| About the Author |
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xi | |
| Preface to the Second Edition |
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xiii | |
| Preface to the Third Edition |
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xv | |
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List of Symbols and Abbreviations |
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xvii | |
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1 Fire Science and Combustion |
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1 | (34) |
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1.1 Fuels and the Combustion Process |
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2 | (10) |
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1.1.1 The Nature of Fuels |
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2 | (4) |
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1.1.2 Thermal Decomposition and Stability of Polymers |
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6 | (6) |
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1.2 The Physical Chemistry of Combustion in Fires |
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12 | (23) |
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14 | (4) |
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1.2.2 Vapour Pressure of Liquids |
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18 | (1) |
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1.2.3 Combustion and Energy Release |
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19 | (7) |
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1.2.4 The Mechanism of Gas Phase Combustion |
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26 | (4) |
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1.2.5 Temperatures of Flames |
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30 | (4) |
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34 | (1) |
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35 | (48) |
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2.1 Summary of the Heat Transfer Equations |
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36 | (2) |
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38 | (14) |
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2.2.1 Steady State Conduction |
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38 | (2) |
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2.2.2 Non-steady State Conduction |
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40 | (8) |
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2.2.3 Numerical Methods of Solving Time-dependent Conduction Problems |
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48 | (4) |
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52 | (7) |
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59 | (24) |
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2.4.1 Configuration Factors |
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64 | (8) |
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2.4.2 Radiation from Hot Gases and Non-luminous Flames |
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72 | (4) |
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2.4.3 Radiation from Luminous Flames and Hot Smoky Gases |
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76 | (3) |
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79 | (4) |
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3 Limits of Flammability and Premixed Flames |
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83 | (38) |
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3.1 Limits of Flammability |
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83 | (14) |
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3.1.1 Measurement of Flammability Limits |
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83 | (5) |
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3.1.2 Characterization of the Lower Flammability Limit |
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88 | (3) |
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3.1.3 Dependence of Flammability Limits on Temperature and Pressure |
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91 | (3) |
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3.1.4 Flammability Diagrams |
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94 | (3) |
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3.2 The Structure of a Premixed Flame |
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97 | (4) |
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3.3 Heat Losses from Premixed Flames |
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101 | (5) |
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3.4 Measurement of Burning Velocities |
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106 | (3) |
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3.5 Variation of Burning Velocity with Experimental Parameters |
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109 | (7) |
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3.5.1 Variation of Mixture Composition |
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110 | (1) |
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3.5.2 Variation of Temperature |
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111 | (1) |
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3.5.3 Variation of Pressure |
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112 | (1) |
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3.5.4 Addition of Suppressants |
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113 | (3) |
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3.6 The Effect of Turbulence |
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116 | (5) |
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118 | (3) |
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4 Diffusion Flames and Fire Plumes |
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121 | (60) |
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123 | (5) |
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128 | (2) |
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4.3 Flames from Natural Fires |
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130 | (35) |
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132 | (7) |
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139 | (12) |
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4.3.3 Interaction of the Fire Plume with Compartment Boundaries |
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151 | (12) |
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4.3.4 The Effect of Wind on the Fire Plume |
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163 | (2) |
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4.4 Some Practical Applications |
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165 | (16) |
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4.4.1 Radiation from Flames |
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166 | (3) |
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4.4.2 The Response of Ceiling-mounted Fire Detectors |
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169 | (2) |
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4.4.3 Interaction between Sprinkler Sprays and the Fire Plume |
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171 | (1) |
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4.4.4 The Removal of Smoke |
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172 | (2) |
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174 | (4) |
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178 | (3) |
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5 Steady Burning of Liquids and Solids |
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181 | (44) |
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182 | (17) |
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182 | (11) |
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193 | (1) |
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5.1.3 Burning of Liquid Droplets |
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194 | (3) |
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5.1.4 Pressurized and Cryogenic Liquids |
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197 | (2) |
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199 | (26) |
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5.2.1 Burning of Synthetic Polymers |
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199 | (10) |
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209 | (12) |
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5.2.3 Burning of Dusts and Powders |
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221 | (2) |
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223 | (2) |
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6 Ignition: The Initiation of Flaming Combustion |
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225 | (52) |
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6.1 Ignition of Flammable Vapour/Air Mixtures |
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225 | (10) |
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235 | (12) |
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6.2.1 Ignition of Low Flashpoint Liquids |
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241 | (1) |
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6.2.2 Ignition of High Flashpoint Liquids |
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242 | (3) |
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6.2.3 Auto-ignition of Liquid Fuels |
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245 | (2) |
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6.3 Piloted Ignition of Solids |
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247 | (22) |
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6.3.1 Ignition during a Constant Heat Flux |
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250 | (13) |
