 | (46) |
|
|
301 | (23) |
|
|
301 | (2) |
|
Conduction Mechanism and Restrictions |
|
|
303 | (8) |
|
Effect of Grain Boundary (GB) Resistance on the Conductivity of Cu-Interconnects |
|
|
311 | (1) |
|
Effect of Grain Size and Morphology of the Substrate |
|
|
311 | (1) |
|
Morphology of the Cu-Film and Its Influence on the Conduction (Electrical) Mechanism of Cu-Interconnects |
|
|
312 | (5) |
|
Effect of Film Thickness on the Conductivity of Cu-Interconnects |
|
|
317 | (1) |
|
Diffusion Related Impacts on the Conductivity of a Cu-Line |
|
|
318 | (1) |
|
Cu-Line Stress and Its Consequences |
|
|
319 | (2) |
|
Conduction of Heat Through Cu-Interconnects |
|
|
321 | (1) |
|
Thermal Cycling (Annealing) Related Phenomena |
|
|
322 | (2) |
|
|
324 | (12) |
|
|
324 | (1) |
|
Mechanism of Electromigration (EM) and Its Effects |
|
|
325 | (4) |
|
|
329 | (1) |
|
Analytical Model on Stress Related EM |
|
|
330 | (3) |
|
Effect of Microstructure of the Film on Mass Migration |
|
|
333 | (2) |
|
Effect of Solute on Electromigration |
|
|
335 | (1) |
|
Melting Temperature of a Metal and Its Effect on Grain Growth |
|
|
335 | (1) |
|
Effect of Temperature on EM |
|
|
336 | (1) |
|
Current Density and Its Effect on EM |
|
|
336 | (1) |
|
|
336 | (11) |
|
|
337 | (10) |
|
|
347 | (58) |
|
|
347 | (15) |
|
|
347 | (2) |
|
Methods of Improving Interconnect Routings |
|
|
349 | (2) |
|
Interconnect Routing Design |
|
|
351 | (8) |
|
Challenges with High Density Routing |
|
|
359 | (2) |
|
|
361 | (1) |
|
Transmission Line Coupling |
|
|
361 | (1) |
|
Clocking of High-Speed System |
|
|
361 | (1) |
|
|
362 | (31) |
|
|
362 | (3) |
|
Reliability Issues Related to Cu-Interconnects |
|
|
365 | (23) |
|
|
388 | (5) |
|
|
393 | (12) |
|
|
394 | (11) |
Glossary (Copper Interconnects) |
|
405 | (10) |
Index |
|
415 | |