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E-raamat: Liquid Silicone Rubber: Chemistry, Materials, and Processing

(University of Leoben, Austria)
  • Formaat: EPUB+DRM
  • Ilmumisaeg: 05-Jul-2019
  • Kirjastus: Wiley-Scrivener
  • Keel: eng
  • ISBN-13: 9781119631378
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  • Formaat: EPUB+DRM
  • Ilmumisaeg: 05-Jul-2019
  • Kirjastus: Wiley-Scrivener
  • Keel: eng
  • ISBN-13: 9781119631378
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One of the very few books devoted to the chemistry, materials and processing of liquid silicone rubber

The scientific literature with respect to liquid silicone rubber is collected in this monograph. The text focuses on the fundamental issues such as properties, curing methods, special materials, as well as the latest developments, and provides a broad overview of the materials used therein. In particular, materials and compositions for liquid functional rubbers are discussed. Methods of curing and special properties are also described, such as tracking and erosion resistance, adhesion properties, storage and thermal stability. Methods of curing are precision casting, hybrid additive manufacturing, peroxide curing, ultraviolet curing, liquid injection moulding, or hot embossing. The book includes applications including automotive and underwater applications, electrical and optical uses, as well as medical uses.
Preface xi
1 Materials 1(62)
1.1 History
1(1)
1.2 Properties
1(33)
1.2.1 Tracking and Erosion Resistance
1(3)
1.2.2 Enhancing Strength
4(3)
1.2.3 Surface Treatment
7(5)
1.2.4 Adhesion Properties
12(5)
1.2.5 Pressure-Sensitive Adhesive Film
17(3)
1.2.6 Storage Stability
20(1)
1.2.7 Thermal Stability
21(1)
1.2.8 Hydrophobed Pyrogenic Silica Filler
22(1)
1.2.9 Superhydrophobic Materials
22(2)
1.2.10 Thermally Conductive Materials
24(2)
1.2.11 Shape-Memory Materials
26(1)
1.2.12 Thermally Conductive Grease
27(2)
1.2.13 Self-Healing Materials
29(2)
1.2.14 Flame Retardancy
31(3)
1.3 Special Materials
34(23)
1.3.1 Borosilicones and Viscoelastic Silicone Rubbers
34(5)
1.3.2 Acrylo-Polyhedral Oligomeric Silsesquioxane
39(1)
1.3.3 Cellulose Nanocomposites
40(1)
1.3.4 Fluorine-Containing Poly(phenylsilsesquioxane)
40(1)
1.3.5 Silicone Rubber Overmolded Poly(carbonate)s
41(1)
1.3.6 Urethane-Containing Silane
42(2)
1.3.7 Glass Fiber Fabric
44(2)
1.3.8 Foams
46(2)
1.3.9 Addition Type Liquid Phenyl Silicone Rubber
48(2)
1.3.10 Organic Foaming Agent
50(2)
1.3.11 Foams without Chemical Blowing Agents
52(1)
1.3.12 Epoxy-Silicone Copolymer
53(4)
References
57(6)
2 Methods 63(22)
2.1 Special Curing Methods
63(10)
2.1.1 Precision Casting
63(1)
2.1.2 Hybrid Additive Manufacturing
64(1)
2.1.3 Peroxide Curing
64(4)
2.1.4 Ultraviolet Curing
68(2)
2.1.5 Addition-Curable Compositions
70(2)
2.1.6 Liquid Injection Molding
72(1)
2.1.7 Hot Embossing
73(1)
2.2 Hydrosilylation Catalysts
73(1)
2.3 Recoating Methods
74(1)
2.4 Shaped Elastomeric Bodies
75(6)
2.4.1 Tailoring of Elastomers
77(1)
2.4.2 Reinforcement of Elastomers
78(3)
References
81(4)
3 Automotive and Underwater Applications 85(36)
3.1 Automotive Applications
85(31)
3.1.1 Turbocharger Hose
85(2)
3.1.2 Automotive Airbags
87(20)
3.1.3 Silicone Rubber Sponge
107(4)
3.1.4 Dilatant Fluid
111(1)
3.1.5 Thermally Conductive Adhesive Composition
112(3)
3.1.6 Automobile Exhaust Systems
115(1)
3.2 Underwater Vehicles
116(2)
3.2.1 Buoyancy Control Device
116(2)
References
118(3)
4 Electrical and Optical Uses 121(88)
4.1 Electrically Conductive Silicone Rubber
121(3)
4.1.1 Conductive Liquid Silicone Rubber-Based Composites
122(1)
4.1.2 Effect of Shape and Size of Nickel-Coated Particles on Conductivity
123(1)
4.2 High-Voltage Insulation
124(3)
4.2.1 Platinum Catalyst and Nitrogen-Containing Silane
124(1)
4.2.2 Amine-Containing MQ Silicone Resin
125(1)
4.2.3 Tracking and Erosion Requirements
126(1)
4.3 Silicone Rubber Composite Insulators
127(16)
4.3.1 Electrical Insulator
128(9)
4.3.2 Liquid Silicone Rubber Exposed to Acid Fog
137(2)
4.3.3 Tracking and Erosion Resistance
139(1)
4.3.4 Color Fading
140(1)
4.3.5 Improving Tracking Resistance and Flame Retardancy
