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E-raamat: Current Developments in Photocatalysis and Photocatalytic Materials: New Horizons in Photocatalysis

Edited by Xinchen Wang (Dean of the College of Chemistry, State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University Fuzhou, China), Edited by Masakazu Anpo (Special Honor Professor and International Advisor, Fuzhou University, Fuzhou, China
Emeritus Pro), Edited by Xianzhi Fu

Formaat: EPUB+DRM
Ilmumisaeg: 29-Nov-2019
Kirjastus: Elsevier Science Publishing Co Inc
Keel: eng
ISBN-13: 9780128190036

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Formaat: EPUB+DRM
Ilmumisaeg: 29-Nov-2019
Kirjastus: Elsevier Science Publishing Co Inc
Keel: eng
ISBN-13: 9780128190036

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Photocatalytic materials can improve the efficiency and sustainability of processes and offer novel ways to address issues across a wide range of fields – from sustainable chemistry and energy production to environmental remediation. Current Developments in Photocatalysis and Photocatalytic Materials provides an overview of the latest advances in this field, offering insight into the chemistry and activity of the latest generation of photocatalytic materials.

After an introduction to photocatalysis and photocatalytic materials, the book goes on to outline a wide selection of photocatalytic materials, covering not only typical metal oxide photocatalysts such as TiO2, but also exploring newly developed organic semiconducting photocatalysts, such as g-C3N4.

Drawing on the experience of an expert team of contributors, Current Developments in Photocatalysis and Photocatalytic Materials highlights the new horizons of photocatalysis, in which photocatalytic materials will come to play an important role in our day-to-day lives.

Reviews developments in both organic- and inorganic-based materials for use in photocatalysis
Presents the fundamental chemistry and activity of a broad range of key photocatalytic materials, including both typical and novel materials
Highlights the role photocatalytic materials can play in sustainable applications

List of contributors

xiii

About the editors

xxvii

Preface

xxix

1 Introduction

(6)

Xinchen Wang

Masakazu Anpo

Xianzhi Fu

References

(1)

2 Rutile TiO2-based new photocatalysts for visible light water oxidation

(16)

Akinobu Miyoshi

Megumi Okazaki

Kazuhiko Maeda

1 Introduction

(3)

2 Ta/N-codoped TiO2

(3)

3 N/F-codoped TiO2

(3)

4 Nanoparticle-sensitized TiO2

(3)

5 Summary and outlook

(1)

References

(3)

3 Factors affecting photocatalytic activity of TiO2

(16)

Suzuko Yamazaki

Daisuke Takaki

Naoto Nishiyama

Yukari Yamazaki

1 Introduction

(1)

2 Synthesis and characterization

(1)

3 Factors affecting photocatalytic degradation of organic pollutants on TiO2

(2)

4 Factors affecting photocatalytic water oxidation on TiO2

(5)

5 Factors affecting photocatalytic degradation of organic pollutants on metal ion-doped TiO2 under VL irradiation

(3)

6 Mechanistic aspect

(1)

7 Conclusion

(1)

Acknowledgments

(1)

References

(2)

4 Controllable synthesis of TiO2: toward an efficient photocatalyst

(18)

Peng Sun

Jun Zhang

Rui Zhang

Yinjuan Xie

Wenxiu Liu

Matiullah Khan

Qipeng Lu

Wenbin Cao

1 Introduction

(1)

2 Doped TiO2

(3)

3 Facet engineering

(6)

4 The design of TiO2-based heterojunction

(4)

5 Summary and prospects

(1)

References

(4)

5 TiO2-based photocatalytic conversion processes: insights from in situ infrared spectroscopy

(20)

Xuesi Yao

Hailiang Jin

Cheng Liu

Steven S.C. Chuang

1 Introduction

(3)

2 Spectroscopic characterization of TiO2

(2)

3 Microscopic structure of TiO2

(3)

4 DRIFTs, transmission, and ATR

(2)

5 Mechanism of photoelectrochemical reaction on TiO2

(4)

6 Conduction band and shallow trap electrons

(2)

7 Summary

(1)

Acknowledgments

(1)

References

(4)

6 Photoreduction of CO2 on non-TiO2-based metal oxides

(12)

Bao Pan

Jiani Qin

Chuanyi Wang

1 Introduction

(1)

2 Thermodynamics and kinetics of CO2 reduction

(2)

3 CO2 reduction on non-TiO2-based metal oxides

(4)

4 Selectivity in CO2 photoreduction

(2)

5 Conclusion and prospects

(1)

References

(4)

7 Titania-based photocatalyst for dynamic degradation of volatile organic compounds

(18)

