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E-raamat: Silica-based Organic-inorganic Hybrid Nanomaterials: Synthesis, Functionalization And Applications In The Field Of Catalysis

(-), (Univ Of Delhi, India), (Univ Of Delhi, India), (Univ Of Delhi, India), (Univ Of Delhi, India), (Univ Of Delhi, India), (Univ Of Delhi, India), (Univ Of Delhi, India)
  • Formaat: 276 pages
  • Sari: Sustainable Chemistry Series 4
  • Ilmumisaeg: 05-Nov-2019
  • Kirjastus: World Scientific Europe Ltd
  • Keel: eng
  • ISBN-13: 9781786347480
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  • Formaat: 276 pages
  • Sari: Sustainable Chemistry Series 4
  • Ilmumisaeg: 05-Nov-2019
  • Kirjastus: World Scientific Europe Ltd
  • Keel: eng
  • ISBN-13: 9781786347480

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Currently the field of nanocatalysis is undergoing many exciting developments and the design of silica-based organic-inorganic hybrid nanocatalysts is a key focus of the researchers working in this field.This book aims to present a succinct overview of the recent research progress directed towards the fabrication of silica-based organic-inorganic hybrid catalytic systems encompassing the key advantages of silica nanoparticles and silica-coated magnetic nanoparticles in an integrated manner. Featuring comprehensive descriptions of almost all approaches utilized for the synthesis of nanomaterials including some latest techniques such as flow and microwave-assisted synthesis that enable large-scale synthesis, it proves useful not only to academics but also industrialists. It also includes a systematic discussion on the vital characterization techniques employed for authenticating the structure of these.The title also offers an enormous amount of knowledge about the fusion of nanotechnology with green chemistry that strives to meet the scientific challenges of protecting human health and the environment.
Foreword v
Preface vii
About Professor R. K. Sharma xi
Chapter 1 An Introduction to Silica-Based Organic-Inorganic Hybrid Nanostructured Catalytic Systems
1(32)
Shivani Sharma
Manavi Yadav
Sriparna Dutta
Rakesh Kumar Sharma
1.1 Introduction
1(3)
1.2 Nanomaterials --- Definition and Classification
4(3)
1.3 Synthetic Approaches of Nanomaterials
7(1)
1.4 Catalysis
8(13)
1.5 A Paradigm Shift Toward Green Chemistry and Nanocatalysis
21(2)
1.6 Nanocatalysis in Chemical Industries
23(1)
1.7 Case Studies
23(4)
1.8 Conclusion
27(1)
References
28(5)
Chapter 2 Silica Nanoparticles: A Smart and Promising Support Material for the Design of Heterogeneous Catalytic Systems
33(34)
Sriparna Dutta
Rashmi Gaur
Shivani Sharma
Rakesh Kumar Sharma
2.1 Introduction
33(3)
2.2 Surface Chemistry of Silica
36(1)
2.3 Classification of SNPs
37(2)
2.4 Synthesis of SNPs
39(21)
2.5 Properties of SNPs
60(2)
2.6 Toxicology of SNPs
62(1)
2.7 Conclusion
62(1)
References
63(4)
Chapter 3 Silica-Encapsulated Magnetic Nanoparticles
67(30)
Yukti Monga
Radhika Gupta
Rashmi Gaur
Rakesh Kumar Sharma
3.1 Introduction
67(2)
3.2 Methods for the Synthesis of Fe3O4
69(1)
3.3 Coating of MNPs
70(3)
3.4 Coating of MNPs with Silica
73(3)
3.5 Methods of Silica Coating
76(8)
3.6 Silica-Coating Regulations
84(4)
3.7 Properties of SMNPs
88(3)
3.8 Conclusion
91(1)
References
92(5)
Chapter 4 Different Approaches for Surface Modification
97(48)
Manavi Yadav
Yukti Monga
Gunjan Arora
Rakesh Kumar Sharma
4.1 Introduction
97(3)
4.2 General Approaches to Surface Modification of Nanostructures
100(3)
4.3 Prime Applications of Surface-Modified Silica-Based Nanomaterials
103(36)
4.4 Conclusion
139(1)
References
139(6)
Chapter 5 Characterization of Metal-Immobilized Silica Nanoparticles and Silica-Coated Magnetic Nanoparticles
145(26)
Rashmi Gaur
Shivani Sharma
Yukti Monga
Rakesh Kumar Sharma
5.1 Introduction
145(1)
5.2 Transmission Electron Microscopy
146(3)
5.3 Scanning Electron Microscopy
149(1)
5.4 X-ray Diffraction
150(3)
5.5 Fourier Transform Infrared Spectroscopy
153(3)
5.6 Vibrating Sample Magnetometer
156(3)
5.7 Energy-Dispersive X-ray Spectroscopy
159(1)
5.8 X-ray Photoelectron Spectroscopy
160(1)
5.9 Thermal Gravimetric Analysis
160(1)
5.10 BET Surface Area Analysis
161(2)
5.11 Nuclear Magnetic Resonance
163(2)
5.12 Atomic Absorption Spectroscopy/Inductive-Coupled Plasma-Optical Emission Spectroscopy (AAS/ICP-OES)
165(1)
5.13 Scanning Transmission Electron Microscopy
166(2)
5.14 Atomic Force Microscopy
168(1)
5.15 Conclusion
168(1)
References
168(3)
Chapter 6 Catalytic Applications of Silica-Based Organic-Inorganic Hybrid Nanomaterials for Different Organic Transformations
171(50)
Radhika Gupta
Gunjan Arora
Manavi Yadav
Rakesh Kumar Sharma
6.1 Introduction
171(3)
6.2 Applications of Silica-Based Nanomaterials in Catalysis
174(34)
6.3 Critical Comparison with Other Supported Catalysts
208(5)
6.4 Conclusion
213(1)
References
213(8)
Chapter 7 Other Potential Catalytic Applications and Future Perspectives
221(38)
Gunjan Arora
Sriparna Dutta
Radhika Gupta
Rakesh Kumar Sharma
7.1 Introduction
221(2)
7.2 Potential Catalytic Applications of Silica-Based Nanomaterials
223(30)
7.3 Conclusion and Future Perspectives
253(1)
References
254(5)
Index 259