| Preface |
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v | |
| Abbreviations |
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vii | |
| Acknowledgements |
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ix | |
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List of Marcus' Papers Considered in the
Chapters of the Book |
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xvii | |
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Chapter 1 Solvent Dynamical and Symmetrized Potential Aspects of ET Rates; Superexchange versus an Intermediate BChl-Mechanism in Reaction Centers of Photosyntetic Bacteria; Dynamical Effects in ET Reactions. II. Numerical Solution; Recent Developments in ET Reaction; Some Recent Developments in ET: Charge Separation, Long Distances, Solvent Dynamics, and Free Energy Aspects; Nonexponential Time Behavior of ET in an Inhomogeneous Polar Medium; An Internal Consistency Test and Its Implications for the Initial Steps in Bacterial Photosynthesis; Early Steps in Bacterial Photosynthesis. Comparison of Three Mechanisms |
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1 | (42) |
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Chapter 2 Early Steps in Bacterial Photosynthesis, Charge Transfer Absorption, Fluorescence Spectra and the Inverted Region, Reorganization Free Energy for ETs at Liquid-Liquid and Dielectric Semiconductor-Liquid Interfaces, Photosynthetic ET, ET in Dynamically Disordered Polar Medium, Dynamics of ET for a Nonsuperexchange Coherent Mechanism |
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43 | (56) |
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Chapter 3 Matrix Elements for Long-range ET, ET across Liquid-Liquid Interfaces, Charge Transfer Spectra in Frozen Media, ET in Proteins: Calculation of Electronic Coupling, ET across Liquid-Liquid Interfaces
2. Schrodinger Equation for Strongly Interacting ET Systems |
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99 | (48) |
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Chapter 4 ET Matrix Elements of Bridged Systems: A Molecular Fragment Approach; Theory of ET, Comparison with Experiments; Tight-binding for Semi-infinite solids; ET in Proteins: An Artificial Intelligence Approach to Electronic Coupling; Surface Properties of Solids Using a Semi-infinite Approach and the Tight-binding Approximation; Theoretical Model of Scanning Tunneling Microscopy |
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147 | (46) |
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Chapter 5 ET in Proteins: Electronic Coupling in Myoglobin, Quantum Corrections for ET Rates. Polarizable vs. Nonpolarizable Description of Solvent, ET in Proteins: Electronic Coupling in Modified Cytochrome c and Myoglobin Derivatives, Free Energy of Nonequilibrium Polarization Systems. 4: A Formalism Based on the Nonequilibrium Dielectric Displacement, ET in Ferrocytochromes |
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193 | (52) |
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Chapter 6 Tunneling Matrix Elements in Ru-modified Blue Copper Proteins: Pruning the Protein in Search of ET Pathways; Gaussian Field Model of Dielectric Solvation Dynamics; Symmetry or Asymmetry of kET and iSTM vs. Potential Curves; A Sequential Formula for Electronic Coupling in Long-Range Bridge-Assisted ET: Formulation of the Theory and Application to Alkanethiol Monolayers; Time-dependent Stokes Shift and Its Calculation from Solvent Dielectric Dispersion Data |
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245 | (22) |
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Chapter 7 ET Model for the Electric Field Effect on Quantum Yield of Charge Separation in Bacterial Photosynthetic Reaction Centers; Theory of Rates of Sn2 Reactions and Relation to Those of Outer Sphere Bond Rupture Electron Transfers; Source of Image Contrast in STM Images of Functionalized Alkanes on Graphite: A Systematic Functional Group Approach |
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267 | (68) |
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Chapter 8 Dynamic Stokes Shift in Solution: Effect of Finite Pump Pulse Duration; Time-dependent Fluorescence Spectra of Large Molecules in Polar Solvents; Remarks on Dissociative Anion Potential Energy Curves for Organic Electron Transfers; Ion Pairing and Electron Transfer |
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335 | (78) |
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Chapter 9 Linear Response Theory of ET Reactions as an Alternative to the Molecular Harmonic Oscillator Model; Nonadiabatic Electron Transfer at Metal Surfaces; On the Theory of Electron Transfer Reactions at Semiconductors Electrode/Liquid Interfaces; On the Theory of Electron Transfer Reactions at Semiconductors Electrode/Liquid Interfaces. II. A Free Electron Model; Temperature Dependence of the Electronic Factor in the Nonadiabatic Electron Transfer at Metal and Semiconductor Electrodes |
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413 | (56) |
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Chapter 10 Theoretical Investigation of the Directional Electron Transfer in 4-Aminonaphtalimide Compounds; Variable-range Hopping Electron Transfer through Disordered Bridge States: Application to DNA; A Model for Charge Transfer Inverse Photoemission; Mechanisms of Fluorescence Blinking in Semiconductor Nanocrystals Quantum Dots; Diffusion-controlled Electron Transfer Processes and Power-law Statistics of Fluorescence Intermittency of Nanoparticles |
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469 | (62) |
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Chapter 11 Single Particle versus Ensemble Average: From Power-law Intermittency of a Single Quantum Dot to Quasistretched Exponential Fluorescence Decay of an Ensemble; Explanation of Quantum Dot Blinking without the Long-lived Trap Hypothesis; Photoinduced Spectral Diffusion and Diffusion-controlled Electron Transfer Reactions in Fluorescence Intermittency of Quantum Dots; Chain Dynamics and Power-law Distance Fluctuations of Single-molecule Systems; Determination of Energetics and Kinetics from Single-particle Intermittency and Ensemble-averaged Fluorescence Intensity Decay of Quantum Dots |
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531 | (94) |
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Chapter 12 Summarizing Lecture: Factors Influencing Enzymatic H-transfers, Analysis of Nuclear Tunneling Isotope Effects and Thermodynamic versus Specific Effects; Enzymatic Catalysis and Transfers in Solution. I. Theory and Computations: A Unified View; H and Other Transfers in Enzymes and in Solution: Theory and Computations: A Unified View.
2. Applications to Experiment and Computations |
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625 | (76) |
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Chapter 13 Evidence for a Diffusion-controlled Mechanism for Fluorescence Blinking of Colloidal Quantum Dots, Universal Emission Intermittency in Quantum Dots, Nanorods, and Nanowires, ET Past and Future, Beyond the Historical Perspective on Hydrogen and Electron Transfers, Interaction between Experiments, Analytical Theories, and Computation, Interaction of Theory and Experiment: Examples from Single Molecule Studies of Nanoparticles, Theory of a Single Dye Molecule Blinking with a Diffusion-based Power Law Distribution, Extension of the Diffusion Controlled Electron Transfer Theory for Intermittent Fluorescence of Quantum Dots: Inclusion of Biexcitons and the Difference of "On" and "Off" Time Distributions |
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701 | |
Lisainfo e-raamatute kohta