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Introduction to Thermodynamics and Phase Transitions |
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1 | (30) |
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Thermodynamic Variables: Simple Fluids |
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1 | (2) |
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Change of Variable and Thermodynamic Potentials |
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3 | (1) |
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Response Functions and Thermodynamic Relations |
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4 | (2) |
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6 | (1) |
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Stationary Properties of Thermodynamic Functions |
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7 | (2) |
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Phase Equillibrium in the Van der Waals Gas |
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9 | (3) |
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The Field-Extensive Variable Representation of Thermodynamics |
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12 | (4) |
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The Field-Density Representation of Thermodynamics |
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16 | (2) |
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General Theory of Phase Equilibrium |
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18 | (5) |
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19 | (3) |
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22 | (1) |
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Classical Theory and Metastability |
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23 | (8) |
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Metastability in a One-Component Fluid |
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25 | (2) |
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The Experimental Situation |
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27 | (1) |
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28 | (3) |
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Statistical Mechanics and the One-Dimensional Ising Model |
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31 | (36) |
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The Canonical Distribution |
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31 | (4) |
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33 | (1) |
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Kinetic and Configuration Variables |
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33 | (2) |
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35 | (4) |
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39 | (3) |
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The Constant Magnetic Field Distribution |
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39 | (1) |
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The Constant-Pressure (Isobaric) Distribution |
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39 | (1) |
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40 | (1) |
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Restricted Distributions for Lattice Models |
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40 | (2) |
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Magnetism and the Ising Model |
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42 | (7) |
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The One-Dimensional Ferromagnet in Zero Field |
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44 | (3) |
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The One-Dimensional Ferromagnet in a Field |
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47 | (2) |
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49 | (4) |
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53 | (4) |
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The One-Dimensional Ising Ferromagnet |
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54 | (2) |
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56 | (1) |
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A One-Dimensional Model for DNA Denaturation |
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57 | (10) |
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63 | (4) |
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The Mean-Field Approximation, Scaling and Critical Exponents |
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67 | (26) |
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The Ising Model Ferromagnet |
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67 | (9) |
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Free Energy and Magnetization |
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68 | (3) |
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Fluctuations in Zero field |
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71 | (5) |
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Interpretations of the Mean-Field Method |
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76 | (2) |
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Many-Neighbour Interactions and the Lebowitz-Penrose Theorem |
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76 | (1) |
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A Distance-Independent Interaction |
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77 | (1) |
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The Mean-Field Method for a More General Model |
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78 | (1) |
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Critical Points and Critical Exponents |
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79 | (5) |
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Scaling and Exponent Relations |
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84 | (2) |
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Classical Critical Exponents |
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86 | (7) |
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The Ising Model Ferromagnet: Mean-Field Approximation |
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87 | (1) |
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88 | (2) |
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90 | (3) |
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Antiferromagnets and Other Magnetic Systems |
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93 | (26) |
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The One-Dimensional Antiferromagnet |
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93 | (1) |
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Antiferromagnetic Ising Models |
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94 | (5) |
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99 | (6) |
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100 | (1) |
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The Antiferromagnetic State |
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101 | (2) |
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The Simple Antiferromagnet |
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103 | (2) |
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Metamagnetism: Tricritical Points and Critical End-Points |
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105 | (5) |
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Ferrimagnetism: Compensation Points |
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110 | (9) |
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113 | (1) |
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114 | (3) |
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117 | (2) |
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119 | (16) |
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119 | (2) |
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The One-Dimensional Lattice Gas and the Continuous Limit |
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121 | (4) |
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121 | (3) |
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124 | (1) |
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The Simple Lattice Gas and the Ising Model |
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125 | (2) |
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Phase Separation in the Simple Lattice Gas |
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127 | (1) |
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A One-Dimensional Water-Like Model |
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128 | (7) |
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132 | (3) |
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Solid Mixtures and the Dilute Ising Model |
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135 | (38) |
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The Restricted Grand Partition Fuction |
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135 | (1) |
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136 | (2) |
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The Equivalence to the Ising Model |
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137 | (1) |
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The Equivalence to a Lattice Gas |
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138 | (1) |
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Order-Disorder on Loose-Packed Lattices |
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138 | (3) |
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The Order Parameter and Landau Expansion |
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141 | (3) |
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First-Order Sublattice Transitions |
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144 | (3) |
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The Equilibrium Dilute Ising Model and Equivalent Models |
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147 | (4) |
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The Equilibrium Dilute Ising Model |
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147 | (2) |
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The Ising Model Lattice Gas |
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149 | (1) |
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The Symmetrical Ternary Solid Mixture |
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149 | (1) |
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The Symmetrical Lattice Gas Mixture |
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150 | (1) |
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151 | (1) |
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151 | (1) |
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Mean-Field Theory and the Dilute Ising Model |
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151 | (3) |
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Multicritical Points in the Dilute Ising Model |
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154 | (4) |
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Multicritical Phenomena with Additional Thermodynamic Dimension |
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158 | (5) |
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The Unsymmetrical and Completely Symmetrical Models |
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163 | (3) |
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Alternatives Forms for the Dilute Ising Model |
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166 | (7) |
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Equilibrium Bond Dilution |
