| Series Preface |
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ix | |
| Volume Preface |
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xi | |
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xiii | |
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Valve Metal, Si and Ceramic Oxides as Dielectric Films for Passive and Active Electronic Devices |
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1 | (106) |
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1 | (4) |
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2 | (3) |
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Fundamentals and Experimental Details |
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5 | (10) |
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Electrochemical Oxide Layer Formation on Valve Metals |
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5 | (2) |
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The C(U) Curve of a Valve Metal Electrode |
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7 | (1) |
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Application of Lasers in Electrochemistry |
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8 | (1) |
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9 | (1) |
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Electrochemical Photocurrent Measurements (Optical/Electrical Method Class), Introduction of a New Model |
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10 | (1) |
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Photocurrent Model for Ultra-thin, Amorphous Films With TiO2 as an Example |
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11 | (4) |
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15 | (59) |
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15 | (1) |
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15 | (2) |
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Determination of Ti Substrate Grain Orientation by SAME |
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17 | (1) |
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Photocurrent Spectra and iph(U) Measurements on Single Ti/TiO2 Grains |
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18 | (1) |
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Microscopic Modification of the TiO2 Films by Means of Laser Scanning |
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19 | (2) |
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Characterization of the Modified TiO2 Films |
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21 | (4) |
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Photoresist Microelectrochemistry (Nanoliter Droplet Method) |
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25 | (3) |
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Applications of Photoresist Microelectrodes |
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28 | (8) |
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Summary and Conclusions for the Ti/TiO2 System |
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36 | (1) |
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Zr/ZrO2 and Hf/HfO2 Systems |
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37 | (1) |
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37 | (9) |
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46 | (2) |
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Systems: Nb/Nb2O5, Ta/Ta2O5 and A1/A12O3 |
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48 | (1) |
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49 | (4) |
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53 | (1) |
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54 | (3) |
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Application of Valve Metals in Electrolytic Capacitor Manufacturing |
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57 | (1) |
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57 | (5) |
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Capacitor Device Types and Production of Ta Capacitors |
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62 | (3) |
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Current Development Trends for Ta Capacitors and Research Issues Involved |
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65 | (2) |
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Effect of Oxygen Content and Sinter Conditions on Dislocation Formation |
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67 | (3) |
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70 | (4) |
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74 | (22) |
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Application of the Si/SiO2 System |
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77 | (1) |
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77 | (3) |
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80 | (2) |
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DRAM Storage Capacitor (Deep Trench) |
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82 | (8) |
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Alternative Dielectric Materials |
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90 | (2) |
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92 | (3) |
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95 | (1) |
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96 | (11) |
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99 | (8) |
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Superconformal Film Growth |
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107 | (84) |
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107 | (1) |
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108 | (2) |
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Stabilization and Smoothing Mechanisms |
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110 | (3) |
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110 | (1) |
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110 | (1) |
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Brightening by Grain Refinement |
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111 | (1) |
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Catalyst-derived Brightening |
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112 | (1) |
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Stabilization Across Length Scales |
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112 | (1) |
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113 | (33) |
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117 | (1) |
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Surface Segregation versus Consumption Processes |
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117 | (1) |
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Adsorbates Segregated onto Growing Surface |
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118 | (1) |
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Adsorbates Incorporated into Growing Deposit |
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119 | (2) |
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Deactivation of Adsorbate |
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121 | (1) |
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121 | (1) |
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122 | (3) |
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Quantifying Adsorbate Inhibition of Metal Deposition |
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125 | (5) |
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130 | (4) |
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Catalysis of Metal Deposition |
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134 | (1) |
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Activation of Blocked Electrodes by Competitive Adsorption of a Catalyst |
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135 | (3) |
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Catalyst Function and Consumption |
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138 | (3) |
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Quantifying the Effects of Competitive Adsorption on Metal Deposition |
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141 | (1) |
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Site Dependence of Charge Transfer Kinetics |
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142 | (1) |
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143 | (1) |
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SPS Adsorption from the Electrolyte |
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143 | (3) |
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Interface Motion and Morphological Evolution |
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146 | (33) |
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146 | (4) |
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150 | (3) |
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153 | (1) |
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153 | (7) |
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160 | (1) |
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Catalyst-derived Brightening |
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161 | (1) |
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161 | (12) |
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173 | (3) |
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Bridging the Length Scales |
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176 | (3) |
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179 | (12) |
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179 | (12) |
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Transition Metal Macrocycles as Electrocatalysts for Dioxygen Reduction |
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191 | (98) |
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191 | (13) |
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192 | (1) |
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Dioxygen Reduction in Aqueous Electrolytes: General Aspects |
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193 | (6) |
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Transition Metal Macrocycles |
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199 | (1) |
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199 | (2) |
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Electrocatalytic Properties Toward Oxygen Reduction |
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201 | (3) |
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Homogeneous Electrocatalysis |
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204 | (15) |
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Intrinsic Properties of Solution Phase Transition Metal Macrocycles |
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204 | (1) |
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Formal Redox Potentials and Diffusion Coefficients |
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204 | (5) |
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209 | (2) |
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Rates of Heterogeneous Electron Transfer Reactions |
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211 | (1) |
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Macrocyclic-Mediated Reduction of Dioxygen in Aqueous Electrolytes |
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212 | (1) |
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212 | (7) |
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Heterogeneous Electrocatalysis |
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219 | (50) |
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220 | (1) |
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Chemically Modified Electrodes |
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221 | (1) |
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Preparation and Electrochemical Characterization |
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221 | (5) |
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In situ Spectroscopic Characterization |
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226 | (6) |
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Redox Active Chemically Modified Electrodes |
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232 | (1) |
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232 | (3) |
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235 | (3) |
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238 | (3) |
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Electrocatalytic Aspects of Dioxygen Reduction |
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241 | (1) |
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Theoretical Considerations |
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241 | (3) |
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244 | (25) |
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Thermal Activation of Transition Metal Macrocycles |
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269 | (20) |
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269 | (1) |
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Electrochemical Characterization |
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269 | (1) |
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270 | (1) |
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Oxygen Reduction Polarization Curves |
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271 | (2) |
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Spectroscopic and Structural Characterization |
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273 | (1) |
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Pyrolysis-Mass Spectrometry |
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273 | (4) |
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Mossbauer Effect Spectroscopy |
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277 | (1) |
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X-ray Absorption Fine Structure |
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278 | (3) |
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X-ray Photoelectron Spectroscopy |
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281 | (1) |
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In Situ and Quasi In Situ Spectroscopic Characterization |
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281 | (2) |
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283 | (2) |
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285 | (4) |
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Multiscale Modeling and Design of Electrochemical Systems |
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289 | (46) |
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289 | (2) |
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Background and Motivation |
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291 | (7) |
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291 | (2) |
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293 | (2) |
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Microelectronic Applications |
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295 | (1) |
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Nanoscale Science and Technology |
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296 | (1) |
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Other Electrochemical Applications |
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297 | (1) |
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Trend Toward Atomistic/Molecular Simulation |
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298 | (6) |
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Integrated Circuit Example |
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298 | (2) |
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300 | (1) |
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Molecular Simulation Methods |
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300 | (3) |
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Coarse-grained Simulation Methods |
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303 | (1) |
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304 | (6) |
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Challenges and Requirements of Multiscale Modeling |
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310 | (1) |
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Addressing the Challenges in Multiscale Modeling |
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311 | (4) |
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Design Based on Multiscale Models |
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315 | (7) |
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322 | (13) |
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324 | (11) |
| Index |
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335 | |