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E-raamat: Organophosphorus Chemistry: Volume 35

Contributions by (University of Groningen), Contributions by (King's College London), Contributions by (Polish Academy of), Contributions by (Sheffield Hallam University), Contributions by , Edited by (Sheffield Hallam University, UK), Contributions by (University of Cambridge, UK), Contributions by (Queen's University Belfast), Edited by (Sheffield Hallam University, UK)
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Organophosphorus Chemistry provides a comprehensive annual review of the literature. Coverage includes phosphines and their chalcogenides, phosphonium salts, low coordination number phosphorus compounds, penta- and hexa-coordinated compounds, tervalent phosphorus acids, nucleotides and nucleic acids, ylides and related compounds, and phosphazenes. The series will be of value to research workers in universities, government and industrial research organisations, whose work involves the use of organophosphorus compounds. It provides a concise but comprehensive survey of a vast field of study with a wide variety of applications, enabling the reader to rapidly keep abreast of the latest developments in their specialist areas. Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.

A concise but comprehensive annual survey of a vast field of study enabling the reader to rapidly keep abreast of the latest developments in this specialist area.



Organophosphorus Chemistry provides a comprehensive annual review of the literature. Coverage includes phosphines and their chalcogenides, phosphonium salts, low coordination number phosphorus compounds, penta- and hexa-coordinated compounds, tervalent phosphorus acids, nucleotides and nucleic acids, ylides and related compounds, and phosphazenes. The series will be of value to research workers in universities, government and industrial research organisations, whose work involves the use of organophosphorus compounds. It provides a concise but comprehensive survey of a vast field of study with a wide variety of applications, enabling the reader to rapidly keep abreast of the latest developments in their specialist areas. Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.

Chapter 1: Phosphines and Related Tervalent Phosphorus Systems;
1: Introduction;
2: Phosphines;
2.1: Preparation;
2.2: Reactions of Phosphines;
3: p?-Bonded Phosphorus Compounds;4: Phosphirenes, Phospholes and Phosphinines;
References;
Chapter 2: Phosphonium Salts and Phosphine Chalcogenides;
1: Phosphonium Salts;
1.1: Preparation;
1.2: Reactions of Phosphonium Salts;
2: Phosphine Chalcogenides;
2.1: Preparation;
2.2: Reactions;
2.3: Structural and Physical Aspects;
2.4: Phosphine Chalcogenides as Ligands;
References;
Chapter 3: Tervalent Phosphorus Acid Derivatives;
1: Introduction;
2: Halogenophosphines;
3: Tervalent Phosphorus Esters;
3.1: Phosphinites;
3.2: Phosphonites;
3.3: Phosphites;
4: Tervalent Phosphorus Amides;
4.1: Aminophosphines;
4.2: Phosphoramidites and Related Compounds;
References;
Chapter 4: Quinquevalent Phosphorus Acids;
1: Introduction;
2: Phosphoric Acids and Their Derivatives;
2.1: Synthesis of Phosphoric Acids and Their Derivatives;
2.2: Reaction of Phosphoric Acids and Their Derivatives;
2.3: Selected Biological Aspects;
3: Phosphonic and Phosphinic Acids;
3.1: Synthesis of Phosphonic and Phosphinic Acids and Their Derivatives;
3.2: Reactions of Phosphonic and Phosphinic Acids and Their Derivatives;
3.3: Selected Biological Aspects;
4: Structure;
References;
Chapter 5: Pentacoordinated and Hexacoordinated Compounds;
Summary;
1: Introduction;
2: Acyclic Phosphoranes;
3: Monocyclic Phosphoranes;
4: Bicyclic Phosphoranes;
5: Hexacoordinate Phosphorus Compounds;
References;
Chapter 6: Nucleic Acids and Nucleotides: Mononucleotides;
1: Introduction;
2: Mononucleotides;
2.1: Nucleoside Acyclic Phosphates;
3: Nucleoside Polyphosphates;3.1: Polyphosphorylated Nucleosides;
3.2: Nucleoside Pyrophosphates;
References;
Chapter 7: Nucleotides and Nucleic Acids;
Oligo- and Poly-nucleotides;
1: Introduction;
1.1: Oligonucleotide Synthesis;
1.2: RNA Synthesis;
1.3: The Synthesis of Modified Oligodeoxyribonucleotides and Modified oribonucleotides;
2: Aptamers;
3: Oligonucleotide Conjugates;
3.1: Oligonucleotide-Peptide Conjugates;
3.2: DNA Templated Organic Synthesis;
3.3: Oligonucleotide-Metal Conjugates;
3.4: Charge Transport;
3.5: Fluorescence;
3.6: Miscellaneous Conjugates;
4: Nucleic Acid Structures;
References;
Chapter 8: Phosphazenes;
1: Introduction;
2: Linear Phosphazenes;
3: Cyclophosphazenes;
4: Polyphosphazenes;
5: Crystal Structures of Phosphazenes and Related Compounds;
References;

Professor David Allen is Emeritus professor of chemistry at the University of Sheffield, UK. His main research interests are in phosphonium salts and related compounds. Current interests include the preparation of phosphonioalkyl derivatives of biologically active molecules, the phosphonioalkyl group facilitating the passage of the biologically active agent through cell membranes, and studies of the formation of biologically active surface-functionalised gold nanoparticles. Professor John C Tebby is a retired organophosphorus chemist, formerly at Keele University, UK.
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