Asad Mahmood

Xiao Wang

Xiaofeng Xie

Jing Sun

1 Introduction

(2)

2 Graphene and graphene oxide-based TiO2 composites

(6)

3 Quantum dots and TiO2 composites

(2)

4 Ag and TiO2 composites

(3)

5 Concluding remarks

102

(1)

References

103

(4)

8 Solvothermal alcoholysis preparation of TiO2 with tailored structures and enhanced activity in environmental and energy photocatalysis

107

(20)

Bian Zhenfeng

Li Hexing

1 Introduction

107

(1)

2 Controllable synthesis of TiO2

108

(7)

3 Environmental and energy photocatalysis

115

(8)

4 Conclusions

123

(1)

Acknowledgment

124

(1)

References

124

(3)

9 TiO2 polymorphs for hydrogen photoproduction

127

(14)

Konstantinos C. Christoforidis

Paolo Fornasiero

1 Introductions

127

(1)

2 General remarks

128

(2)

3 TiO2 polymorphs-phase composition

130

(8)

4 Concluding remarks and outlook

138

(1)

References

138

(3)

10 Progress in fundamental studies and practical applications of SrTiO3 photocatalysts to overall water splitting

141

(18)

Park Yohan

Hisatomi Takashi

Domen Kazunari

1 A brief history of the SrTiO3 photocatalyst

141

(1)

2 Surface modification

142

(2)

3 Morphological control

144

(4)

4 Doping

148

(3)

5 Large-scale application

151

(3)

6 Future prospects

154

(1)

Acknowledgments

154

(1)

References

155

(4)

11 Environmental-friendly synthesis of high-efficient composite-type photocatalysts

159

(20)

Shu Yin

Atsushi Muramatsu

1 Introduction

159

(1)

2 Environmental-friendly synthesis of visible light-induced photocatalysts

159

(9)

3 Enhanced visible light-induced activity of composite-type photocatalysts

168

(7)

4 Remarks and outlook

175

(1)

References

175

(4)

12 Photocatalytic conversion of CO2 by H2O over heterogeneous photocatalysts

179

(12)

Rui Pang

Kentaro Teramura

Tsunehiro Tanaka

1 Basic principles of photocatalytic conversion of CO2 by H20

179

(2)

2 Effective photocatalytic conversion of CO2 by H20

181

(5)

3 Conclusion and perspectives

186

(2)

References

188

(3)

13 Seizing solar hydrogen from water promoted by magic spin transporting, chiral-induced spin state-selective filtering, and upconversion

191

(20)

Wenyan Zhang

Gongxuan Lu

1 Introduction

191

(1)

2 Inducing spin transfer in photocatalytic system to promote hydrogen evolution

192

(8)

3 Chiral-induced spin selectivity effect on promoting water-splitting effect

200

(5)

4 The important role of upconversion material in promoting water oxidation

205

(1)

5 The future of spin transfer, CISS effect, and upconversion strategies on promoting water splitting

206

(1)

Acknowledgments

207

(2)

References 207 Further reading

209

(2)

14 Recent advances in the development of photocatalytic NOx abatement

211

(20)

Van-Huy Nguyen

Joseph Che-Chin Yu

Chao-Wei Huang

Jeffrey C.S. Wu

1 Introduction

211

(1)

2 Tailoring the photocatalysts for photocatalytic NOx abatement

212

(3)

3 Designing of photoreactors for photocatalytic NOx abatement

215

(1)

4 Elucidating of reaction pathways for photocatalytic NOx abatement

216

(7)

5 Appling in practical industrial for photo-deNOx processes

223

(3)

6 Summary and perspective

226

(1)

References

227

(4)

15 ZnO nanomaterials: strategies for improvement of photocatalytic and photoelectrochemical activities

231

(14)

Xiuquan Gu

Tomas Edvinsson

Jiefang Zhu

1 Introduction

231

(2)

2 Main applications of ZnO-based photocatalysts

233

(4)

3 Strategies for optimizing the PC activities of ZnO

237

(4)

4 Summary and outlook

241

(1)

Acknowledgment

242

(1)

References

242

(3)

16 BiVO4, a ternary metal oxide as an efficient photocatalytic material

245

(22)

Yuwaraj K. Kshetri

Chhabilal Regmi

Tae-Ho Kim

Soo Wohn Lee

1 Introduction

245

(1)

2 BiVO4 as a photocatalyst

246

(1)

3 Crystal and electronic structure of BiVO4

246

(1)

4 Strategies for improving the charge kinetics of BiVO4

247

(17)

5 Conclusions

264

(1)

References

264

(3)

