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E-raamat: Electron Spin Echo Envelope Modulation (ESEEM) Spectroscopy

(University of Illinois-Champaign, Champaign, Illinois, USA),
  • Formaat: 432 pages
  • Ilmumisaeg: 01-Nov-2024
  • Kirjastus: CRC Press Inc
  • Keel: eng
  • ISBN-13: 9781040283639
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Electron Spin Echo Envelope Modulation (ESEEM) SpectroscopySuurem pilt
  • Formaat: 432 pages
  • Ilmumisaeg: 01-Nov-2024
  • Kirjastus: CRC Press Inc
  • Keel: eng
  • ISBN-13: 9781040283639
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The first volume devoted entirely to Electron Spin Echo Envelope Modulation (ESEEM) Spectroscopy

This valuable book provides an introduction and broad survey of topics in ESEEM spectroscopy, including the theory, instrumentation, peculiarities of ESE experiments, and analysis of experimental data with particular emphasis on orientationally disordered systems. Applications of ESEEM spectroscopy to study chemically and biologically important paramagnetic centers in single crystals, amorphous solids, and powders are discussed as well. Electron Spin Echo Envelope Modulation (ESEEM) Spectroscopy will benefit specialists in magnetic resonance spectroscopy, physicists, chemists, and biologists who use magnetic resonance in their research.
PRINCIPLES of ESE and ESEEM. INTRODUCTION TO ESEEM PHENOMENON. The ESE
Method. Vector Model for Echo Formation. Electron Spin Echo Envelope
Modulation. Qualitative ESEEM Models. INTRODUCTION TO THE THEORY OF NUCLEAR
ESEEM. General Quantum Mechanical Calculation of Nuclear ESEEM. Midulation
Frequencies and Their Amplitudes. ESEEM Resulting from Coupling with Several
Nuclei. ESEEM from a Nucleus with I=1/2. ESEEM Due to hfi with a Nucleus of
an Arbitrary Spin. ESEEM for a Triplet State. CHARACTERISTICS OF ESEEM
EXPERIMENT. Elements of ESE Spectrometers. Dead Time in ESE Spectroscopy. ESE
Resonators. Sensitivity and Time Resolution of ESE Spectroscopy. ESEEM
Frequency Analysis. Two-Dimensional (2D) ESEEM Spectroscopy. PARAMAGNETIC
CENTERS IN SINGLE CRYSTALS. Radicals and Metal Ions in Single Crystals.
Triplet States in Single Crystals. ESEEM RESULTING FROM INTERACTIONS OF
ELECTRON SPINS. ESEEM SPECTROSCOPY IN ORIENTATIONALLY DISORDERED SYSTEMS.
ESEEM FROM I=1/2 NUCLEI IN TIME AND FREQUENCY DOMAINS IN DISORDERED SYSTEMS.
ESEEM in Extremely Weak hfi Limit. Numerical Calculations of ESEEM in the
Time Domain for Arbitrary hfi Parameters. The Influence of the Spatial
Configuration of Nuclei. The Influence of a Spread in the Nuclear Zeeman
Frequency. Lineshapes of the Basic Frequencies a(B) in ESEEM Spectra of
Disordered Systems. Comparison with ENDOR. Combination Lines in ESEEM
Spectra. Change of the ESEEM Spectra in Multifrequency Experiment. The Map of
the Lines Maxima of the Basic and Combination Frequencies. Influence of
Spectrometer Dead Time on the ESEEM Spectra of Disordered Systems. ESEEM DUE
TO I>1 NUCLEI WITH WEAK NUCLEAR QUADRUPOLE INTERACTION. ESEEM Due to Weak
Hyperfine Interaction with Nucleus of Arbitrary Spin. The Influence of Weak
Nuclear Quadrupole Interaction Upon ESEEM Due to Nuclei of Arbitrary Spin.
The Influence of the Nuclear Quadrupole Interaction Due to Deuterium Nuclei
in Time Domain. Manifestation of Weak Nuclear Quadrupole Interaction in ESEEM
S
Sergei A. Dikanov, Yuri Tsvetkov
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