About the Author |
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xi | |
Preface |
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xiii | |
Acknowledgments |
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xv | |
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2 | (2) |
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1.2 Low Temperature in Science and Technology |
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4 | (4) |
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1.3 Defining Cryogenic Fluids or Liquids |
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8 | (10) |
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1.4 Heat Transfer and Thermal Design |
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18 | (7) |
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1.5 Refrigeration and Liquefaction |
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25 | (8) |
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1.6 Industrial Applications |
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33 | (14) |
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1.7 Cryogenic Fluid Management |
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47 | (3) |
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50 | (4) |
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50 | (1) |
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51 | (3) |
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2 Properties of Pure Substances |
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54 | (1) |
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2.2 Properties of Pure Substances: Phase Changes |
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55 | (3) |
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58 | (1) |
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2.4 Real Gases and Vapors |
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59 | (14) |
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2.5 T---V Diagram for a Simple Compressible Substance |
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73 | (1) |
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2.6 P---V Diagram for a Simple Compressible Substance |
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73 | (2) |
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2.7 P---V---T Diagram for a Simple Compressible Substance |
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75 | (6) |
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79 | (1) |
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79 | (2) |
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81 | (4) |
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85 | (1) |
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86 | (2) |
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86 | (2) |
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4.1 Introduction of the Work and Heat |
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88 | (1) |
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88 | (2) |
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4.3 Quasi-Static Processes |
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90 | (1) |
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4.4 Quasi-Equilibrium Work due to Moving Boundary |
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91 | (4) |
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4.5 Definition of a Cycle in Thermodynamics |
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95 | (1) |
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4.6 Path Functions and Point or State Functions |
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96 | (2) |
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4.7 PdV Work for Quasi-Static Process |
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98 | (3) |
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101 | (1) |
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102 | (9) |
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4.10 Reversible and Irreversible Processes |
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111 | (1) |
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4.11 Definition of Energy (Thermal Energy or Internal Energy) |
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112 | (1) |
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113 | (1) |
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4.13 Comparison of Work and Heat |
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114 | (6) |
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117 | (1) |
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117 | (3) |
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5 First Law of Thermodynamics |
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120 | (2) |
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5.2 System and Surroundings |
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122 | (2) |
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5.3 Signs for Heat and Work in Thermodynamics |
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124 | (1) |
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5.4 Work Done During Volume Changes |
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125 | (3) |
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5.5 Paths Between Thermodynamic States |
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128 | (3) |
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131 | (1) |
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132 | (1) |
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5.8 Heat as Energy in Transition |
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133 | (1) |
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5.9 The First Law of Thermodynamics Applied to a Cycle |
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134 | (1) |
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135 | (1) |
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5.11 Heat Is a Path Function |
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135 | (2) |
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5.12 Energy Is a Property of a System |
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137 | (1) |
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5.13 Energy of an Isolated System is Conserved |
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138 | (2) |
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5.14 Internal Energy and the First Law of Thermodynamics |
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140 | (5) |
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5.15 Internal Energy of an Ideal Gas |
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145 | (1) |
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5.16 Introduction to Enthalpy |
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146 | (1) |
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147 | (2) |
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149 | (6) |
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5.19 Heat Capacities of an Ideal Gas |
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155 | (2) |
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5.20 Adiabatic Processes for an Ideal Gas |
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157 | (5) |
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162 | (3) |
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163 | (2) |
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6 Second Law of Thermodynamics |
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165 | (1) |
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6.2 Heat Engines, Heat Pumps, and Refrigerators |
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166 | (1) |
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6.3 Statements of the Second Law of Thermodynamics |
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167 | (1) |
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168 | (1) |
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168 | (3) |
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6.6 The Concept of Entropy |
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171 | (2) |
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6.7 The Concept of Entropy in Ideal Gas |
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173 | (2) |
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6.8 Entropy for an Ideal Gas With Variable Specific Heats |
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175 | (2) |
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6.9 Entropy for Steam, Liquids, and Solids |
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177 | (1) |
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6.10 The Inequality of Clausius |
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178 | (1) |
