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E-raamat: Pollutants Generated by the Combustion of Solid Biomass Fuels

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This book considers the pollutants formed by the combustion of solid biomass fuels. The availability and potential use of solid biofuels is first discussed because this is the key to the development of biomass as a source of energy.
This is followed by details of the methods used for characterisation of biomass and their classification.
The various steps in the combustion mechanisms are given together with a compilation of the kinetic data. The chemical mechanisms for the formation of the pollutants: NOx, smoke and unburned hydrocarbons, SOx, Cl compounds, and particulate metal aerosols are given in detail. Combustion kinetics required for the application for design purposes are given. Examples are given of emission levels of a range different types of combustion equipment. Data is given of NOx, particulates and other pollutant arising from combustion of different fuels in fixed bed combustion, fluidized bed combustion and pulverised biomass combustion and co-firing. Modeling methods including computational fluid dynamics for the various pollutants are outlined. The consequential issues arising from the wide scale use of biomass and future trends are then discussed. In particular the role of carbon capture and storage in large biomass combustion plants is considered as well as the opportunity of reducing the concentration of atmospheric concentration of carbon dioxide.
1 Introduction to Biomass Combustion
1(8)
1.1 The Role of Biomass Combustion in World Energy
1(4)
1.2 Resources---Supply of Biomass
5(4)
References
6(3)
2 Combustion of Solid Biomass: Classification of Fuels
9(16)
2.1 Methods of Utilisation
9(6)
2.2 Forms of Solid Biomass Fuels
15(2)
2.3 Types of Solid Biomass Fuels and Their Classification
17(2)
2.4 Characterisation by Chemical Analysis
19(2)
2.5 Characterisation by TGA, PY-GC-MS and FTIR
21(4)
References
23(2)
3 The Combustion of Solid Biomass
25(20)
3.1 General Mechanism of Combustion
25(3)
3.2 Particle Heating and Moisture Evaporation
28(1)
3.3 Devolatilisation
29(5)
3.4 Combustion of the Volatiles--Gases and Tars
34(2)
3.5 Char Combustion
36(9)
References
41(4)
4 Pollutant Formation and Health Effects
45(18)
4.1 General Feature of Pollutants Arising from Biomass Combustion
45(1)
4.2 Smoke, UBH, Volatiles, PAH and Odour
46(7)
4.3 Nitrogen Oxides (NOx) and Other Nitrogenous Pollutants
53(4)
4.4 Sulphur, Chlorine Compounds and Dioxins
57(1)
4.5 Metals, K--Cl--S Chemistry and Aerosol Emissions
58(5)
References
60(3)
5 Emissions from Different Types of Combustors and Their Control
63(8)
5.1 Emissions from Biomass Combustion
63(1)
5.2 Emissions from Fixed and Travelling Bed Combustors
64(4)
5.3 Emissions from Large Industrial Combustion Plant
68(1)
5.4 Wild Fires
69(2)
References
69(2)
6 Mathematical Modelling
71(28)
6.1 Modelling Biomass Combustion Using Computational Fluid Dynamics
71(8)
6.1.1 Reynolds-Averaged Navier-Stokes Equations
74(3)
6.1.2 Turbulence-Chemistry Interactions
77(2)
6.2 Modelling Pulverised Biomass Particle Combustion
79(8)
6.2.1 Particle Motion
79(5)
6.2.2 Heat Transfer
84(1)
6.2.3 Devolatilisation
85(1)
6.2.4 Char Combustion
86(1)
6.3 Modelling Pulverised Fuel Co-firing in Power Stations
87(4)
6.4 Modelling Fixed Bed Combustion
91(2)
6.5 Modelling Fluidised Bed Combustion
93(1)
6.6 Modelling Pollutant Emissions
93(6)
6.6.1 Nitrogen Oxides
93(1)
6.6.2 SOx Emissions
94(1)
6.6.3 Modelling Aerosol Pollutants
94(2)
References
96(3)
7 Biomass Combustion: Carbon Capture and Storage
99(6)
7.1 Introduction
99(1)
7.2 Combustion with Air or Oxygen
100(2)
7.3 Gasification
102(1)
7.4 Chemical Looping
102(1)
7.5 Carbon Capture and Storage
103(2)
References
103(2)
Appendix A Calculation of Flue Gas Composition 105(2)
Appendix B Gaseous Emissions Conversion Table 107(2)
Appendix C Physical and Thermal Properties of Biomass 109