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E-raamat: Perfluorinated Chemicals (PFCs): Contaminants of Concern

  • Formaat: PDF+DRM
  • Ilmumisaeg: 29-Nov-2016
  • Kirjastus: Wiley-Scrivener
  • Keel: eng
  • ISBN-13: 9781119363835
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  • Formaat: PDF+DRM
  • Ilmumisaeg: 29-Nov-2016
  • Kirjastus: Wiley-Scrivener
  • Keel: eng
  • ISBN-13: 9781119363835

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This new volume provides a timely study on the environmental challenges from a specific class of perfluorinated chemical compounds (PFCs) that are now being recognized as a worldwide health threat.  Recent studies report that levels of classes of PFCs known as polyfluoroalkyl and perfluoroalkyl (PFASs) exceed federally recommended safety levels in public drinking-water supplies for 6 million people in the United States and that as many as 100 million people could be at risk from exposure to these chemicals.

These chemicals occur globally in wildlife and humans. Both PFCAs and PFSAs have been produced for more than 50 years, but have only become of interest to regulators and environmentalists since the late 1990s. Recent advances in analytical methodology has enabled widespread detection in the environment and humans at trace levels. These toxic chemicals have been found in outdoor and indoor air, surface and drinking water, house dust, animal tissue, human blood serum, and human breast milk. Of great concern to communities is the presence of these compounds in a number of drinking water supplies in the U.S. and other countries.

This new volume provides a timely explanation of the chemicals, provides a detailed review of the regulations both in the US and European Community, explains the health risk literature, and then explores in great detail available treatment technologies. The volume is a must for public water supply facilities, industrial operations that have historically used these chemicals and face legacy pollution issues, policy makers and the general public.

Preface ix
About the Author xv
Abbreviations and Acronyms xvii
Useful Conversion Factors xxi
1 What Fluoropolymers Are
1(20)
1.1 Introduction
1(2)
1.2 Evolution of Fluoropolymers and the Markets
3(3)
1.3 PFAS Compounds
6(11)
1.3.1 General Description
6(4)
1.3.2 How They Are Made
10(5)
1.3.3 The Proliferation of PFAS
15(2)
1.4 Terminology
17(4)
References
19(2)
2 Definitions, Uses, and Evolution of PFCs
21(34)
2.1 Perfluorinated Chemicals (PFCs) Of Interest
21(22)
2.2 The PFC Family
43(1)
2.3 PFOS
44(5)
2.4 PFOA
49(1)
2.5 Fluorotelomers
50(5)
References
52(3)
3 Fire Fighting Foams
55(8)
3.1 What AFFFs Are
55(3)
3.2 Environmental Impacts
58(5)
References
62(1)
4 Health Risk Studies
63(28)
4.1 General
63(2)
4.2 PFOA
65(12)
4.3 PFOS
77(1)
4.4 EFSA -- EU Food and Safety Authority Findings
77(14)
References
90(1)
5 Overview of the Environmental Concerns
91(18)
5.1 Where It All Began
91(2)
5.2 Emerging Contaminants of Concern
93(3)
5.3 PFOS
96(4)
5.4 PFOA
100(9)
References
107(2)
6 The Supply Chain and Pathways to Contamination
109(20)
6.1 Losses Along the Supply Chain and End of Life
109(10)
6.2 Consumer Articles
119(5)
6.3 Consumer Exposure to PFOS And PFOA
124(5)
References
127(2)
7 Standards, Advisories, and Restrictions
129(24)
7.1 Extent of Groundwater Contamination in the United States
129(4)
7.2 The U.S. Water Quality Standards
133(9)
7.3 Remedial Guidelines
142(1)
7.4 Standards in Other Countries
143(10)
7.4.1 United Kingdom
144(1)
7.4.2 Canada
144(1)
7.4.3 Germany
145(1)
7.4.4 Norway
145(1)
7.4.5 European Union (EU)
146(2)
7.4.6 OECD
148(1)
7.4.7 Stockholm Convention on Persistent Organic Pollutants (POPs)
149(1)
7.4.8 United Nation's Economic Commission for Europe (ECE)
150(1)
References
151(2)
8 Overview of Water Treatment Technology Options
153(12)
8.1 Technology Options
153(3)
8.2 Case Studies, Literature, and Technologies
156(9)
Reference
163(2)
9 Adsorption Technology
165(38)
9.1 Overview
165(4)
9.2 Activated Carbon and Other Carbonaceous Adsorbents
169(9)
9.3 Zeolites
178(1)
9.4 Polymeric Adsorbents
179(1)
9.5 Oxidic Adsorbents
180(1)
9.6 Adsorption Theory Basics and Isotherms
181(5)
9.7 Adsorption of PFOA
186(3)
9.8 Hardware and Operational Considerations
189(7)
9.9 Backwashing
196(1)
9.10 Permitting
197(1)
9.11 Spent Carbon Management
197(1)
9.12 Recommended References
198(5)
References
201(2)
10 Case Studies
203(26)
10.1 PFOA in Southern New Hampshire
203(3)
10.2 Former Wurtsmith Air Force Base
206(7)
10.3 Dupont Washington Works in West Virginia
213(5)
10.4 PFC Contamination in Minnesota
218(11)
References
228(1)
Index 229
Nicholas P. Cheremisinoff is the Principal of No Pollution Enterprises. He is a chemical engineer specializing in the safe handling and management of industrial chemicals and hazardous materials with nearly forty years of industry, business and applied research experience. He earned his B.Sc., M.Sc. and Ph.D. in chemical engineering from Clarkson College of Technology in Potsdam, New York. Over his long career he has worked pollution prevention and waste to energy projects in the refining, gas processing and the petrochemicals industries for numerous U.S. and foreign clients. For international lending institutions including the World Bank Organization, the U.S. Export-Import Bank, the International Finance Corporation, and donor agencies including the U.S. Agency for International Development, the U.S. Trade & Development Agency, and the European Union he has served as consultant and technical advisor on pollution management, worker safety, and environmental management practices. He has also held academic positions, including adjunct professor at the New Jersey Institute of Technology and Farleigh Dickenson University, and has been an invited Lecturer at the Russian and Ukrainian Academies of Sciences, the Jordan University of Science and Technology, Texas A&M University, University of Missouri-Rolla, Cooper Union University, and the University of Leuven. He has authored, co-authored or edited more than 100 technical reference and textbooks.