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6.11 Entropy Change for an Irreversible Process |
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179 | (2) |
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6.12 The Second Law Applied to a Control Volume |
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181 | (4) |
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183 | (2) |
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7 The Kinetic Theory of Gases |
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7.1 Kinetic Theory Basis for the Ideal Gas Law |
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185 | (4) |
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7.2 Collisions With a Moving Wall |
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189 | (1) |
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7.3 Real Gas Effects and Equations of State |
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190 | (1) |
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7.4 Principle of Corresponding States |
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191 | (1) |
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7.5 Kinetic Theory of Specific Heat |
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192 | (3) |
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7.6 Specific Heat for Solids |
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195 | (1) |
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7.7 Mean Free Path of Molecules in a Gas |
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196 | (2) |
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7.8 Distribution of Mean Free Paths |
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198 | (1) |
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7.9 Coefficient of Viscosity |
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199 | (3) |
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7.10 Thermal Conductivity |
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202 | (3) |
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204 | (1) |
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204 | (1) |
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8 Reversible Work, Irreversibility, and Exergy (Availability) |
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8.1 Reversible Work and Irreversibility |
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205 | (3) |
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208 | (6) |
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212 | (2) |
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9 Gas Kinetic Theory of Entropy |
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9.1 Some Elementary Microstate and Macrostate Models |
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214 | (6) |
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9.2 Stirling's Approximation for Large Values of N |
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220 | (1) |
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9.3 The Boltzmann Distribution Law |
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221 | (3) |
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9.4 Estimating the Width of the Most Probable Macrostate Distribution |
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224 | (3) |
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9.5 Estimating the Variation of W With the Total Energy |
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227 | (1) |
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9.6 Analyzing an Approach to Thermal Equilibrium |
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228 | (1) |
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9.7 The Physical Meaning of β |
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229 | (1) |
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9.8 The Concept of Entropy |
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230 | (1) |
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231 | (1) |
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9.10 Indistinguishable Objects |
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231 | (7) |
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9.11 Evaluation of Partition Functions |
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238 | (4) |
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9.12 Maxwell---Boltzmann Velocity Distribution |
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242 | (3) |
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243 | (2) |
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10 Thermodynamic Relations |
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10.1 Thermodynamic Potentials |
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245 | (2) |
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247 | (5) |
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252 | (1) |
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10.4 Specific Heat Relations Using the Maxwell Relations |
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253 | (1) |
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10.5 The Difference Between the Specific Heats for a Real Gas |
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254 | (2) |
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10.6 Joule--Thomson Coefficient |
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256 | (4) |
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257 | (1) |
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257 | (3) |
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11.1 Fundamental Modes of Heat Transfer |
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260 | (1) |
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260 | (1) |
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260 | (1) |
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261 | (3) |
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11.5 Heat Conduction in a Slab |
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264 | (1) |
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11.6 Heat Conduction in Curvilinear Geometries |
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265 | (4) |
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269 | (1) |
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11.8 Boundary Layer Concept |
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269 | (4) |
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11.9 Dimensionless Numbers or Groups |
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273 | (3) |
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11.10 Correlations for Common Geometries |
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276 | (8) |
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11.11 Enhanced Heat Transfer |
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284 | (3) |
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11.12 Pool Boiling and Forced Convection Boiling |
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287 | (3) |
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11.13 Nucleate Boiling Regimen |
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290 | (3) |
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293 | (3) |
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11.15 Film Boiling Regimen |
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296 | (4) |
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297 | (1) |
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297 | (3) |
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12.1 Heat Exchanger Types |
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300 | (1) |
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12.2 Classification of Heat Exchanger by Construction Type |
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301 | (4) |
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305 | (1) |
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306 | (1) |
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12.5 Classification According to Compactness |
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306 | (1) |
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12.6 Types of Applications |
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307 | (1) |
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307 | (1) |
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12.8 Regenerators and Recuperators |
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307 | (6) |
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12.9 Heat Exchanger Analysis: Use of the Log Mean Temperature Difference |
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313 | (7) |
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12.10 Effectiveness-NTU Method for Heat Exchanger Design |
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320 | (5) |
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12.11 Special Operating Conditions |