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166 | (1) |
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167 | (1) |
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167 | (1) |
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Equilibrium Site Dilution ε < 0 |
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168 | (1) |
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169 | (4) |
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Cluster Variation Methods |
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173 | (32) |
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173 | (1) |
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A First-Order Method Using a General Site Group |
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174 | (4) |
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174 | (3) |
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177 | (1) |
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The Pair Approximation and the Ising Model |
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178 | (3) |
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179 | (1) |
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180 | (1) |
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181 | (1) |
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Phase Transitions in Amphipathic Monolayers |
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181 | (6) |
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A Lattice Gas Model for Fluid Water |
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187 | (6) |
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Ordering on the Face-Centred Cubic Lattice |
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193 | (4) |
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197 | (8) |
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200 | (5) |
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Exact Results for Two-Dimensional Ising Models |
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205 | (36) |
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205 | (1) |
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The Low-Temperature Form and the Dual Lattice |
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206 | (2) |
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The High-Temperature Form and the Dual Transformation |
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208 | (3) |
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The Star-Triangle Transformation |
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211 | (3) |
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The Star-Triangle Transformation with Unequal Interactions |
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214 | (2) |
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A Linear Relation for Correlations |
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216 | (2) |
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Baxter and Enting's Transformation and the Functional Equation |
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218 | (2) |
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The Solution of the Functional Equation |
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220 | (6) |
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A Preliminary Result of f (K&varbar;κ) |
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221 | (2) |
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Expressions for A(∞&varbar;κ) and B (∞&varbar;κ) |
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223 | (1) |
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224 | (2) |
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226 | (3) |
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Thermodynamic Functions for the Square Lattice |
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229 | (3) |
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Thermodynamic Functions for the Triangular and Honeycomb Lattices |
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232 | (3) |
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235 | (6) |
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238 | (3) |
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Applications of Transform Methods |
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241 | (52) |
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The Decoration Transformation |
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241 | (3) |
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244 | (2) |
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244 | (1) |
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The Equilibrium Bond Dilute Ising Model |
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245 | (1) |
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Heat Capacity and Exponent Renormalization |
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246 | (5) |
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Three-Dimensional Lattices |
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247 | (3) |
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250 | (1) |
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Fisher's Decorated Antiferromagnetic Model |
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251 | (5) |
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The Decorated Lattice Ferrimagnet |
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256 | (6) |
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The Kagome Lattice Ising Model |
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262 | (2) |
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A Modified Star-Triangle Transformation and Three-Spin Correlation |
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264 | (2) |
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The Star-Triangle Ferrimagnet |
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266 | (2) |
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The Unsymmetrical Ising Model |
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268 | (3) |
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A Competing Interaction Magnetic Model |
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271 | (2) |
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Decorated Lattice Mixtures of Orientable Molecules |
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273 | (5) |
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The Decorated Lattice Gas |
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278 | (11) |
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278 | (3) |
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281 | (2) |
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Maxithermal, Critical Double and Cuspoidal Points |
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283 | (6) |
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Decorated Lattice Gas Mixtures |
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289 | (4) |
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290 | (3) |
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293 | (42) |
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Two-Dimensional Ice-Rule Models |
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293 | (2) |
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295 | (2) |
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Graphical Representation and Ground States |
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297 | (2) |
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Free Energy and Transfer Matrices |
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299 | (2) |
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Transfer Matrix Eigenvalues |
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301 | (5) |
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302 | (1) |
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302 | (2) |
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304 | (2) |
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The Low-Temperature Frozen Ferroelectric State |
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306 | (1) |
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307 | (2) |
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The Solution of the Integral Equation for -1 < Δ < 1 |
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309 | (2) |
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The Free Energy of the Disordered State |
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311 | (2) |
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312 | (1) |
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312 | (1) |
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313 | (1) |
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The Ferroelectric Transition in Zero Field |
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313 | (3) |
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The Antiferroelecrtic State |
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316 | (3) |
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Fild-Induced Transitions to the Completely Polarized State |
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319 | (3) |
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An Antiferroelectric in an Electric Field |
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322 | (3) |
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325 | (10) |
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The Staggered Six-Vertex Model |
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326 | (3) |
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The Solvable Case ΞhΞ = 1 |
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329 | (1) |
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The Solvabel Case ΞhΞv = -1 |
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330 | (1) |
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The Polarization and Internal Energy |
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331 | (1) |
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332 | (1) |
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332 | (3) |
A. Appendices |
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335 | (16) |
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335 | (2) |
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A.2 Elliptic Integrals and Functions |
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337 | (5) |
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A.2.1 Eiiliptic Integrals |
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338 | (1) |
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339 | (1) |
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A.2.3 Results Required for Chapter 8 |
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340 | (2) |
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A.3 The Water Molecule and Hydrogen Bonding |
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342 | (2) |
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A.4 Results for the Six-Vertex Model |
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344 | (5) |
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345 | (1) |
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345 | (1) |
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345 | (3) |
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348 | (1) |
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A.5 Fourier Transforms and Series |
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349 | (2) |
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349 | (1) |
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349 | (2) |
References and Author Index |
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351 | (14) |
Subject Index |
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365 | |