Klienditugi: 7440010 (E-R 10-18)

E-raamat: Eco-Friendly Corrosion Inhibitors: Principles, Designing and Applications

Edited by Lei Guo (Professor, Tongren University, Tongren, China), Edited by Chandrabhan Verma (Researcher, Department of Chemical and Petroleum Engineering, Khalifa University, Abu Dhabi, United Arab Emirates), Edited by Dawei Zhang (Professor, University of Science and Technology Beijing, Beijing, Chi)

Formaat: EPUB+DRM
Ilmumisaeg: 21-Jun-2022
Kirjastus: Elsevier - Health Sciences Division
Keel: eng
ISBN-13: 9780323998420

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Formaat: EPUB+DRM
Ilmumisaeg: 21-Jun-2022
Kirjastus: Elsevier - Health Sciences Division
Keel: eng
ISBN-13: 9780323998420

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Eco-Friendly Corrosion Inhibitors: Principles, Designing, and Applications wraps up new developments in corrosion inhibitors and their current applications in real-life environments such as in strong acidic pickling and petroleum-based liquids. The book covers several types of environmentally-friendly corrosion inhibitors in detail. In addition, it highlights both established research and technology on industrial scale corrosion inhibitors and their rapidly emerging aspects and future research directions.

Provides fundamental basics and applied practices of corrosion prevention at industrial scale
Serves as a valuable reference for scientists and engineers who are searching modern design for industrial scale corrosion inhibitors
Focuses on the most advanced industrial scale corrosion inhibitors, including current challenges during manufacturing
Includes up-to-date reference material such as websites of interest and information about the latest research

Contributors

Preface

Part 1 Overview of industrial corrosion and inhibition

1 General principles of industrial corrosion

Sheerin Masroor

1.1 Introduction

(1)

1.2 Materials in industrial applications

(1)

1.3 General principles or theories of industrial corrosion

(1)

1.4 Different types of corrosion in industries

(5)

1.5 Corrosion of metal in industries

(2)

References

(1)

2 Corrosion prevention and protection methods

Saman Zehra

Mohammad Mobin

Ruby Aslam

2.1 Introduction

(1)

2.2 Important considerations required for the corrosion prevention and control methods

(4)

2.3 Strategies of the corrosion prevention and control methods

(1)

2.4 Methods of corrosion control

(7)

Conclusion

(1)

Acknowledgment

(1)

Useful books

(1)

Useful websites

(1)

References

(1)

3 Development process for eco-friendly corrosion inhibitors

Mohamed Rbaa

Mouhsine Galai

Omar Dagdag

Lei Guo

Burak Tuzun

Elyor Berdimurodov

Abdelkader Zarrouk

Brahim Lakhrissi

3.1 Introduction

(1)

3.2 Process for development of eco-friendly synthesizing corrosion inhibitors

(2)

3.3 Process for development of eco-friendly extracting corrosion inhibitors

(9)

Conclusion

(1)

References

(5)

Part 2 Industrial environments & corrosion inhibitors

4 Acidizing corrosion inhibitors

Hao Li

Yujie Qiang

Chandrabhan Verma

4.1 Introduction of acidizing corrosion inhibitors

(1)

4.2 Acidizing inorganic corrosion inhibitor

(1)

4.3 Acidizing organic corrosion inhibitor

(1)

4.4 New acidizing corrosion inhibitor

(5)

Conclusion

(1)

References

(2)

5 Corrosion inhibitors used in alkaline environments

Daquan Zhang

Junyu Yang

Pei Gan

Wenyue Zhang

5.1 Corrosion inhibitor used for alkaline metal-air battery

(9)

5.2 Corrosion inhibitors for rebar in concrete reinforcement

(1)

5.3 Corrosion inhibitors in other alkaline media

(1)

Summary and outlook

(1)

Acknowledgments

(1)

References

(4)

6 Corrosion inhibitors in near neutral media

K.R. Ansari

Ambrish Singh

Abdullah K. Alanazi

M.A. Quraishi

6.1 Introduction

(1)

6.2 Metals corrosion and their inhibition in a neutral environment

(1)

6.3 Heterocyclic corrosion inhibitors for neutral environments

(4)

Acknowledgment

(1)

References

(3)

7 Supramolecular corrosion inhibitors for cooling water systems

Baomin Fan

Hua Hao

7.1 Introduction to supramolecular corrosion inhibitors

(3)

