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E-raamat: Static Compression of Energetic Materials

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Developing and testing novel energetic materials is an expanding branch of the materials sciences. Reaction, detonation or explosion of such materials invariably produce extremely high pressures and temperatures. To study the equations-of-state (EOS) of energetic materials in extreme regimes both shock and static high pressure studies are required. The present volume is an introduction and review of theoretical, experimental and numerical aspects of static compression of such materials. Chapter 1 introduces the basic experimental tool, the diamond anvil pressure cell and the observational techniques used with it such as optical microscopy, infrared spectrometry and x-ray diffraction. Chapter 2 outlines the principles of high-nitrogen energetic materials synthesis. Chapters 3 and 4, examine and compare various EOS formalisms and data fitting for crystalline and  non-crystalline materials, respectively. Chapter 5 details the reaction kinetics of detonating energetic materials. Chapter 6 investigates the interplay between static and dynamic (shock) studies. Finally, Chapters 7 and 8 introduce numerical simulations: molecular dynamics of energetic materials under either  hydrostatic or uni-axial stress and ab-inito treatments of defects in crystalline materials. This timely volume meets the growing demand for a state-of-the art introduction and review of the most relevant aspects of static compression of energetic materials and will be a valuable reference to researchers and scientists working in academic, industrial and governmental research laboratories.
Preface v
1 Diamond Anvil Cell Techniques 1
Gasper J. Piermarini
2 Synthesis of High-Nitrogen Energetic Material 75
Mikhail I. Eremets, Ivan A. Trojan, Alexander G. Gavriliuk, and Sergey A. Medvcdev
3 Equations of State and High-Pressure Phases of Explosives 99
Suhithi M. Peiris and Jared C. Gump
4 Equations of State of Binders and Related Polymers 127
Dana M. Dattelbaum and Lewis L. Stevens
5 Reaction Kinetics 203
Suhithi M. Peiris
6 Understanding Shock-Induced Changes in Molecular Crystals 219
Zbigniew A. Dreger
7 Equilibrium Molecular Dynamics Simulations 255
Betsy M. Rice and Thomas D. Sewell
8 Modeling Defect-Induced Phenomena 291
Maija M. Kuklja and Sergey N. Rashkeev
Index 327