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E-raamat: Electrochemical Water and Wastewater Treatment

Edited by (Universidad de Castilla La Mancha, Spain), Edited by (Universidade Federal do Rio Grande do Norte, Brazil), Edited by (Università degli Studi di Palermo, Italy)
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  • Ilmumisaeg: 29-May-2018
  • Kirjastus: Butterworth-Heinemann Inc
  • Keel: eng
  • ISBN-13: 9780128131619
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  • Formaat: EPUB+DRM
  • Ilmumisaeg: 29-May-2018
  • Kirjastus: Butterworth-Heinemann Inc
  • Keel: eng
  • ISBN-13: 9780128131619
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Electrochemical Water Treatment Methods provides the fundamentals and applications of electrochemical water treatment methods to treat industrial effluents. Sections provide an overview of the technology, its current state of development, and how it is making its way into industry applications. Other sections deal with historical developments and the fundamentals of 18 methods, including coupled methods, such as Electrocoagulation, Peroxi-Coagulation and Electro-Fenton treatments. In addition, users will find discussions that relate to industries such as Pulp and Paper, Pharmaceuticals, Textiles, and Urban/Domestic wastewater, amongst others. Final sections present advantages, disadvantages and ways to combine renewable energy sources and electrochemical methods to design sustainable facilities.

Environmental and Chemical Engineers will benefit from the extensive collection of methods and industry focused application cases, but researchers in environmental chemistry will also find interesting examples on how methods can be transitioned from lab environments to practical applications.

  • Offers an excellent overview of the research advances and current applications of electrochemical technologies for water treatment
  • Explains, in a comprehensive way, the fundamentals of different electrochemical uses and applications of different technologies
  • Provides a large number of examples as evidence of practical applications of electrochemistry to environmental protection
  • Explores the combination possibilities with other treatment technologies or emerging technologies for destroying water pollutants
Contributors xi
Preface xiii
Editors Biography xvii
I Historical Developments And Fundamentals
1 Electroreduction
Sandra Rondinini
Cristina Locatelli
Alessandro Minguzzi
Alberto Vertova
Introduction
3(5)
Materials
8(10)
Reactors and Reaction Schemes
18(4)
Conclusions and Perspectives
22(1)
References
23(5)
Further Reading
28(2)
2 Electrochemical Conversion of CO2 to Value-Added Products
Angel Irabien
Manuel Alvarez-Guerra
Jonathan Albo
Antonio Dominguez-Ramos
Introduction
30(6)
Electrochemical CO2 Reduction to Formate/Formic Acid
36(9)
Electrochemical CO2 Reduction to Methanol
45(8)
Conclusions
53(1)
References
54(7)
3 Electrocoagulation: Fundamentals and Prospectives
Carlos E. Barrera-Diaz
Patricia Balderas-Hernandez
Bryan Bilyeu
Coagulation Versus Electrocoagulation
61(2)
Electrocoagulation Fundamentals
63(2)
The Faraday Law and Its Importance in Electrocoagulation
65(1)
Superfaradic Efficiency
65(1)
Predominant Chemical Species Distribution in Aqueous Solution During Electrocoagulation Process
66(4)
Coupled Electrocoagulation-Ozone
70(3)
Future Perspectives
73(1)
References
73(6)
4 Electroflotation
Gessica De O. Santiago Santos
Marilia M. De Salles Pupo
Vanessa M. Vasconcelos
Katlin I. Barrios Eguiluz
Giancarlo R. Salazar Banda
Introduction and Historical Background Fundamentals
79(7)
Engineering Aspects
86(14)
Water and Wastewater Treatment by Electroflotation
100(8)
Cost Analysis
108(3)
Concluding Remarks and Perspectives
111(1)
References
112(7)
5 Electrocatalysis in Wastewater Treatment
Achille De Battisti
Carlos A. Martinez-Huitle
