| Preface |
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v | |
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Introduction and a short dictionary of network terminology |
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1 | (18) |
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Who is this book written for? |
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2 | (1) |
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Nomenclature used in this book |
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2 | (2) |
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Why did we write this book? |
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4 | (4) |
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4 | (1) |
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4 | (1) |
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Problems with names and nomenclature |
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5 | (1) |
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What this book is and is not |
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6 | (1) |
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6 | (2) |
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Some words, their origin and current usage |
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8 | (11) |
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Tectons and building blocks |
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9 | (1) |
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Nets of coordination polymers and metal-organic frameworks |
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10 | (1) |
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Crystal engineering and reticular chemistry |
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11 | (1) |
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Supramolecular self assembly using synthons and secondary building units |
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12 | (2) |
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14 | (5) |
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19 | (20) |
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Possible impact on society |
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19 | (2) |
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A fruitful way of looking at molecular crystals with strong, directed intermolecular bonding |
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21 | (4) |
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The analysis of a crystal structure |
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21 | (2) |
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Three reasons for the net approach |
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23 | (1) |
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Seeing the structure in all these structures |
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24 | (1) |
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Synthetic targets for molecular nets: magnetism, chiral channels, gas storage and more |
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25 | (7) |
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Intrinsic properties of 3D-nets |
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25 | (1) |
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26 | (6) |
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Patents related to molecular 3D-nets |
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32 | (7) |
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39 | (18) |
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40 | (2) |
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Short survey of network interactions |
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42 | (9) |
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42 | (1) |
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43 | (2) |
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``Normal'' hydrogen bonds |
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45 | (2) |
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47 | (2) |
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49 | (1) |
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50 | (1) |
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Metal-metal bonds and interactions |
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50 | (1) |
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51 | (2) |
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53 | (4) |
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``Nature abhors a vacuum'' |
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53 | (4) |
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Naming the nets and finding them |
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57 | (24) |
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A state of some concern, but with a solution? |
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57 | (1) |
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58 | (11) |
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Nomenclature according to Wells |
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60 | (1) |
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60 | (1) |
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61 | (2) |
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Extended Schlafli or vertex symbols |
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63 | (1) |
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Zeolite-like abbreviations |
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64 | (3) |
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67 | (1) |
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68 | (1) |
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68 | (1) |
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69 | (4) |
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69 | (3) |
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72 | (1) |
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73 | (3) |
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73 | (2) |
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Searching the Cambridge Structural Database |
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75 | (1) |
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76 | (1) |
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A few words about Alexander F. Wells |
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77 | (4) |
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81 | (18) |
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Requirements for a 3D-net |
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82 | (1) |
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83 | (16) |
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The 103-srs or (10, 3)-a net, also known as the SrSi2 net |
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84 | (2) |
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The 103-ths or (10, 3)-b net, also called the ThSi2-net |
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86 | (1) |
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The 66-dia or diamond net |
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87 | (2) |
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The 64.82-nbo or NbO net with square planar coordination |
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89 | (1) |
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The 65.8-cds or cadmium sulphate net with square planar coordination |
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90 | (2) |
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The platinum sulphide, (42.84)(42.84)-pts net, a square and a tetrahedron |
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92 | (1) |
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The 46.64-bnn, or boron nitride net |
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93 | (1) |
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The 412.63-pcu net with octahedral nodes |
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94 | (5) |
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99 | (28) |
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Some remarks concerning the building blocks |
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99 | (3) |
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99 | (2) |
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Torsion angles, ω, between consecutive nodes |
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101 | (1) |
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102 | (1) |
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Uninodal three-connected nets |
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102 | (12) |
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102 | (1) |
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The (10, 3)-c 103-bto net |
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103 | (2) |
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The (10, 3)-d or 103-utp net |