7.2 Preparation of supramolecular corrosion inhibitors via molecular recognition and self-assembly

(5)

7.3 Assembly mechanism of the supramolecular corrosion inhibitor based on CDs

(2)

7.4 Characterizations of supramolecular corrosion inhibitors

(10)

7.5 Inhibition effect and mechanism of supramolecular corrosion inhibitors

(6)

7.6 Supramolecular corrosion inhibitor used in industrial water treatment

105

(4)

Conclusions

109

(1)

Useful links

109

(1)

References

109

(2)

8 Corrosion inhibitors for oil and gas systems

Brahim El Ibrahimi

8.1 Well acidizing treatments in the oil and gas industry

111

(1)

8.2 Materials used for well construction in the oil and gas industry

112

(1)

8.3 Significance of corrosion and its associated agents in the oil and gas industry

113

(1)

8.4 Corrosion inhibitors and environmental concerns

114

(2)

8.5 Eco-friendly corrosion mitigation in the oil and gas industry

116

(6)

8.6 Developing the corrosion inhibitor formulation

122

(1)

Conclusion

123

(1)

Useful links

124

(1)

References

124

(3)

9 Vapor inhibitors for corrosion protection

K.R. Ansari

Ambrish Singh

Abdullah K. Alanazi

M.A. Quraishi

9.1 Introduction

127

(1)

9.2 Mechanism of VCI action

128

(2)

9.3 Developed VCIs for ferrous and nonferrous metals

130

(3)

9.4 Some important techniques used for corrosion inhibition monitoring

133

(1)

9.5 Advantages of VCIs

133

(1)

9.6 Market growth

134

(1)

9.7 Methods of VCI application

134

(1)

Acknowledgment

135

(1)

References

135

(2)

10 Inhibitors for microbiologically influenced corrosion (MIC)

Li Feng

Hailin Zhu

Xuemei Ma

Zhiyong Hu

Amir Zomorodian

10.1 Introduction

137

(1)

10.2 Microorganism species and MIC mechanism

138

(5)

10.3 MIC inhibitors

143

(6)

Conclusion

149

(1)

References

150

(5)

11 Corrosion inhibitors for Cu chemical mechanical planarization (CMP)

Baimei Tan

Lei Guo

Xinhuan Niu

Da Yin

Tengda Ma

Shihao Zhang

Chenwei Wang

11.1 Benzotriazole (BTA) used for Cu CMP

155

(3)

11.2 1,2,4-triazole (TAZ) used for Cu CMP

158

(3)

11.3 2,2'-[ [ (methyl-1H-benzotriazol-1-yl) methyfjimino] diethanol (TT-LYK) used for Cu CMP

161

(4)

11.4 Other inhibitors used for Cu CMP

165

(1)

11.5 The synergistic effects of mixed corrosion inhibitor used for Cu CMP

165

(2)

Conclusions

167

(1)

Useful links

167

(1)

References

167

(6)

Part 3 Modern environmentally friendly corrosion inhibitor systems

12 Heterocyclic corrosion inhibitors with multianchoring groups

Mouhsine Galai

Mohamed Rbaa

K. Dahmani

Brahim Lakhrissi

M. Ebn Touhami

Lei Guo

12.1 Introduction

173

(2)

12.2 Corrosion inhibition review of quinoline derivatives

175

(3)

12.3 Example of a complete study on the use of two heterocyclic inhibitors

178

(12)

Conclusion

190

(1)

References

190

(5)

13 Pharmaceutical drugs as corrosion inhibitors I

Hassane Lgaz

Mustafa R. Al-Haueethi

Rachid Salghi

Han-Seung Lee

13.1 Introduction

195

(1)

13.2 General overview on drug synthesis and reuse

196

(3)

13.3 Application of drugs and expired drugs as corrosion inhibitors

199

(5)

Conclusions and future outlook

204

(1)

Acknowledgments

205

(1)

References

205

(6)

14 Pharmaceutical drugs as corrosion inhibitors II

Shveta Sharma

Richika Ganjoo

Shimaa M. Elsaeed

Ashish Kumar

14.1 introduction

211

(1)

14.2 Industrial applications of drugs as corrosion inhibitors

211

(1)

14.3 Experimental section

212

(10)

