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E-raamat: Crystallization in Multiphase Polymer Systems

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  • Kirjastus: Elsevier Science Publishing Co Inc
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  • ISBN-13: 9780128094310
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  • Formaat: EPUB+DRM
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  • Keel: eng
  • ISBN-13: 9780128094310
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Crystallization in Multiphase Polymer Systems is the first book that explains in depth the crystallization behavior of multiphase polymer systems. Polymeric structures are more complex in nature than other material structures due to their significant structural disorder. Most of the polymers used today are semicrystalline, and the subject of crystallization is still one of the major issues relating to the performance of semicrystalline polymers in the modern polymer industry.

The study of the crystallization processes, crystalline morphologies and other phase transitions is of great significance for the understanding the structure-property relationships of these systems. Crystallization in block copolymers, miscible blends, immiscible blends, and polymer composites and nanocomposites is thoroughly discussed and represents the core coverage of this book. The book critically analyzes the kinetics of nucleation and growth process of the crystalline phases in multi-component polymer systems in different length scales, from macro to nanoscale.

Various experimental techniques used for the characterization of polymer crystallization process are discussed. Written by experts in the field of polymer crystallization, this book is a unique source and enables professionals and students to understand crystallization behavior in multiphase polymer systems such as block copolymers, polymer blends, composites and nanocomposites.

  • Covers crystallization of multiphase polymer systems, including copolymers, blends and nanocomposites
  • Features comprehensive, detailed information about the basic research, practical applications and new developments for these polymeric materials
  • Analyzes the kinetics of nucleation and growth process of the crystalline phases in multi-component polymer systems in different length scales, from macro to nanoscale

Muu info

A unique book covering the latest developments in crystallization of multiphase polymer systems, including copolymers, blends and nanocomposites
List of Contributors
xv
Preface xix
Chapter 1 Introduction on Crystallization in Multiphase Polymer Systems
1(16)
P. Mohammed Arif
Nandakumar Kalarikkal
Sabu Thomas
1 Introduction to Polymer Crystallization
1(1)
2 Crystallization in Multiphase Polymer Systems
2(3)
2.1 Nucleation in Polymer Crystallization
3(1)
2.2 Growth of Lamella
3(2)
3 Different Types of Polymer Crystallization in Multiphase Systems
5(5)
3.1 Fractionated Crystallization
5(1)
3.2 Transcrystallization
5(1)
3.3 Confined Crystallization
6(1)
3.4 Strain-Induced Crystallization
7(2)
3.5 Cocrystallization
9(1)
4 Crystallization in Block Copolymers
10(1)
5 Crystallization in Polymer Blends
10(1)
6 Crystallization in Composites and Nanocomposites
11(2)
7 Conclusion and Future Challenges
13(4)
References
13(4)
Chapter 2 Theoretical Aspects of Polymer Crystallization in Multiphase Systems
17(32)
Guodong Liang
Suping Bao