Fundamentals of the Electrochemical Oxidation
119
Recent Mechanism Advances
115(11)
Mineralization of Organics by Molecular Oxygen
126(2)
New Approaches for Electrochemical Oxidation
128(1)
Advantages and Disadvantages of the EO Approach
129(1)
Concluding Remarks
130(1)
Acknowledgments
131(1)
References
131(3)
6 Indirect Electrochemical Oxidation Using Hydroxyl Radical, Active Chlorine, and Peroxodisulfate
Karine Groenen Serrano
Introduction
134(1)
Reactive Oxygen Species
135(1)
Ozone
136(2)
Hydrogen Peroxide
138(2)
Hydroxyl Radicals
140(6)
Active Chlorine
146(5)
Peroxo-Compounds
151(7)
Conclusion
158(2)
Acknowledgments
160(1)
References
160(4)
Further Reading
164(2)
7 Indirect Electrochemical Oxidation by Using Ozone, Hydrogen Peroxide, and Ferrate
Cristina Saez
Manuel Andres Rodrigo
Ana S. Fajardo
Carlos A. Martinez-Huitle
Production of Oxidants in the Anode During the Electrolysis of Water
166(4)
Improvement of Treatment Efficiency With Cathodic Processes
170(5)
Ozone Oxidation
175(4)
Hydrogen Peroxide
179(3)
Ferrates
182(1)
New Applications of Oxidants Electrochemically Generated for Treating Wastewaters
183(4)
Acknowledgments
187(1)
References
187(6)
8 Electro-Fenton Process: Background, New Developments, and Applications
Nihal Oturan
Mehmet A. Oturan
Introduction
193(2)
Principles and Fundamentals of the EF Process
195(4)
Effect of Operating Parameters
199(4)
Application of EF Process to Removal of Organic Micropollutants
203(4)
Recent Developments in EF Process
207(1)
Heterogeneous EF
208(3)
Bioelectro-Fenton (Bio-EF)
211(3)
Concluding Remarks and Perspectives
214(1)
References
215(8)
9 Photo and Solar Fenton Processes for Wastewater Treatment
Juan M. Peralta-Hernandez
Shraddha Vijay
Oscar Rodriguez-Narvaez
Martin A. Pacheco-Alvarez
Introduction
223(3)
Principles and Fundamentals of the Photoelectro-Fenton Process
226(7)
Conclusions
233(1)
Acknowledgment
234(1)
References
234(3)
Further Reading
237(3)
10 Photo-Electrochemical Technologies for Removing Organic Compounds in Wastewater
Elisama V. Dos Santos
Onofrio Scialdone
Introduction
240(1)
Fundamentals of Photoelectrocatalysis
241(2)
Photo-Anode Type
243(4)
Photo-Assisted Electrochemical Treatments
247(6)
Production of Oxidants by PEC
253(3)
Effect of the Nature of the Cathode
256(1)
Effect of pH
257(1)
Application of Photoelectrocatalytic Processes
258(2)
Conclusions
260(1)
References
261(5)
Further Reading
266(2)
11 Hybrid and Sequential Chemical and Electrochemical Processes for Water Decontamination
Enric Brillas
Ignasi Sires
Introduction
268(1)
Single-Step Processes
269(20)
Two-Step Processes
289(8)
Conclusions
297(1)
References
297(7)
Further Reading
304(1)
12 Microbial Fuel Cells and Wastewater Treatment
Sidney Aquino Neto
Valeria Reginatto
Adalgisa R. De Andrade
Introduction
305(4)
Biological Processes: Anaerobic Digestion
309(8)
Microbial Fuel Cells
317(6)
Microbial Electrolysis Cells
323(3)
Perspectives
326(1)
References
327(9)
II Applications Of Electrochemical Technologies For Decontamination And Disinfection Of Water
13 Fine Chemical Industry, Pulp and Paper Industry, Petrochemical Industry and Pharmaceutical Industry
Marco Panizza
Introduction
336(1)
Fine Chemical Industries
337(5)
Pulp and Paper Industries
342(7)
Petrochemical Industries
349(8)
Pharmaceutical Industries
357(4)
Conclusions
361(1)
References
362(4)
14 Application of Electrochemical Processes for Treating Effluents From Hydrocarbon Industries
Alejandro Medel
Florencio Lugo
Yunny Meas
Introduction
366(1)
Water System (and Effluents) in Refineries
367(3)
Electrochemical Advanced Oxidation Processes
370(10)
Conversion/Incineration in Refinery Effluents
380(9)
Conclusions
389(1)
References
389(3)
Further Reading
392(1)
15 Application of Electrochemical Processes for Treating Effluents From Landfill Leachate as Well as the Agro and Food Industries
Carolina Espinoza-Cisternas
Ricardo Salazar