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6.3.2 Ignition Involving a `Discontinuous' Heat Flux |
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263 | (6) |
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6.4 Spontaneous Ignition of Solids |
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269 | (2) |
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6.5 Surface Ignition by Flame Impingement |
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271 | (1) |
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272 | (5) |
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6.6.1 Extinction of Premixed Flames |
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272 | (1) |
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6.6.2 Extinction of Diffusion Flames |
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273 | (2) |
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275 | (2) |
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277 | (40) |
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7.1 Flame Spread Over Liquids |
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277 | (7) |
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7.2 Flame Spread Over Solids |
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284 | (23) |
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7.2.1 Surface Orientation and Direction of Propagation |
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284 | (8) |
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7.2.2 Thickness of the Fuel |
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292 | (2) |
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7.2.3 Density, Thermal Capacity and Thermal Conductivity |
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294 | (2) |
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7.2.4 Geometry of the Sample |
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296 | (1) |
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7.2.5 Environmental Effects |
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297 | (10) |
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7.3 Flame Spread Modelling |
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307 | (5) |
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7.4 Spread of Flame through Open Fuel Beds |
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312 | (1) |
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313 | (4) |
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7.5.1 Radiation-enhanced Flame Spread |
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313 | (2) |
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7.5.2 Rate of Vertical Spread |
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315 | (1) |
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315 | (2) |
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8 Spontaneous Ignition within Solids and Smouldering Combustion |
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317 | (32) |
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8.1 Spontaneous Ignition in Bulk Solids |
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317 | (14) |
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8.1.1 Application of the Frank-Kamenetskii Model |
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318 | (6) |
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324 | (1) |
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8.1.3 Ignition of Dust Layers |
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325 | (4) |
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8.1.4 Ignition of Oil - Soaked Porous Substrates |
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329 | (1) |
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8.1.5 Spontaneous Ignition in Haystacks |
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330 | (1) |
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8.2 Smouldering Combustion |
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331 | (16) |
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8.2.1 Factors Affecting the Propagation of Smouldering |
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333 | (9) |
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8.2.2 Transition from Smouldering to Flaming Combustion |
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342 | (2) |
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8.2.3 Initiation of Smouldering Combustion |
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344 | (2) |
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8.2.4 The Chemical Requirements for Smouldering |
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346 | (1) |
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347 | (2) |
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348 | (1) |
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9 The Pre-flashover Compartment Fire |
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349 | (38) |
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9.1 The Growth Period and the Definition of Flashover |
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351 | (3) |
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354 | (33) |
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9.2.1 Conditions Necessary for Flashover |
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354 | (10) |
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9.2.2 Fuel and Ventilation Conditions Necessary for Flashover |
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364 | (14) |
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9.2.3 Factors Affecting Time to Flashover |
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378 | (4) |
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9.2.4 Factors Affecting Fire Growth |
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382 | (3) |
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385 | (2) |
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10 The Post-flashover Compartment Fire |
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387 | (54) |
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387 | (9) |
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10.2 Fully Developed Fire Behaviour |
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396 | (8) |
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10.3 Temperatures Achieved in Fully Developed Fires |
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404 | (16) |
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10.3.1 Experimental Study of Fully Developed Fires in Single Compartments |
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404 | (2) |
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10.3.2 Mathematical Models for Compartment Fire Temperatures |
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406 | (12) |
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10.3.3 Fires in Large Compartments |
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418 | (2) |
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10.4 Fire Resistance and Fire Severity |
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420 | (7) |
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10.5 Methods of Calculating Fire Resistance |
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427 | (8) |
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10.6 Projection of Flames from Burning Compartments |
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435 | (2) |
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10.7 Spread of Fire from a Compartment |
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437 | (4) |
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439 | (2) |
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11 Smoke: Its Formation, Composition and Movement |
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441 | (34) |
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11.1 Formation and Measurement of Smoke |
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443 | (16) |
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11.1.1 Production of Smoke Particles |
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443 | (4) |
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11.1.2 Measurement of Particulate Smoke |
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447 | (3) |
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11.1.3 Methods of Test for Smoke Production Potential |
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450 | (5) |
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11.1.4 The Toxicity of Smoke |
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455 | (4) |
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459 | (10) |
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11.2.1 Forces Responsible for Smoke Movement |
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459 | (6) |
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11.2.2 Rate of Smoke Production in Fires |
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465 | (4) |
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11.3 Smoke Control Systems |
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469 | (6) |
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11.3.1 Smoke Control in Large Spaces |
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470 | (1) |
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11.3.2 Smoke Control in Shopping Centres |
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471 | (2) |
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11.3.3 Smoke Control on Protected Escape Routes |
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473 | (2) |
| References |
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475 | (52) |
| Answers to Selected Problems |
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527 | (4) |
| Author Index |
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531 | (14) |
| Subject Index |
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545 | |