Fangming Zhu
1 Introduction
17(1)
2 Crystallization Mechanisms in Multiphase Polymer Systems
17(1)
3 Crystallization Thermodynamics of Multiphase Polymer Systems
18(2)
4 Crystallization Kinetics of Multiphase Polymer Systems
20(13)
4.1 Isothermal Crystallization
20(7)
4.2 Nonisothermal Crystallization
27(6)
5 Crystallization Models of Multiphase Polymer Systems
33(2)
5.1 Breakout Crystallization
33(1)
5.2 Confined Crystallization
34(1)
6 Crystallization Morphology of Multiphase Polymer Systems
35(7)
6.1 Lamellar Crystals
35(1)
6.2 Cylindrical Micelle
36(1)
6.3 Capsules
36(1)
6.4 Nanoribbons
37(3)
6.5 Flowers
40(2)
7 Conclusion and Outlook
42(7)
References
43(6)
Chapter 3 Experimental Techniques for Understanding Polymer Crystallization
49(24)
N. Sanjeeva Murthy
1 Introduction
49(1)
2 Density Methods
50(1)
3 Thermal Analysis
51(2)
4 X-Ray Diffraction
53(4)
4.1 Wide-Angle X-Ray Diffraction
54(1)
4.2 Small-Angle Scattering
55(2)
5 Spectroscopic Methods
57(6)
5.1 Infrared Spectroscopy
58(1)
5.2 Raman Scattering
59(2)
5.3 Nuclear Magnetic Resonance
61(2)
6 Mapping of Crystallinity
63(1)
7 Crystallization Kinetics
64(4)
7.1 Calorimetry
64(1)
7.2 Microscopy
65(1)
7.3 Dilatometry
65(1)
7.4 Light Scattering
66(1)
7.5 X-Ray Scattering
67(1)
8 Concluding Remarks
68(5)
References
69(4)
Chapter 4 Effects of Mass Transport on Crystallization From Miscible Polymer Blends
73(20)
Jerold M. Schultz
1 Introduction
73(1)
2 Nucleation of Spherulites in Miscible Blends
73(7)
2.1 Introduction
73(1)
2.2 Effect of the Transport of Substituents
74(4)
2.3 Effect of Concurrent Liquid Phase Separation
78(2)
3 Growth of Spherulites in Miscible Polymer Blends
80(8)
3.1 Introduction: Mass Transfer at the Growth Front---The Role of the Diffusion Length
80(3)
3.2 Growth at the Lamellar Level
83(3)
3.3 Growth at the Fibril (Growth Arm) Level
86(2)
4 Concluding Remarks
88(5)
References
89(4)
Chapter 5 Crystallization Behavior of Crystalline---Amorphous and Crystalline---Crystalline Block Copolymers Containing Poly(L-lactide)
93(30)
Selvaraj Nagarajan
Deepthi Krishnan
Vijayan Pillai Sivaprasad
E. Bhoje Gowd
1 Introduction
93(1)
2 Morphological Development in Crystalline---Amorphous and Crystalline---Crystalline Block Copolymers
94(2)
3 Crystallization and Microphase Separation of Block Copolymers Containing PLLA Blocks
96(16)
3.1 Immiscible or Strongly Segregated Systems
96(1)
3.2 Poly(L-lactide)-fl/oc&-Polyethylene Block Copolymer (Tm of PLLA = Tm of PE)
96(1)
3.3 Poly(styrene)-Block-Poly(L-lactide) Diblock Copolymer [ Tc of PLLA < Tg of PS (Hard Confinement) and Tc of PLLA ≥ Tg of PS (Soft Confinement)]
97(1)
3.4 Poly(4-methyl-l-pentene)-Block-poly(L-lactide) Diblock Copolymer (Tg of sPMP = Tg of PLLA)
98(1)
3.5 Poly(L-lactide-b-dimethylsiloxane-b-L-lactide) Triblock Copolymer (Tg of PLLA > Tg or Tm of PDMS)
99(2)
3.6 Syndiotactic Poly(p-methyl styrene)-Block-poly(L-lactide) Block Copolymer (Tg of sPPMs > Tg of PLLA)
101(3)
3.7 Miscible or Weakly Segregated Systems
104(1)
3.8 Poly(L-lactide)-b-poly(ethylene Oxide) Diblock Copolymers and Poly(L-lactide)-b-poly(ethylene Oxide)-b-poly(L-lactide) Triblock Copolymers
105(4)
3.9 Poly(L-lactide)-b-poly(ε-caprolactone) Block Copolymers
109(1)
3.10 Poly(L-lactide)-b-poly(vinylidene fluoride)-b-poly(L-lactide) Triblock Copolymers
109(1)
3.11 Poly(L-lactide-b-2-dimethylaminoethyl methacrylate) Diblock Copolymers and Poly(L-lactide-b-2-dimethylaminoethyl methacrylate-b-L-lactide) Triblock Copolymers
