| Introduction |
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xiii | |
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1 Basic Concepts and Representations of Mechanochemistry: Methods of Mechanical Action and Physicochemical Changes of the Substance |
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1 | (14) |
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1.1 Historical Stages in the Development of Mechanochemistry as a Technological Process |
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1 | (6) |
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1.2 Methods of Action and the Main Physicochemical Processes in the Mechanochemistry of Inorganic and Organic Substances |
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7 | (8) |
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2 Mechanochemical Treatment, Activation, Synthesis, and Modification of the Surface of Particles of Inorganic Materials |
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15 | (48) |
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2.1 Theoretical Basis of Crushing and Activation of Solids: Energy Intensity of Grinding Machines and Stored Energy of Materials Processed in Them |
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15 | (6) |
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2.2 Physicochemical Processes of Substance Transformation during Mechanochemical Treatment |
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21 | (24) |
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2.2.1 Deformation, Destruction, and Activation are the Main Stages in the Transformation of Matter under Mechanical Action |
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21 | (4) |
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2.2.2 Models of Mechanochemical Processes: The Localization of Deformation and the Physicochemical Processes Accompanying It |
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25 | (8) |
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2.2.3 Mechanisms of Initiation of Mechanochemical Reactions |
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33 | (8) |
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2.2.4 Structural Rearrangement and Modification of the Surface of Dispersible Particles |
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41 | (4) |
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2.3 Kinetics and Thermodynamics of Mechanochemical Treatment of Inorganic Materials |
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45 | (7) |
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2.4 Features of Mechanochemistry of Organic Compounds and Systems of Inorganic and Organic Materials |
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52 | (11) |
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3 Principles of Mechanochemical Activation in Technological Processes |
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63 | (38) |
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3.1 The Influence of the Form of Grinding Bodies on the Parameters of Mechanochemical Treatment |
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63 | (9) |
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3.2 Influence of the Coated Layer Thickness on the Parameters and Kinetics of Mechanical Activation |
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72 | (9) |
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3.3 The Phenomenon of Abrasive-Reactive Wear in Mechanochemical Processes |
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81 | (9) |
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3.4 The Effectiveness of the Implementation of the Abrasive-Reactive Wear in the Mechanochemical Processing of Mineral Raw Materials |
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90 | (11) |
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4 Structural Changes of Silicon Dioxide under Thermal and Mechanical Impact |
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101 | (18) |
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4.1 The Variety of Structural Forms and Features of the Surface Layers of Silicon Dioxide |
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101 | (5) |
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4.2 Mechanochemistry of Quartz, Features of Structural Changes during Dispersion of Quartz--Surface Radicals and Their Transformation |
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106 | (5) |
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4.3 Modification and Radical Polymerization of the Surface of Quartz Particles during Mechanochemical Processing |
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111 | (8) |
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5 Activation and Modification of Quartz in Mechanical Reactors: Synthesis of Nanocomposition Quartz Particles Capsulated in Carbon-Containing Shells |
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119 | (74) |
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5.1 Changes in the State, Structure, and Properties of Activated Quartz |
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119 | (11) |
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5.2 Structure, State, and Properties of Quartz Powder after Mechanical Treatment with Modifiers |
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130 | (10) |
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5.3 Morphological and Structural Features of Activated and Modified Quartz |
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140 | (35) |
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5.3.1 Electron Microscopy of Modified Quartz |
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140 | (7) |
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5.3.2 IR Spectroscopy of Activated and Modified Quartz |
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147 | (9) |
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5.3.3 EPR, Mossbauer Spectroscopy and X-Ray Phase Analysis of Quartz Modified by Mechanochemical Processing |
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156 | (19) |
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5.4 Features of Ferromagnetism of Quartz Powder Induced as a Result of Mechanochemical Processing |
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175 | (18) |
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6 Theoretical Preconditions for Creation of Mechanochemical Synthesis of Composite Nanostructured Systems Based on Quartz |
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193 | (34) |
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6.1 The Main Processes in Mechanochemistry of the Quartz Particle Modification |
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193 | (13) |
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6.2 The Piezoelectric Effect of Quartz Is Part of the Process of Modifying the Surface of Particles with Organic Compounds |
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206 | (8) |
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6.3 Simulation of the Process |
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214 | (13) |
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7 Mechanochemical Synthesis of Disperse Composition Systems of Different Purpose |
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227 | (24) |
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7.1 Composition Systems Quartz Core-Polymer Shell |
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227 | (8) |
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7.2 Composite Systems Inorganic Core-Polymer Shell, Obtained by Mechanochemical Treatment of Calcite and Wollastonite |
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235 | (16) |
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8 Mechanochemistry under the Conditions of Ultrasonic Treatment of Powder Systems |
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251 | (44) |
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8.1 Ultrasonic Treatment of the Material Is a Way to Change the Structure and State and Obtaining Nanostructured Systems |
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251 | (5) |
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8.2 Changes in the Structure, Properties, and Modification of Quartz and Calcite under the Influence of Ultrasound |
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256 | (8) |
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8.3 Changes in the Structure, Properties, and Modification of Wollastonite under the Influence of Ultrasound |
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264 | (10) |
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8.4 Simulation and Quantum-Chemical Calculations of the Formation of Surface Compounds in the Mechanochemical Synthesis of Hybrid Powder Nanocomposite Systems |
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274 | (21) |
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8.4.1 Methods for Calculating the Electronic Structure of Molecules and Solids, Simulation and Quantum |
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274 | (6) |
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8.4.2 Adsorption Complexes of Butanol and Urea on the Surface of Silica and Wollastonite |
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280 | (15) |
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9 Mechanochemical Treatment and Modification of Metal Systems |
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295 | (40) |
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9.1 Mechanochemical Treatment of Aluminum Powders with Organic Additives |
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298 | (11) |
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9.2 Mechanochemical Activation of Aluminum Powders with Organic Modifiers in the Presence of Quartz |
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309 | (4) |
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9.3 Study of Aluminum-Based Powders after MCT |
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313 | (13) |
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9.4 Determination of the Activity of Modified Aluminum Powders |
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326 | (9) |
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10 Fields of Application of Composite Materials Obtained Using MCT |
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335 | (104) |
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10.1 Mechanochemical Synthesis of Multifunctional Sorbents Based on Nanostructured Composite Quartz-Containing Systems |
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335 | (21) |
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10.1.1 Modified Quartz as a Sorbent Material for Water Purification from Various Types of Pollution |
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337 | (6) |
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10.1.2 Magnetic Sorbents Obtained by Mechanochemical Treatment of Quartz-Containing Systems to Collect Oil from the Water Surface |
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343 | (13) |
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10.2 Composite Systems with Fillers Modified by Mechanochemical and Ultrasonic Treatment |
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356 | (19) |
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10.3 SH-Synthesis of Ceramic Materials Based on Pre-Activated and Modified Systems |
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375 | (40) |
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10.3.1 The Main Macrokinetic Aspects of the Synthesis of SHS Systems and Methods of Process Control |
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375 | (5) |
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10.3.2 Influence of Mechanochemical Treatment and Modification of Quartz, Calcite and Wollastonite on the Technological Combustion of Systems |
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380 | (22) |
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10.3.4 SH-Synthesis of Composite Systems with Participation of Aluminum Modified during MCT |
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402 | (13) |
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10.4 The Use of Energy-Intensive Powders Based on Aluminum, Obtained by Mechanochemical Treatment, in the Composition of Solid Rocket Fuels |
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415 | (24) |
| Index |
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439 | |