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325 | (1) |
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12.12 Compact Heat Exchangers |
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326 | (6) |
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330 | (1) |
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330 | (2) |
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13 Gas Power and Air Cycles |
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332 | (4) |
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13.2 Gas Compressors and the Brayton Cycle |
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336 | (7) |
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13.3 The Nonideal Brayton Cycle |
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343 | (4) |
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13.4 The Air Standard Cycle |
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347 | (4) |
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13.5 Equivalent Air Cycle |
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351 | (1) |
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351 | (4) |
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355 | (6) |
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361 | (5) |
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13.9 Comparison of Otto and Diesel Cycles |
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366 | (2) |
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368 | (4) |
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372 | (2) |
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374 | (2) |
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376 | (2) |
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378 | (2) |
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13.15 Deviation of Actual Cycles from Air-Standard Cycles |
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380 | (1) |
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13.16 Linde---Hampson Cycle |
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381 | (2) |
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383 | (5) |
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385 | (1) |
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385 | (3) |
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14 The Beginning and Concept of Cryogenics, Basic Principles |
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388 | (4) |
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14.2 Quick Summary of Thermodynamics Application in Science of Cryogenics |
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392 | (16) |
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14.3 Heat Transfer Summary |
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408 | (8) |
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14.4 Momentum Transfer and Process |
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416 | (2) |
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14.5 The Beginning of Cryogenics |
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418 | (4) |
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14.6 Ultra Low-Temperature Refrigeration, Cryogenic State |
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422 | (6) |
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14.7 Process of Cool Down to Cryogenic State |
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428 | (29) |
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14.8 Technical Challenges of Cryogenic Fluids Transfer and Transportation |
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457 | (4) |
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461 | (1) |
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14.10 Hazards Associated With Cryogenic Materials |
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462 | (2) |
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464 | (2) |
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14.12 General Safety Practices |
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466 | (1) |
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14.13 Specific Procedures |
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467 | (2) |
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14.14 Storage of Cryogenic Liquids |
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469 | (1) |
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14.15 Cryogenic Storage Tanks |
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469 | (1) |
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14.16 Emergency Procedures and First Aid |
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470 | (1) |
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14.17 Spills and Disposal of Cryogenics |
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471 | (1) |
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472 | (4) |
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472 | (4) |
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15 Transport Properties of Solid at Cryogenic State |
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476 | (4) |
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480 | (17) |
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15.3 General Laws of Radiation |
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497 | (3) |
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15.4 Emissivity, Absorptivity, and Reflectivity at Cryogenic State |
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500 | (3) |
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15.5 Electrical Properties of Materials at Cryogenic State |
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503 | (6) |
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15.6 Refrigeration and Liquefaction |
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509 | (10) |
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15.7 Overall Cooling Methods |
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519 | (1) |
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519 | (2) |
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15.9 Pulse-Tube Refrigerators |
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521 | (2) |
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15.10 Superconductivity at a Cryogenic State |
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523 | (3) |
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526 | (1) |
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15.12 Terms Used in the Cryogenic Field |
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527 | (3) |
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527 | (1) |
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528 | (2) |
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16 Cryogenic Equipment, Systems, and Applications |
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530 | (1) |
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16.2 Compression and Compressors |
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531 | (4) |
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16.3 Expansion Process and Engines |
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535 | (3) |
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538 | (3) |
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541 | (2) |
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543 | (1) |
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543 | (2) |
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16.8 Cryogenic Heat Exchangers |
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545 | (8) |
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16.9 The Right Materials in Heat Exchangers (PFHEs) |
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553 | (1) |
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16.10 Cryogenic PFHE Packaging Options |
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553 | (4) |
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16.11 Other Types of Heat Exchangere for Cryogenic Liquid Natural Gases (LNG) |
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557 | (4) |
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561 | (1) |
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16.13 Cryogenic Liquid Gas Transfer |
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562 | (1) |
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16.14 Cryogenic Storage Stage and Tanks |
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563 | (2) |
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564 | (1) |
Appendix A Table and Graph Compilations |
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565 | (130) |
Appendix B Cryogenic Material Properties Database |
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695 | (8) |
Index |
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703 | |