110(2)
4 Crystallization and Microphase Separation of Conducting Block Copolymers Containing PLLA Blocks
112(5)
4.1 Poly(3-hexylthiophene)-b-poly(L-lactide) Diblock Copolymers
112(5)
5 Conclusions and Outlook
117(6)
Acknowledgments
117(1)
References
117(6)
Chapter 6 Crystallization and Morphology of Block Copolymers and Terpolymers With More Than One Crystallizable Block
123(58)
Jordana K. Palacios
Agurtzane Mugica
Manuela Zubitur
Alejandro J. Muller
1 Introduction
123(1)
2 Crystallization and Morphology of Double Crystalline AB and ABA Diblock and Triblock Copolymers
124(40)
2.1 Medium and Strongly Segregated Systems
124(17)
2.2 Miscible or Weakly Segregated Systems
141(23)
3 Crystallization and Morphology of Triple Crystalline ABC Triblock Terpolymers
164(6)
3.1 Block Terpolymers of Poly(Ethylene Oxide), Poly(ε-Caprolactone), and Poly(L-Lactide)
164(6)
4 Conclusions
170(11)
Acknowledgments
171(1)
References
171(10)
Chapter 7 Crystallization Behavior of Semicrystalline Immiscible Polymer Blends
181(32)
Nguyen-Dung Tien
Robert E. Prud'homme
1 Introduction
181(2)
2 Fractionated Crystallization
183(2)
3 Adding Copolymers
185(3)
4 Adding Nanoparticles
188(5)
5 Effect of Flow
193(5)
6 Cocontinuous Morphologies
198(3)
7 Blends in Thin and Ultrathin Films
201(3)
8 Conclusions
204(9)
Nomenclature
205(1)
Acknowledgments
206(1)
References
207(6)
Chapter 8 Crystallization Behavior of Miscible Semicrystalline Polymer Blends
213(26)
Zhaobin Qiu
1 Introduction
213(1)
2 Crystallization Behavior of Miscible Crystalline/Amorphous Polymer Blends
214(9)
3 Crystallization Behavior of Miscible Crystalline/Crystalline Polymer Blends
223(11)
3.1 Systems With Small Melting Point Difference
224(6)
3.2 Systems With Large Melting Point Difference
230(4)
4 Conclusions
234(5)
Acknowledgments
236(1)
References
236(3)
Chapter 9 Fractionated Crystallization in Polymer Blends
239(30)
Deepak Langhe
1 Introduction
239(1)
2 Droplet Dispersions in Liquid Media
240(2)
3 Fractionated Crystallization in Blends
242(6)
3.1 Fractionated Crystallization in Crystalline Polymer Matrices
247(1)
4 Blends From Nanolayer Films
248(10)
4.1 Additives, Catalyst Residues, and Substrates
250(2)
4.2 Origin of Heterogeneous Nucleation in Polypropylene
252(3)
4.3 Nature of Heterogeneous Nucleation: Effect of Nucleating Agents
255(1)
4.4 Probing Homogeneous Nucleation
255(3)
5 Miscible Blends
258(1)
6 Droplets From Thin Films
259(2)
7 Block Copolymers
261(2)
8 Fractionated Crystallization Using Templates
263(1)
9 Conclusions
264(5)
References
265(4)
Chapter 10 Crystallization Behavior of Polymer Nanocomposites
269(44)
V.P. Cyras
D.A. D'Amico
L.B. Manfredi
1 Introduction
269(1)
2 Crystallization in Polymer Nanocomposites
269(36)
2.1 Polymer Nanolayered Nanocomposites
269(10)
2.2 Metal---Polymer Nanocomposites
279(3)
2.3 Carbon Nanotube---Based Nanocomposites
282(6)
2.4 Calcium Carbonate Nanocomposites
288(4)
2.5 Silica Nanocomposites
292(1)
2.6 Nanocellulose-Based Nanoparticles as Reinforcement in Polymer Nanocomposites
293(12)
3 Concluding Remarks
305(8)
Acknowledgments
306(1)
References
306(7)
Chapter 11 Crystallization of Polymer Blend Nanocomposites
313(28)
Sonalee Das
Sushanta K. Samal
Smita Mohanty
Sanjay K. Nayak
1 Introduction
313(1)
2 Fundamentals of Crystallization
314(2)
2.1 Polymer Crystallization
314(1)
2.2 Crystallization in Polymer Blends
314(1)
