Proceedings of the NATO Advanced Research Workshop, held in Kyiv, Ukraine, from 8 to 12 June 2003
Advanced mixed ionic electronic conducting (MIEC) perovskites play an important role in many electrochemical systems for advanced energy technologies. They are major components in such devices as solid oxide fuel cells (SOFCs), oxygen separation membranes, chemical sensors and catalysts. In addition to energy technology, the development of these multifunctional materials is of crucial importance for transportation, aerospace engineering, and electronics. The use of these materials as chemical sensors is also important for anti-terrorism initiatives. The present book discusses progress and problems in the development of ionic, electronic, and MIEC materials as active materials in advanced energy systems; the development and design of solid-oxide fuel cells (SOFCs) for next-generation vehicles, chemical sensors and oxygen separation membranes; and identifies directions for future research, such as conducting mechanisms, stability and reliability of devices, degradation problems, crystal structure, classification of phase transitions exhibited by the materials.
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Oxide Components for the Solid Oxide Fuel Cell.- Vacancy Segregation at
Grain Boundaries in Ceramic Oxides.- Metallic Conductivity and Magnetism: The
Great Potential of Manganese and Cobalt Perovskites.- Raman Diagnostics of
LaCoO3 Based Perovskites.- Mobility and Reactivity of the Surface and Lattice
Oxygen of Some Complex Oxides with Perovskite Structure.- LaFeO3 and LaCoO3
Based Perovskites: Preparation and Properties of Dense Oxygen Permeable
Membranes.- Optimisation of Perovskite Materials for Fuel Electrodes.- Single
Crystal Growth of Oxides and Refractory Materials.- Ionic Transport in
Perovskite-Related Mixed Conductors: Ferrite-, Cobaltite-, Nickelate-, and
Gallate-Based Systems.- Structural/Property Relationships of The Mixed
Electronic/Ionic Conductors Based on Lanthanum Gallate.- Microwave-Assisted
Regeneration of Soot Filters.- Microheterogeneous Solid Solutions in
Perovskites: Formation, Microstructure, and Catalytic Activity.- Phase
Transitions and Ion Transport in SrFe 1-XMXO2.5, Where M = Ga, Cr.-
Connection of Giant Volume Magnetostriction with Colossal Magnetoresistance
in Manganites.- SOFC Perspectives in Ukraine.- Measurement of Oxygen Ionic
Transport in Mixed Conductors.- A New Approach to The Defect Chemistry of
Doped Lal-?MnO3+?.- Structure, Microstructure and Transport Properties of
Mixed Conducting Lanthanum Gallate Based Perovskite Ceramics.- Synthesis
Structure peculiarities of (La, Sr)MnO3 Based Nanomanganites.- Nanoscale
magnetism and Magnetotransport Phenomena of (LaSr)MnO Compact.- LSGM Single
Crystals: Crystal Structure, Thermal Expansion, Phase Transitions and
Conductivity.- Real Structure of LSGMO Crystal Studied by Laue Method.-
Microwave Regeneration of Diesel Soot Filters.- Oxygen Transport in composite
Materials for OxygenSeparators and Syngas Membranes.- Pulsed Lased Deposition
of MIEC Sr4Fe6O13±? Epitaxial Thin Films.- The Development of Gas Tight Thin
Films of (La,Sr)(Ga,Fe)O3, (La,Sr)(Co,Fe)O3, and La2Nio4 for Oxygen
Separation.- Investigation into Thermal Expansion and Sintering of La2Mo4+D
(Ln = La, Pr and M = Ni, Co).- Oxide Ion Transport in Novel K2NiF4-Type
Oxides.- Conductivity and Electronic Structure of Lanthanum Nickelites.-
Defect Chemistry of Mixed Ionic/Electronic P-Type Oxides.- Authors Index.-
Notes.
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