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E-raamat: Introduction to Polymer Viscoelasticity

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(University of Massachusetts, Amherst), (University of Connecticut)
  • Formaat: EPUB+DRM
  • Ilmumisaeg: 25-Jun-2018
  • Kirjastus: John Wiley & Sons Inc
  • Keel: eng
  • ISBN-13: 9781119181828
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Introduction to Polymer ViscoelasticitySuurem pilt
  • Formaat: EPUB+DRM
  • Ilmumisaeg: 25-Jun-2018
  • Kirjastus: John Wiley & Sons Inc
  • Keel: eng
  • ISBN-13: 9781119181828
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Completely revised and updated, the fourth edition of this classic text continues to offer the reader a thorough understanding of viscoelastic behavior, essential for the proper utilization of polymers.

  • Explains principles, corresponding equations, and experimental methods with supporting real-life applications
  • Adds coverage of measurement techniques (nano-indentation, atomic force microscopy (AFM), and diffusing wave spectroscopy (DWS)), biopolymer viscoelasticity, and the relationship between mechanical polymer properties and viscoelastic functions
  • Has two new ections to address modern areas of viscoelastic measurement: large amplitude oscillatory shear (LAOS) and microrheology
  • Includes problems in the text and an Instructor’s Manual (including solutions) available for adopting professors
  • Prior edition reviews: "The book is clear written and…[ is] appropriate for students in introductory undergraduate courses and for others wanting introduction to the fundamentals of the subject." (CHOICE, December 2005); "This book is invariably well written, logically organized and easy to follow...I highly recommend this book to anyone studying polymer viscoelasticity." (Polymer News, December 2005)
Preface to the Fourth Edition xiii
Preface to the Third Edition xv
Preface to the Second Edition xviii
Preface to the First Edition xx
1 Introduction
1(8)
Problems
6(1)
General Reference Texts
7(1)
References
8(1)
2 Phenomenological Treatment of Viscoelasticity
9(16)
A Elastic Modulus
9(12)
B Transient Experiments
21(4)
C Dynamic Experiments
25(1)
1 Low-Strain Measurements
25(5)
2 Large Amplitude Oscillatory Shear (LAOS)
30(4)
3 Microrheology
34(4)
D Boltzmann Superposition Principle
38(5)
E Relationship Between the Creep Compliance and the Stress Relaxation Modulus
43(1)
F Relationship Between Static and Dynamic Properties
44(1)
Appendix 2-1 Connecting Creep Compliance and Stress Relaxation Modulus Using Laplace Transforms
45(3)
Appendix 2-2 Borel's Theorem
48(1)
Appendix 2-3 Geometries for the Measurement of Viscoelastic Functions
49(8)
1 Linear Motion Geometries
49(4)
2 Rotational Motion Geometries
53(4)
Problems
57(7)
References
64(2)
3 Viscoelastic Models
66(59)
A Mechanical Elements
66(15)
1 Maxwell Model
68(6)
2 Voigt Model
74(2)
3 Generalized Maxwell Model
76(3)
4 Voigt--Kelvin model
79(2)
B Distributions of Relaxation and Retardation Times
81(3)
C Molecular Theories---The Rouse Model
84(9)
D Application of Flexible-Chain Models to Solutions
93(1)
E The Zimm Modification
94(2)
F Extension To Bulk Polymer
96(12)
G Reptation
108(4)
Appendix 3-1 Manipulation of the Rouse Matrix
112(5)
Problems
117(6)
References
123(2)
4 Time--Temperature Correspondence
125(25)
A Four Regions of Viscoelastic Behavior
125(8)
B Time--Temperature Superposition
133(3)
C Master Curves
136(1)
D The Wlf Equation
136(7)
E Molecular Interpretation of Viscoelastic Response
143(1)
Problems
144(5)
References
149(1)
5 Transitions and Relaxation in Amorphous Polymers
150(48)
A Phenomenology of the Glass Transition
150(5)
B Theories of the Glass Transition
155(11)
1 Free-Volume Theory
155(3)
2 Thermodynamic Theory
158(6)
3 Kinetic Theories
164(2)
C Structural Parameters Affecting the Glass Transition
166(6)
D Relaxations In the Glassy State
172(4)
E Relaxation Processes In Networks
176(4)
1 Physical Relaxation
176(1)
2 Chemical Processes
177(3)
F Biopolymer Viscoelasticity
180(9)
1 Biopolymer Sources
180(1)
2 Humidity Control
181(2)
3 Examples of Biopolymer Viscoelastic Response
183(6)
Problems
189(7)
References
196(2)
6 Elasticity of Rubbery Networks
198(51)
A Thermodynamic Treatment
199(6)
B Statistical Treatment
205(15)
1 Derivation
205(11)
2 Energy Contribution
216(4)
C Phenomenological Treatment
220(4)
D Factors Affecting Rubber Elasticity
224(10)
1 Effect of Degree of Crosslinking
224(2)
2 Effect of Swelling
226(3)
3 Effect of Fillers
229(3)
4 Effect of Strain-Induced Crystallization
232(2)
Appendix 6-1 Statistics of a Polymer Chain
234(6)
Appendix 6-2 Equation of State for a Polymer Chain
240(2)
Problems
242(4)
References
246(3)
7 Dielectric and NMR Methods
249(35)
A Dielectric Methods
249(25)
1 Phenomenology
250(7)
2 Molecular Interpretation of Dielectric Constant
257(7)
3 Interfacial Polarization
264(1)
4 Application to Polymers
265(3)
5 Experimental Methods
268(4)
6 Application of Dielectric Relaxation to Poly(methyl methacrylate)
272(1)
7 Comparisons between Mechanical and Dielectric Relaxation for Polymers
273(1)
B Nuclear Magnetic Resonance Methods
274(6)
Problems
280(2)
References
282(2)
Answers to Selected Problems
284(40)
Chapter 2
284(12)
Chapter 3
296(8)
Chapter 4
304(4)
Chapter 5
308(4)
Chapter 6
312(8)
Chapter 7
320(4)
List of Major Symbols 324(7)
List of Files on the Website 331(3)
Author Index 334(5)
Subject Index 339
MONTGOMERY T. SHAW, PhD, is Emeritus Distinguished Professor of Chemical Engineering at the University of Connecticut. Among his books are the prior edition of Introduction to Polymer Viscoelasticity and Introduction to Polymer Rheology, both published by Wiley.

WILLIAM J. MACKNIGHT, PhD, is a Professor Emeritus at the University of Massachusetts Amherst, where he was formerly the co-Principal Investigator for the Center for UMass/Industry Research on Polymers (CUMIRP). He has been a co-author for each edition of Introduction to Polymer Viscoelasticity, all published by Wiley.
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