17 Photocatalytic and photo-fenton catalytic degradation of organic pollutants by non-TiO2 photocatalysts under visible light irradiation

267

(18)

Tayyebeh Soltani

Byeong-Kyu Lee

1 Introduction

267

(1)

2 Developed semiconductor materials of photocatalysis

267

(3)

3 Developments of new visible light-driven photocatalysts

270

(9)

4 Factors affecting the photodegradation performance

279

(1)

5 Adsorption isotherm in dark

280

(1)

6 Kinetic models

281

(1)

7 Stability and reusability

282

(1)

8 Conclusions

282

(1)

References

282

(3)

18 Preparation and photocatalytic performance of monolayer inorganic oxide nanosheets

285

(18)

Song Yujie

Liang Shijing

Wu Ling

1 Introduction

285

(2)

2 2D oxide-based nanosheets

287

(1)

3 Preparation methods for the 2D oxide-based nanosheets

287

(3)

4 Applications of the 2D transition metal oxide nanosheets in photocatalysis

290

(5)

5 Surface coordination on 2D metal oxide nanosheets

295

(4)

6 Conclusion and prospects

299

(1)

References

300

(3)

19 TiO2/carbon composite nanomaterials for photocatalysis

303

(20)

Chencheng Dong

Mingyang Xing

Juying Lei

Jinlong Zhang

1 Introduction

303

(1)

2 Carbon dots-TiO2 nanomaterials

303

(5)

3 g-C3N4/TiO1 nanomaterials

308

(6)

4 Graphene/Ti02 nanomaterials

314

(5)

References

319

(4)

20 The design and development of MOF photocatalysts and their applications for water-splitting reaction

323

(16)

Masaya Matsuoka

Shinya Mine

Takashi Toyao

Yu Horiuchi

1 Introduction

323

(1)

2 H2 production reaction on visible light-responsive MOF photocatalysts

324

(8)

3 O2 production reaction on visible light-responsive MOF photocatalysts

332

(3)

4 Hydrogenation reaction on visible light-responsive MOF photocatalysts

335

(2)

5 Summary

337

(1)

References

337

(2)

21 Light-induced organic transformations over some MOF materials

339

(14)

Mingming Hao

Zhaohui Li

1 Introduction of MOFs as photocatalysts

339

(2)

2 Photoredox reactions initiated by metal nodes in MOFs

341

(6)

3 Light-initiated all-in-one or cascade/tandem reactions over MOFs

347

(3)

4 Challenges and perspectives

350

(1)

References

351

(2)

22 Mesoporous silica-supported Ag-based plasmonic photocatalysts

353

(16)

Priyanka Verma

Yasutaka Kuwahara

Kohsuke Mori

Hiromi Yamashita

1 Introduction

353

(2)

2 Size- and color-controlled Ag plasmonic catalysts

355

(4)

3 Bimetallic combination of plasmonic Ag with active metal species

359

(3)

4 Plasmonic Ag in combination with single site Ti oxide species

362

(2)

5 Mechanism of enhancements

364

(2)

6 Conclusions

366

(1)

References

366

(3)

23 Development of metal sulfide-based photocatalysts for hydrogen evolution under visible light

369

(16)

Wei Zhang

Yabo Wang

Rong Xu

1 Introduction

369

(1)

2 CdS-based photocatalysts

369

(4)

3 ZnxCd1-xS-based photocatalysts

373

(4)

4 Sulfide cocatalysts

377

(3)

5 Ni-S molecular catalysts

380

(1)

6 DFT calculations

381

(1)

7 Conclusions and outlook

381

(1)

References

382

(3)

24 Photocatalysis with octahedral sulfides

385

(18)

Raquel Lucena

Jose-Carlos Conesa

1 Introduction

385

(2)

2 Photodegradation of HCOOH with ZnIn2S4: spectral response

387

(6)

3 Photodegradation of rhodamine B with In2S3: mechanism insights

393

(7)

4 Conclusions

400

(1)

Acknowledgments

400

(1)

References

400

(3)

25 Reduced graphene oxide (rGO)-supported mixed metal oxide catalysts for photocatalytic reactions

403

(14)

P. Karthik

V. Vinesh

M. Anpo

B. Neppolian

1 Introduction

403

(1)

2 Synthesis of graphene oxide(GO) and reduced graphene oxide(rGO)

404

(1)

3 Synthesis of rGO-supported metal oxide photocatalyst

405

(2)

4 Application of reduced graphene oxide supported-metal oxide composites in photocatalysis

407

(7)

5 Conclusion

414

(1)

References

414

(3)