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105 | (1) |
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Other uninodal (10, 3)-nets |
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106 | (2) |
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The (8, 3)-a and (8, 3)-b nets (83-eta and 83-etb) |
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108 | (2) |
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The (8210)-a, LiGe or 82.10-lig net |
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110 | (1) |
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110 | (1) |
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111 | (1) |
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112 | (2) |
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Binodal three-connected nets |
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114 | (6) |
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The (6.102)(62.10)-nof net |
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114 | (1) |
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115 | (1) |
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The (103)(6.102)3-noh net |
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116 | (1) |
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The (82.10)(82.10)-nod or (82.10)-b net |
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117 | (1) |
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The (6.122)(6.102)2-nob net |
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118 | (1) |
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Two uniform binodal nets: (9, 3)-a: (93)(93)-nta and (9, 3)-b: (93)(93)2-ntb |
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119 | (1) |
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Trinodal three-connected nets |
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120 | (3) |
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The (4.122)(4.122)(4.122)-mot-a net |
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120 | (1) |
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The (72.8)2(72.8)(7.123)-noe net |
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121 | (1) |
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(4.122)(4.122)2(123)2-``net 10'' |
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122 | (1) |
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Multinodal three-connected nets |
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123 | (1) |
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The (83)(83)(82.10)(82.10) (83)(83)-nos net, a hexanodal net. |
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123 | (1) |
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Summary of three-connected nets |
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123 | (4) |
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127 | (22) |
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Uninodal tetrahedral nets |
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127 | (12) |
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The SrAl2 or 42.63.8-sra net |
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127 | (2) |
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The sodalite or 42.64-sod net |
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129 | (1) |
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The quartz or 66.82-qtz net |
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130 | (2) |
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132 | (1) |
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The gismondine or 43.83-gis net |
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133 | (1) |
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The lonsdaleite or 66-lon net |
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134 | (1) |
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The Irish ladder or 42.63.8-irl net |
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135 | (1) |
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The polycubane or 43.83-pcb net |
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136 | (1) |
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137 | (1) |
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66-neb, 54.62-unh, 4.65-cag, 66-gsi, 66-mmt, and 4.64.8-zni |
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138 | (1) |
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Uninodal nets with ``square planar'' nodes |
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139 | (2) |
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139 | (1) |
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140 | (1) |
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Nets with both tetrahedral and square planar nodes |
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141 | (8) |
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The twisted pts or (4.63.82)2(42.62.82)(62.84)-ptt net |
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142 | (1) |
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The or (42.62.82)2(4.64.8)-mog net |
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143 | (1) |
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The (43.63)4(64.102)-asv net |
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144 | (5) |
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Nets with both three-and four-connected nodes |
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149 | (16) |
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Alternating nets with stoichiometry (3-conn)4(4-conn)3 (ns3/ns4 = 4/3) |
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150 | (5) |
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Boracite, (63)4(62.84)3-bor and twisted boracite (63)4(62.82.102)3-tho |
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150 | (2) |
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The Pt3O4 or (83)4(86)3-pto net |
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152 | (1) |
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The C3N4 or (83)4(86)3-ctn net |
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153 | (1) |
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Other alternating nets with stoichiometry (3-conn)4(4-conn)3 |
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154 | (1) |
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Nets with 1:1 stoichiometery (ns3/ns4 = 1) |
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155 | (2) |
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The InS or (63)(65.8)-ins net |
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155 | (1) |
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156 | (1) |
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Nets with 1:2 stoichiometery (ns3/ns4 = 1/2) |
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157 | (1) |
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The (5.82)(4.52.6.7.8)2-dme net |
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157 | (1) |
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158 | (1) |
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Nets with 4:1 stoichiometery (ns3/ns4 = 4) |
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158 | (3) |
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The (62.10)4(64.102)-jph net |
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159 | (1) |
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160 | (1) |
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Nets with 2:1 stoichiometery (ns3/ns4 = 2) |
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161 | (1) |
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The (83)(86)2-tfa net based on tetrahedral nodes |
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161 | (1) |
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The (83)(85.12)2 tfc net based on square planar four connected nodes |
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161 | (1) |
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Summary of three- and four-connected nets |
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162 | (3) |
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Nets with higher connectivity than four |
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165 | (26) |
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165 | (4) |
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165 | (1) |
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166 | (2) |
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168 | (1) |
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The 34.42.84-cab net and other five-connected nets with cubic symmetry |
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168 | (1) |
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169 | (4) |
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The NiAs or the (412)(49.66)-nia net |
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169 | (1) |
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170 | (1) |
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171 | (1) |
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172 | (1) |