140(3)
4.4 Electromagnetic Wave Absorber
143(1)
4.5 Suppression of Surface Charge
143(5)
4.5.1 Outdoor Insulation Materials
143(1)
4.5.2 Antistatic Compositions
144(4)
4.6 Heat Dissipation Devices
148(4)
4.6.1 Liquid-Encapsulation Heat Dissipation Member
149(1)
4.6.2 Loop Heat Pipe
149(3)
4.7 Optical Fiber Sensor
152(1)
4.8 Optical Semiconductor Device
153(1)
4.9 Light-Emitting Devices
154(5)
4.9.1 Composition for a Light-Emitting Diode
154(2)
4.9.2 Encapsulating Materials
156(1)
4.9.3 Waterproof LED Lamp
157(1)
4.9.4 High Precision Optics
158(1)
4.10 Capacitance Sensors
159(1)
4.11 Dielectric Elastomer Transducers
159(2)
4.12 Solar Cells
161(3)
4.12.1 Foamed Sealing Materials
163(1)
4.13 Portable Electronic Devices
164(1)
4.14 Cable Accessories
165(8)
4.14.1 Water Diffusion Model
165(1)
4.14.2 Cold Shrink Splices
166(2)
4.14.3 Lubricious Cable Jackets for Medical Uses
168(5)
4.15 Electrophotography
173(12)
4.15.1 Electrophotographic Fixing Device
173(2)
4.15.2 Electrophotographic Copy Machine
175(10)
4.16 Secondary Battery Pack
185(4)
4.17 Pressure and Temperature Sensor
189(2)
4.18 Piezoresistive Device
191(2)
4.19 Proton Exchange Membrane Fuel Cells
193(3)
4.19.1 Degradation Experiments
193(3)
4.20 Light-Emitting Diodes
196(1)
4.21 Recycling of Used Composite Electric Isolators
197(1)
4.22 Triboelectric Nanogenerator for Wearable Electronics
198(1)
4.23 Large Specific Surface Area Electrodes
199(1)
4.24 Casing
199(2)
References
201(8)
5 Medical Uses 209(56)
5.1 Sensors for Medical Application
209(11)
5.1.1 Piezoresistant Sensor
209(2)
5.1.2 Pressure Sensor
211(1)
5.1.3 Flexible Pressure Sensor
212(1)
5.1.4 Intraocular Pressure Sensor
213(1)
5.1.5 Rod Template
213(2)
5.1.6 Cupping Appliance Device
215(5)
5.2 Materials for Medical Instruments and Uses
220(25)
5.2.1 Wound Regeneration
220(1)
5.2.2 Prostate Brachytherapy
221(1)
5.2.3 Breast Implants
222(1)
5.2.4 Implant with Reinforcing Fibers
223(1)
5.2.5 Hair Implants
224(3)
5.2.6 Nasal Implants
227(1)
5.2.7 Injectable Implants
227(2)
5.2.8 3D Printing of Medical Implants
229(1)
5.2.9 Voice Prostheses
230(1)
5.2.10 Implantable Medical Leads
231(1)
5.2.11 Cochlear Electrode Array
232(2)
5.2.12 Wear of the Total Intervertebral Disc Prosthesis
234(1)
5.2.13 Hand-Actuated Retention Catheter
234(3)
5.2.14 Medical Catheter
237(4)
5.2.15 Silicone-Coated Stents
241(1)
5.2.16 Suture Sleeve
242(1)
5.2.17 Silicone Tubings
243(1)
5.2.18 Fresnel Lenses
244(1)
5.3 Biomaterials
245(4)
5.3.1 Bioactive Peptides Grafted Silicone Dressings
245(1)
5.3.2 Antibacterial and Antibiofouling Clay Nanotube-Silicone Composites
246(1)
5.3.3 Biofunctionalization with Microgroove-Patterned Surface
247(1)
5.3.4 Bionic Composites
248(1)
5.4 Pharmaceutical Compositions
249(9)
References
258(7)
6 Other Uses 265(36)
6.1 Non-aqueous Organic Product Sensor
265(2)
6.2 Synthetic Leather
267(1)
6.3 Two-Part Curable Composition
268(2)
6.4 Microchannel Thermocured Silicone Rubber
270(1)
6.5 Dry Cleaning of Surfaces
271(4)
6.6 Adhesive Tapes
275(2)
6.7 Capsules for Beverages
277(3)
6.8 Usage for Toner
280(4)
6.9 Acoustic Applications
284(2)
6.10 High Temperature Gas Line Heater System
286(4)
6.11 Cosmetic Compositions
290(1)
6.11.1 Crosslinked Silicone Rubber Powder
290(1)
6.12 Silk Fibers
291(1)
6.13 Elastic Silicone Rubber Belt
292(3)
6.14 Recycling and Devulcanizing
295(1)
6.15 Mobile Robots
296(1)
References
297(4)
Index 301(1)
Acronyms 301(2)
Chemicals 303(5)
General Index 308
Johannes Karl Fink is Professor of Macromolecular Chemistry at Montanuniversität Leoben, Austria. His industry and academic career spans more than 30 years in the fields of polymers, and his research interests include characterization, flame retardancy, thermodynamics and the degradation of polymers, pyrolysis, and adhesives. Professor Fink has published several books on physical chemistry and polymer science including A Concise Introduction to Additives for Thermoplastic Polymers (Wiley-Scrivener 2009), The Chemistry of Biobased Polymers (Wiley-Scrivener 2014), Polymer Waste Management (Wiley-Scrivener 2018) and 3D Industrial Printing with Polymers (Wiley-Scrivener 2019).