Conclusion

222

(1)

Useful links

222

(1)

References

223

(6)

15 Pharmaceutical drugs protecting metals in aggressive environments

Ruby Aslam

Mohammad Mobin

Jeenat Aslam

Afroz Aslam

15.1 Introduction

229

(4)

15.2 Corrosion inhibitors

233

(1)

15.3 Drugs as corrosion inhibitor: Literature survey

234

(17)

15.4 Experimental validation

251

(1)

15.5 Limitations and future directions

252

(5)

Conclusions

257

(1)

Acknowledgments

257

(1)

Abbreviations

257

(1)

Useful links

257

(1)

References

258

(5)

16 Plant extracts as environmentally sustainable corrosion inhibitors I

Xin Zhang

Bochuan Tan

Wenpo Li

16.1 Preparation of plant extracts

263

(2)

16.2 Experimental methods of plant extracts

265

(3)

16.3 Mechanism of plant extracts

268

(1)

16.4 Recent advances of plant extracts

269

(5)

16.5 Modification of plant extracts

274

(1)

Summary and outlook

275

(2)

References

277

(6)

17 Plant extracts as environmentally sustainable corrosion inhibitors II

Abhinay Thakur

Humira Assad

Savas Kaya

Ashish Kumar

17.1 Introduction

283

(2)

17.2 Prominent metrics for extract preparation

285

(3)

17.3 Plant extract as corrosion inhibitor

288

(12)

17.4 Mode of inhibitor adsorption on substrate

300

(1)

17.5 Effect of temperature and concentration

301

(1)

17.6 Techniques to evaluate corrosion inhibition efficiency

302

(3)

17.7 Advantage and disadvantages of green corrosion inhibitors

305

(1)

17.8 Future outlooks

305

(1)

Conclusion

306

(1)

Useful links

306

(1)

References

307

(4)

18 Amino acids and their derivatives as corrosion inhibitor

Jeenat Aslam

Ruby Aslam

Afroz Aslam

18.1 Introduction

311

(3)

18.2 Classification and properties of amino acids

314

(1)

18.3 Corrosion inhibition mechanism by amino acids

314

(2)

18.4 Literature survey on amino acids and their derivatives

316

(3)

18.5 Challenges and recent progress

319

(7)

Conclusions

326

(1)

Abbreviations

326

(1)

Websites related to the topic

326

(1)

References

326

(5)

19 Ionic liquids as green and sustainable corrosion inhibitors I

Elyor Berdimurodov

Abduvali Kholikov

Khamdam Akbarov

Lei Guo

Nurbek Umirov

Dakeshwar Kumar Verma

Mohamed Rbaa

Omar Dagdag

Rajesh Haldhar

Savas Kaya

19.1 ILs as environmental-friendly corrosion inhibitors

331

(2)

19.2 ILs are corrosion inhibitors for steel materials

333

(36)

19.3 ILs are corrosion inhibitors for copper

369

(5)

19.4 ILs are corrosion inhibitors for magnesium materials

374

(4)

19.5 ILs are corrosion inhibitors for other metallic materials

378

(4)

19.6 Inhibition mechanism of ILs

382

(1)

Conclusions

382

(1)

Abbreviations

383

(1)

References

383

(8)

20 Ionic liquids as green and sustainable corrosion inhibitors II

Richika Ganjoo

Shveta Sharma

Bharmal A. Shabbirbhai

Shimaa M. Elsaeed

Ashish Kumar

20.1 Introduction

391

(3)

20.2 ILs as corrosion inhibitors

394

(4)

20.3 Techniques for conducting corrosion experiments and deciphering the mechanism of corrosion

398

(7)

20.4 Contact angle measurements of ionic liquids

405

(1)

20.5 Mechanism for the corrosion inhibitive property of ionic liquids

405

(1)

Conclusion

406

(1)

Useful links

406

(1)

References

406

(5)

21 Applications of nanomaterials in corrosion inhibitors

Yuqin Tian

Qi Chen

Xiaoya Sun

Jiajia Zhu

Renhui Zhang

21.1 Introduction

411

(1)

21.2 Nanomaterials and nanocomposites

411

(4)

21.3 Nanoparticles as corrosion inhibitors

415

(6)

21.4 Important issues related with anticorrosive nanomaterials

421

(1)

References

421

(8)