26 Current development of graphitic carbon nitride photocatalysts as one of the organic semiconducting photocatalytic materials

417

(20)

Honghui Ou

Masakazu Anpo

Xinchen Wang

1 Introduction

417

(1)

2 Graphitic carbon nitride for photocatalytic water splitting

418

(2)

3 Crystal-structure engineering

420

(4)

4 Nanostructure design

424

(3)

5 Molecular design and structure optimization

427

(3)

6 Surface engineering using cocatalysts

430

(2)

7 Conclusions and perspectives

432

(1)

Acknowledgments

433

(1)

References

433

(4)

27 Carbon nitride as photocatalyst in organic selective transformations

437

(20)

Elisa L. Garcia-Lopez

Giuseppe Marci

Marianna Bellardita

Leonardo Palmisano

1 Introduction

437

(3)

2 Photocatalytic selective oxidation in the presence of C3N4

440

(13)

3 Conclusion

453

(1)

References

453

(4)

28 Heterogeneous photocatalysis by organic materials: from fundamental to applications

457

(18)

Amene Naseri

Morasae Samadi

Mandi Ebrahimi

Malihe Kheirabadi

Alireza Z. Moshfegh

1 Introduction

457

(1)

2 Three-dimensional organic materials in photocatalysis

458

(2)

3 Two-dimensional organic materials in photocatalysis

460

(6)

4 One-dimensional organic materials in photocatalysis

466

(3)

5 Zero-dimensional organic materials in photocatalysis

469

(2)

6 Conclusions

471

(1)

Acknowledgments

471

(1)

References

471

(4)

29 Photocatalytic performance of hexagonal boron carbon nitride nanomaterials

475

(16)

Bo Wang

Masakazu Anpo

Zhanggao Le

Xinchen Wang

1 Introduction

475

(1)

2 A brief history of BCN

476

(1)

3 Synthesis of h-BCN

477

(2)

4 Characterization of BCN

479

(2)

5 Photocatalytic application of h-BCN

481

(8)

6 Conclusions and perspective

489

(1)

References

489

(2)

30 Theoretical studies of two-dimensional photocatalyst materials

491

(20)

Qiang Wan

Junkang Xu

Sen Lin

1 Introduction

491

(1)

2 Theoretical simulations of 2D photocatalysts

492

(16)

3 Summary

508

(1)

References

508

(3)

31 Atomically scale design of van der Waals heterostructures as photocatalysts

511

(16)

Baisheng Sa

1 Introduction

511

(2)

2 Atomically scale calculation methods

513

(3)

3 Transition metal dichalcogenide-based vdW heterostructures

516

(3)

4 III-VI monolayer-based van der Waals heterostructures

519

(4)

5 Conclusions

523

(1)

References

523

(4)

Index

527

Prof. Xinchen Wang is currently the director of the State Key Laboratory of Photocatalysis on Energy and Environment, and the dean of college of chemistry in Fuzhou University. He obtained his BSc and MSc in Fuzhou University, and went to The Chinese University of Hong Kong to pursue his PhD. In 2006, he moved to Tokyo University as a JSPS post-doctor, then he went to Max Planck Institute of Colloide and Interfaces, Germany, as Alexander von Humboldt fellow, and was promoted as a Group Leader during 2008-2012. He started his professorship in Fuzhou University at 2005. His research interests cover catalysis and photocatalysis, and in this research field he published more than 200 peer-reviewed papers with H-index of 96. Prof. Masakazu Anpo is presently a Special Honor Professor & International Advisor of the State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University. He worked for 40 years at Osaka Prefecture University and served as Dean, Vice President & Executive Director for last 10 years and is now a Professor Emeritus. He is a pioneer in the research of photochemical reactions on solid surfaces, design of visible-light-responsive TiO2 photocatalysts, and single-site heterogeneous photocatalysts constructed within zeolites. He is the editor-in-chief of Res. Chem. Intermed. (Springer). He has published more than 100 books and 500 original peer-reviewed papers. He is a member of Academia Europaea and Science Council of Japan. Prof. Xianzhi Fu received his Ph.D. degree in Physical Chemistry from Peking University, China, in 1991. He did postdoctoral research on catalysis and photocatalysis at Peking University and University of Wisconsin-Madison, respectively. He joined Fuzhou University in 1997 where he was promoted to a full professor in 1998. Currently, he is the President of Fuzhou University. His research interests are mainly focused on Photocatalysis. He is the author or co-author of more than 300 peer-reviewed scientific publications and 40 patents. Professor Fu has won many important awards including the National Science and Technology Progress Award. He was elected as a member of the Chinese Academy of Engineering in 2009.

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