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173 | (1) |
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173 | (1) |
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174 | (2) |
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The CsClor 424.64-bcu net |
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175 | (1) |
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175 | (1) |
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Nets with three- and five-connected nodes |
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176 | (2) |
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The stacked hexagonal layer net, or (63)(69.8)-hms net |
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176 | (1) |
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The graphite or (63)(69.8)-gra net |
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177 | (1) |
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The (4.82)(4.56.6.82)-mcf-d net |
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178 | (1) |
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Nets with three- and six-connected nodes |
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178 | (5) |
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The rutile or (4.62)(42.610.83)-rtl net |
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178 | (1) |
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The pyrite or (63)(612.83)-pyr net |
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179 | (3) |
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The (4.62)(4.2.610.82)-sit net |
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182 | (1) |
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Nets with four- and six-connected nodes |
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183 | (2) |
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Tetrahedrons and octahedrons; the corundum or (43.63)3(46.69)2-cornet |
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183 | (1) |
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Square planar and octahedral nodes, the (44.62)(48.67)-fsg net |
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184 | (1) |
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Tetrahedrons and octahedrons, another (44.62)(48.66.8) net |
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185 | (1) |
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Tetrahedrons and octahedrons; the (43.63)(46.66.83)-fsh net |
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185 | (1) |
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Nets with four- and eight-connected nodes |
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185 | (2) |
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185 | (2) |
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Summary of higher connected nets |
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187 | (4) |
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Some mathematics related to 3D-nets |
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191 | (20) |
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Nets, Polyhedra and Topology |
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192 | (5) |
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192 | (1) |
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The Platonic bodies and the (n, p) relation to dimensionality |
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192 | (3) |
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195 | (2) |
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197 | (10) |
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A classification of nets in terms of their genus |
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197 | (2) |
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Comparison to Wells Zt classification |
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199 | (3) |
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Nets as tilings and the concept of transitivity |
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202 | (2) |
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The analysis of the voids as the dual of a net |
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204 | (2) |
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The pqrs to srqp relation of dual nets |
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206 | (1) |
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207 | (4) |
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Interpenetration - strategies and nomenclature |
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211 | (16) |
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211 | (1) |
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Strategies to control interpenetration |
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212 | (5) |
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212 | (1) |
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Lengths and thickness of links, size of counter ion |
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213 | (2) |
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Analysis of the voids within a net |
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215 | (2) |
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Specially designed ligands |
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217 | (1) |
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217 | (10) |
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3D-nets as specific synthetic targets -- Crystal Engineering |
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227 | (18) |
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Choice of interaction (hydrogen bonds, coordinative bonds etc) |
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227 | (4) |
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227 | (1) |
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Metal-ligand bonds (coordination bonds) |
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227 | (1) |
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228 | (2) |
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Connecting the building blocks |
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230 | (1) |
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231 | (4) |
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Solvents and concentrations |
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231 | (1) |
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231 | (1) |
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Methods of crystallization |
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232 | (1) |
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Hydrothermal or solvothermal methods |
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233 | (1) |
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Grinding and kneading, mechanochemical methods |
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234 | (1) |
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Synthesis of chiral, porous, 3D nets |
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235 | (4) |
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Intrinsic chiral nets and induced chiral nets |
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235 | (2) |
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237 | (1) |
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Some chiral nets other than srs |
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238 | (1) |
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Some notes on polymorphism and supramolecular isomerism |
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239 | (2) |
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Specific properties of nets and their analysis |
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241 | (4) |
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245 | (12) |
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Regular visualisation tools for net discovery and analysis |
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245 | (6) |
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246 | (2) |
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248 | (3) |
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251 | (1) |
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251 | (1) |
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Software packages that can search for a nets |
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251 | (6) |
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251 | (3) |
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254 | (3) |
| Appendix A |
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257 | (1) |
| Ideal nets |
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257 | (14) |
| Appendix B |
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271 | (1) |
| Stereo drawings |
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271 | (40) |
| Subject Index |
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311 | |
Lisainfo e-raamatute kohta