2.3 Crystallization in Polymer Blend Nanocomposites
315(1)
3 Crystallization in Polymer Blend Nanocomposites: Effect of Nanoreinforcement on the Crystallization Behavior of Polymer Blend
316(10)
3.1 Amorphous/Crystalline Blend Nanocomposites
316(2)
3.2 Crystalline/Crystalline Blend Nanocomposites
318(6)
3.3 Thermoplastic---Thermoset Polymer Blend Nanocomposites
324(2)
4 Crystallization Kinetics in Polymer Blend Nanocomposite
326(8)
5 Conclusions
334(7)
References
335(6)
Chapter 12 Transcrystallization in Polymer Composites and Nanocomposites
341(26)
Yuezhen Bin
Hai Wang
1 Introduction
341(1)
2 Materials and Preparation Techniques
341(7)
2.1 Materials
341(4)
2.2 Preparation Techniques and Apparatus
345(3)
3 Characterization
348(10)
3.1 Morphology and Crystal Modification
348(3)
3.2 Lamellar Structures in Transcrystalline Region
351(3)
3.3 Mechanical Property
354(4)
4 Formation Mechanisms and Modeling
358(3)
4.1 Formation Mechanism
358(1)
4.2 Modeling
359(2)
5 Conclusions
361(6)
List of Abbreviations
361(1)
References
362(5)
Chapter 13 Crystallization of Polymers in Confined Space
367(66)
Pratick Samanta
Chien-Liang Liu
Bhanu Nandan
Hsin-Lung Chen
1 Introduction
367(2)
2 Confined Crystallization in Block Copolymer
369(25)
2.1 Crystalline-Block-Amorphous Diblock Copolymers
370(20)
2.2 Crystalline-b-Crystalline Block Copolymer
390(4)
3 Confined Crystallization in Anodic Aluminum Oxide Nanoporous Membranes
394(12)
3.1 Crystallization Behavior in Anodic Aluminum Oxide Membranes
397(5)
3.2 Preferred Orientation of Crystallites in Anodic Aluminum Oxide
402(4)
4 Confined Crystallization in Electrospun Nanofibers
406(5)
5 Confined Crystallization in Some Other Systems
411(3)
5.1 Thin Films and Multilayers
411(2)
5.2 Emulsions
413(1)
5.3 Polymer Blends
414(1)
6 Conclusions and Future Outlook
414(19)
List of Abbreviations
415(2)
Acknowledgments
417(1)
References
417(16)
Chapter 14 Crystallization Behavior of Semicrystalline Polymers in the Presence of Nucleation Agent
433(38)
Zhiyong Wei
Ping Song
1 Introduction
433(1)
2 Experiments
434(3)
2.1 Materials and Sample Preparation
434(2)
2.2 Measurements
436(1)
3 Crystallization Behavior and Nucleation Analysis of Poly(L-Lactic Acid) With a Multiamide Nucleating Agent
437(13)
3.1 Isothermal Crystallization Behavior
437(6)
3.2 Melting Behavior After Isothermal Crystallization
443(1)
3.3 Nucleation Efficiency and Nucleation Activity
444(5)
3.4 Spherulite Morphology
449(1)
4 Rapid Crystallization of Poly(L-Lactic Acid) Induced by a Nanoscale Zinc Citrate Complex as Nucleating Agent
450(9)
4.1 Nonisothermal Crystallization and Melting Behavior
450(1)
4.2 Isothermal Crystallization Behavior
450(4)
4.3 Spherulite Morphology and Nucleation Mechanism
454(2)
4.4 Mechanical Properties
456(3)
5 Crystallization and Melting Behavior of Isotactic Polypropylene Nucleated With Individual and Compound Nucleating Agents
459(8)
5.1 Isothermal Crystallization Kinetics
459(3)
5.2 Nonisothermal Crystallization Behavior
462(1)
5.3 Nonisothermal Crystallization Activation Energy
463(2)
5.4 Melting Behavior
465(2)
6 Conclusions
467(4)
References
468(3)
Chapter 15 Strain-Induced Crystallization
471(38)
Aitor Larranaga
Erlantz Lizundia
1 Introduction
471(1)
2 Stress-Strain Relation During SIC
472(2)
3 Chain Relaxation, Kinetics, Morphology, Chain Conformation, and Effect of Processing Parameters
474(15)
3.1 Chain Relaxation
474(1)
3.2 Crystallization Kinetics
475(3)