Introduction
393(17)
Coupled Processes
410(4)
Conclusions
414(1)
Acknowledgments
415(1)
References
415(7)
16 Practical Aspects on Electrochemical Disinfection of Urban and Domestic Wastewater
Simonetta Palmas
Michele Mascia
Annalisa Vacca
Laura Mats
Simona Corgiolu
Elisabetta Petrucci
Introduction
422(4)
Electrode Materials
426(6)
Issues Related to Direct Electrolysis
432(7)
Conclusions
439(1)
References
440(12)
III Chemical And Technological Advantages And Disadvantages Of Electrochemical Approaches
17 Advantages, Disadvantages, and Future Challenges of the Use of Electrochemical Technologies for Water and Wastewater Treatment
Brian P. Chaplin
Introduction
452(1)
Electrochemical Advanced Oxidation Processes
452(12)
Key Advantages and Innovations of EAOPs
464(7)
Challenges Associated With EAOP Implementation
471(9)
Future Research and Engineering Needs
480(2)
References
482(12)
Further Reading
494(2)
18 Integration of Electrochemical Advanced Oxidation With Membrane Separation and Biodegradation
Ane M. Urtiaga
Raquel Ibanez
Maria J. Rivero
Inmaculada Ortiz
Introduction
496(1)
Electrochemical Treatment as a Way to Increase Effluent Biodegradability
496(6)
Integration of Electrochemical Treatment With Membrane Separation
502(5)
Concluding Remarks
507(1)
Acknowledgments
508(1)
References
508(6)
IV Renewable Energies And Electrochemical Technologies
19 Prospective Applications of Renewable Energy-Based Electrochemical Systems in Wastewater Treatment
Vicente Montiel
David Valero
Francisco Gallud
Vicente Garcia-Garcia
Eduardo Exposito
Jesus Iniesta
Introduction
514(1)
Solar Photovoltaic Energy and Electrochemical Treatments
514(23)
References
537(6)
Index 543
Carlos Alberto Martinez Huitle graduated in Chemistry at Universidad de las Américas-Puebla (México) under supervision of Prof. Dr. Marco Antonio Quiroz Alfaro. After a work experience in CibaSpecialty Chemicals (currently acquired by the German chemical company BASF), he moved to Ferrara (Italy) where he received his PhD in Chemical Sciences at the University of Ferrara under supervision of Prof. Achille De Battisti. During the same period, he worked as visiting scientist in the group of Prof. Christos Comninellis at the EPFL Institute, Switzerland. From since 2005 to 2008, he has served as faculty member in the Department of Chemistry at the University of Milan. In 2008, he also moved to Brazil where he currently is an Associate Professor in the Institute of Chemistry at the Federal University of Rio Grande do Norte. Manuel A Rodrigo obtained his PhD degree in the University of Valencia in 1997, with a research focused on the modelling and automation of biological nutrient removal processes. In 1997, he joined the University the Castilla La Mancha and began researching on electrochemical engineering. In this first postdoctoral stage, his research was focused on the electrolyses of industrial wastewater. After a first postdoctoral training in the Lab of Prof. Comninellis (EPFL, Switzerland), he started working with diamond electrodes, one of the key topics in his research. In 2000, he was appointed as Associate Professor at the University of Castilla La Mancha, and began researching on electrocoagulation and high temperature PEM fuel cells. Onofrio Scialdone studied Chemical Engineering at the University of Palermo. He obtained his PhD degree in Electrochemical Engineering in the Politecnico di Milano in 1999 and a Master in Economy at the Scuola Mattei of ENI (2000). He is Professor of Industrial Chemistry at Università degli Studi di Palermo and he leads the research activities on electrochemistry of the Laboratory of Chemical and Electrochemical Technologies” at the same University. His main research interests are in electrochemical reaction engineering, with particular emphasis on synthesis of fine chemicals, environmental protection and electrical energy generation