Part 4 Emerging trends in corrosion inhibition

22 Modern testing and analyzing techniques in corrosion

Chong Zhu

Zhaosen Zhou

Yang Zhou

Bin Xiang

22.1 Traditional used corrosion testing techniques

429

(14)

22.2 Potential corrosion detection approaches

443

(4)

Conclusions

447

(1)

References

447

(4)

23 Development of high temperature corrosion inhibitors

Abdolreza Farhadian

Lei Guo

23.1 Introduction

451

(1)

23.2 Plant extracts

452

(9)

23.3 Ionic liquids

461

(4)

23.4 Amino acids

465

(1)

23.5 Carbohydrates

466

(6)

23.6 Vegetable oils

472

(3)

23.7 Miscellaneous

475

(10)

Conclusions

478

(1)

Useful links

478

(1)

References

478

(75)

24 Smart corrosion inhibitor: Present status and future scenario

Xingwen Zheng

Lei Guo

Dawei Zhang

24.1 Introduction

485

(1)

24.2 Controlled release inhibitor

486

(3)

24.3 pH-responsive inhibitor

489

(8)

24.4 Ion exchange inhibitor

497

(4)

24.5 Other smart inhibitor

501

(1)

Summary and future scenario

502

(1)

References

502

(3)

25 Controllable fabrication of carbon dots based corrosion inhibitors with fluorescence properties

Yu Zhang

Bochuan Tan

Lei Guo

Mengyue Zhu

25.1 Corrosion inhibitor used for metal protection

505

(3)

25.2 Introduction of carbon dots

508

(3)

25.3 Synthetic strategies of CDs

511

(3)

25.4 Corrosion inhibition performance of CDs

514

(7)

Conclusions and outlook

521

(1)

Useful links

522

(1)

References

522

(5)

26 Computational methods used in corrosion inhibition research

Savas Kaya

Akpan N. Ikot

Ashish Kumar

Selcuk Simsek

Mengyue Zhu

Lei Guo

26.1 Introduction

527

(2)

26.2 Conceptual density functional theory (CDFT)

529

(2)

26.3 Some electronic structure principles and rules for corrosion inhibition research

531

(2)

26.4 Molecular dynamics and Monte Carlo simulations approaches in corrosion science

533

(1)

26.5 The application of first-principles calculation approach

534

(2)

Conclusions

536

(1)

References

536

(3)

27 Corrosion inhibition strategy: Synergistic effects

Peng Han

Jiawei Fan

Linghui Kong

Buyun Zhang

Zhixuan Chang

27.1 Problems and challenges in the study of synergistic effect of corrosion inhibitors

539

(4)

27.2 Advances of synergistic effect

543

(2)

27.3 Advances in theoretical research on synergistic effect of corrosion inhibitors

545

(3)

27.4 Significance and prospect of synergistic effect of corrosion inhibitor

548

(1)

Abbreviations

549

(1)

References

549

(4)

Index

553

Lei Guo received his PhD degree in materials chemistry from the Chongqing university of china. His research is dedicated to synthesis and characterization of organic molecules and their application towards corrosion inhibition property for the protection of metals and alloys from acid corrosion. His interests also encompass theoretical and experimental research in condensed matter physics Chandrabhan Verma, PhD, works at the Interdisciplinary Research Center for Advanced Materials, King Fahd University of Petroleum and Minerals, Dhahran, Saudi Arabia. He is a member of the American Chemical Society (ACS). His research interests mainly focus on the synthesis and design of environment-friendly corrosion inhibitors used for several industrial applications. Dr. Verma received his PhD degree from the Department of Chemistry at IIT?BHU, Varanasi, India and MSc degree in organic chemistry (Gold Medalist). Dr. Verma is the author of several research and review articles in peer-reviewed international journals. He has also received several national and international awards for his academic achievements.

Dawei Zhang is a full professor at University of Science & Technology Beijing. He is the Director of International Relations of Chinese Society for Corrosion and Protection and Chair of East Pacific and Asia Area of NACE International. His current research interests include smart coatings and surfaces, microbiologically influenced corrosion and corrosion machine learning. He has published over 100 papers on journals including Nature, Corrosion Science and Journal of Materials Chemistry A. He is currently an Editor of Corrosion Science and member on editorial boards of several journals including Materials Degradation and Corrosion Engineering Science & Technology.

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