3.3 Morphology Changes
478(5)
3.4 Chain Conformation and Orientation
483(4)
3.5 Effect of Processing Parameters
487(2)
4 Applications and Properties
489(10)
4.1 Thermal Transitions
489(2)
4.2 Mechanical Properties
491(3)
4.3 Barrier Properties
494(2)
4.4 Piezoelectricity
496(3)
5 Conclusions and Perspectives
499(10)
References
499(9)
Further Reading
508(1)
Chapter 16 Effect of Ionic Liquids on the Crystallization Kinetics of Various Polymers and Polymer Electrolytes
509(26)
Shalu
Rajendra Kumar Singh
1 Introduction
509(1)
2 Polymer Crystallization: Some Basics
509(3)
3 Different Methods Used to Study Crystallization Kinetics of Polymer and Polymer Electrolytes
512(3)
3.1 Crystallization Kinetics by Isothermal Method
512(2)
3.2 Crystallization Kinetics by Nonisothermal Method
514(1)
3.3 Growth Rate of Crystallized Spherulites by Polarized Optical Microscopy
514(1)
3.4 Crystallization Kinetics Study Probed by Dielectric Spectroscopy
515(1)
4 Effect of Ionic Liquids on the Crystallization Kinetics of Different Polymers and Polymer Electrolytes
515(14)
4.1 Effect of IL on Crystallization Kinetic Behavior of Polymers/Polymer Electrolytes Probed Using Isothermal Method
517(4)
4.2 Effect of IL on Crystallization Kinetic Behavior of Polymers/Polymer Electrolytes Probed Using Nonisothermal Method
521(6)
4.3 Growth Rate of Crystallized Spherulites by Polarized Optical Microscopy
527(2)
5 Conclusions
529(6)
Acknowledgments
531(1)
References
531(4)
Chapter 17 Stereocomplex Crystallization of Polymers With Complementary Configurations
535(40)
Qing Xie
Chengtao Yu
Pengju Pan
1 Introduction
535(2)
2 Stereocomplexable Polymers
537(14)
2.1 Aliphatic Polyester
537(9)
2.2 Aliphatic Polycarbonate
546(2)
2.3 Polyamide and Poly(Amino Acid)
548(2)
2.4 Polyketone
550(1)
2.5 Poly(Methyl Methacrylate)
550(1)
2.6 Other Polymers
551(1)
3 Factors Influencing Stereocomplex Crystallization of Poly(Lactic Acid)
551(3)
3.1 Molecular Weight
551(1)
3.2 Blend Ratio
552(1)
3.3 Stereoregularity
553(1)
3.4 Crystallization Condition
553(1)
4 Promotion of Stereocomplex Formation in Poly(Lactic Acid)
554(10)
4.1 Stereoblock Copolymerization
554(2)
4.2 Incorporation of Noncovalent Bonding Units
556(1)
4.3 Change of Macromolecular Architecture
557(1)
4.4 Polymer Blending
558(2)
4.5 Use of Stretch or Shear Flow
560(1)
4.6 Use of Polymer Processing Additives
561(2)
4.7 Other Methods
563(1)
5 Concluding Remarks
564(11)
Acknowledgments
564(1)
References
565(10)
Index 575
Dr. Sabu Thomas (Ph.D.) is the Director of the School of Energy Materials, School of Nanoscience and Nanotechnology of Mahatma Gandhi University, India. He received his Ph. D. in 1987 in Polymer Engineering from the Indian Institute of Technology (IIT), Kharagpur, India. He is a fellow of the Royal Society of Chemistry, London, and a member of the American Chemical Society. He has been ranked no.1 in India about the number of publications (most productive scientists). Prof. Thomass research group specialized areas of polymers which includes Polymer blends, Fiber filled polymer composites, Particulate-filled polymer composites and their morphological characterization, Ageing and degradation, Pervaporation phenomena, sorption and diffusion, Interpenetrating polymer systems, Recyclability and reuse of waste plastics and rubbers, Elastomer cross-linking, Dual porous nanocomposite scaffolds for tissue engineering, etc. Prof. Thomass research group has extensive exchange programs with different industries, research, and academic institutions all over the world and is performing world-class collaborative research in various fields. Professors Centre is equipped with various sophisticated instruments and has established state-of-the-art experimental facilities which cater to the needs of researchers within the country and abroad. His H Index- 133, Google Citations- 86424, Number of Publications- 1300, and Books-160.

Mohammed Arif P is currently working as Senior Research Fellow at the International and Inter University Centre for Nanoscience and Nanotechnology, Mahatma Gandhi University, Kerala, India. His research focuses on Polymer Blends, Polymer Nanocomposites, Conductive Polymers and EMI shielding. Apart from a patent on Polymer Nanocomposites to his credit, he has more than four publications in peer reviewed journals. He has also authored three book chapters. Dr. E. Bhoje Gowd is a Polymer Physicist. His research interests include: crystallization and crystallization kinetics of semicrystalline polymers and multiphase polymeric systems (in particular biodegradable polymers, block copolymers, and nano-composites), polymer self-assembly, nanostructured materials, polymorphic phase transitions in semicrystalline polymers, polymer/inorganic hybrid nanocomposites, polymer-solvent complexes. He received his B.Sc. and M.Sc. (Tech) in Polymer Science and Technology from Sri Krishnadevaraya University, Anantapur, Andhra Pradesh and his Ph.D. from University of Pune, Pune (work carried out at National Chemical Laboratory under the guidance of Dr. C. Ramesh). He worked as a post-doctoral fellow in Prof. Kohji Tashiros group at Toyota Technological Institute, Nagoya, Japan and as an Alexander von Humboldt Fellow in Prof. Manfred Stamms group at Leibniz Institute of Polymer Research, Dresden, Germany. After a short stay at Indian Institute of Science, Bangalore as a Centenary post-doctoral fellow in Prof. S. Ramakrishnans group, he joined CSIR-NIIST, Thiruvananthapuram as a DST Ramanujan Fellow. In 2011, he accepted the senior scientist position at CSIR-NIIST. In 2014, he has been awarded IUSSTF research fellowship by Indo-US Science and Technology Forum. He is also the recipient of Materials Research Society of India (MRSI) Medal in 2016. He has authored more than 50 publications in peer reviewed journals and 3 book chapters. Dr. Gowd has given several invited lectures in more than 8 countries around the world. Dr. Nandakumar Kalarikkal is an Associate Professor at the School of Pure and Applied Physics and Joint Director of the International and Inter University Centre for Nanoscience and Nanotechnology of Mahatma Gandhi University, Kottayam, Kerala, India. His research activities involve applications of nanostructured materials, laser plasma, and phase transitions. He is the recipient of research fellowships and associateships from prestigious government organizations such as the Department of Science and Technology and Council of Scientific and Industrial Research of the Government of India. He has active collaborations with national and international scientific institutions in India, South Africa, Slovenia, Canada, France, Germany, Malaysia, Australia, and the United States. He has more than 130 publications in peer-reviewed journals. He also co-edited nine books of scientific interest and co-authored many book chapters.