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E-raamat: Subsurface Contamination Monitoring Using Laser Fluorescence

(Rice University, Houston, Texas, USA), (Rice University, Houston, Texas, USA), (Bellaire, Texas, USA)
  • Formaat: EPUB+DRM
  • Sari: AATDF Monograph Series
  • Ilmumisaeg: 16-Aug-2019
  • Kirjastus: CRC Press Inc
  • Keel: eng
  • ISBN-13: 9781000724462
  • Formaat - EPUB+DRM
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  • Formaat: EPUB+DRM
  • Sari: AATDF Monograph Series
  • Ilmumisaeg: 16-Aug-2019
  • Kirjastus: CRC Press Inc
  • Keel: eng
  • ISBN-13: 9781000724462

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While innovative technologies in remediation need to be developed, so do innovative ways of site assessment. This monograph describes the development, testing, and performance of a new laser-induced fluorescence soil probe. A screening tool for site characterization, this probe has the potential to provide an economical, rapid assessment of contaminated sites. Cone Penetrometer testing equipment advances the probe into the subsurface. The probe identifies hydrocarbon classes using a multi-channel excitation-emission matrix. This technique facilitates the collection of significant amounts of subsurface information - surpassing conventional data collection methods - that can be used to rapidly identify areas of concern beneath a site. The technology has significant application for the following:

Rapid environmental site assessment

Monitoring remediation programs

Monitoring manufacturing processes and industrial waste water operations Subsurface Contamination Monitoring Using Laser Fluorescence provides comprehensive reference material for researchers and engineers as well as engineering consultants interested in subsurface monitoring techniques or further development of this technology. It describes innovative technology that focuses on finding cost effective solutions for site assessment and remediation.

Arvustused

"...easily the best and most up-to-date book this reviewer has read on the subject... Given the reasonable price for this book, the quality and quantity of information contained, and its timeliness, it is highly recommended." -Choice

Executive Summary 1(2)
Introduction
3(4)
LIF-CPT Technology for Site Monitoring
3(1)
Project Background and Phases
4(3)
LIF-EEM Engineering Design
7(18)
Excitation-Emission Matrix
7(1)
Design Goals
8(1)
Selection of Excitation Wavelengths
8(3)
System Components
11(7)
Nd:YAG Laser
11(1)
Raman Shifter and Excitation Beams
12(2)
Multichannel Optical Fiber and Launch Assemblies
14(2)
LIF Probe
16(1)
Detection System
17(1)
Laser Energy Calibration at the Probe
18(2)
EEM Data Analysis
20(3)
Cone Penetrometer Testing Equipment
23(2)
Summary of Technology Demonstration
25(14)
General Scope of Field Work
25(1)
Field Test No. 1: Hanscom AFB
26(7)
Site Conditions
26(1)
Field Operations
26(2)
Soil Sample Collection and Analysis
28(1)
Equipment Calibration
29(1)
Summary of Equipment and Software Performance
29(3)
Presentation of Fluorescence Data
32(1)
Field Test No. 2: Otis Air National Guard Base
33(6)
Site Conditions
33(2)
Field Operations
35(1)
Equipment Calibration
36(1)
Soil Sample Collection and Analysis
37(1)
Summary of Equipment and Software Performance
37(1)
Presentation of Fluorescence Data
38(1)
Data Interpretation and Evaluation
39(26)
General Scope of Data Analysis
39(1)
Hanscom AFB Data Analysis Results
39(3)
Data Analysis for Otis Field Operation
42(23)
LIF Calibrations and Tests Performed in Tufts Laboratory
44(6)
Results of On-Site Soil Sampling
50(2)
Results of In Situ LIF Measurements
52(13)
Outlook
65(2)
Developmental Goals
65(1)
Post-AATDF Development
65(1)
Field Testing
66(1)
Applicability of the LIF-EEM Technology
67(4)
Detectable Contaminants
67(1)
Use of Data for Human Health Risk Assessments
68(1)
Limitations
68(1)
Equipment Development And Patent Considerations
69(2)
Comparison with other LIF Systems
71(8)
Common Components
71(1)
SCAPS System
72(1)
Engineering Design
72(1)
Data Presentation
72(1)
Fugro Geosciences' ROST™ System
73(1)
Engineering Design
73(1)
Data Presentation
73(1)
Tufts University System
74(1)
Typical Costs
75(4)
References
77(2)
Appendices 79(1)
A. Design Manual for the Laser-Induced Fluorescence Cone Penetrometer Tool
79(1)
A.1 Introduction
79(1)
A.2 Experimental Strategy
80(1)
A.3 Theory of Components
80(1)
A.3.1 Properties of Lasers and Stimulated Raman Scattering (SRS)
80(1)
A.3.2 Light Throughput in Optical Fibers
81(3)
A.3.3 Probe Interface
84(1)
A.3.4 Optical Detection System
84(3)
A.3.5 Cone Penetrometry
87(1)
A.4 Design and Assembly of Components
88(1)
A.4.1 Laser Excitation Table
88(3)
A.4.2 Optical Fibers and Light Delivery
91(1)
A.4.3 LIF Probe and Sampling Interface
93(1)
A.4.4 Detection Instrumentation
94(2)
A.5 System Performance
96(1)
A.5.1 Excitation System
96(2)
A.5.2 LIF-CPT Probe
98(1)
A.5.3 Detector/Fiber Interface
99(1)
A.5.4 CCD Detector Performance
99(1)
References
100(1)
B. Operation and Calibration Manual for the Laser Excitation-Emission Matrix Cone Penetrometer Tool
101(1)
B.1 Introduction
101(1)
B.2 Assembly of LIF/CPT System
102(1)
B.2.1 Fiber Probe Assembly
102(1)
B.2.1.1 Material
102(1)
B.2.1.2 Assembly of Fiber Probe
103(4)
B.3 Assembly of Laser Breadboard
107(1)
B.3.1 Installation of Flashlamp
107(1)
B.3.2 Installation of Harmonic Generation (HG) Modules
107(1)
B.3.3 Laser Alignment Verification
108(1)
B.3.4 Assembly of Raman Shifter
108(1)
B.3.5 Optics Alignment on the Optical Breadboard
109(1)
B.4 Calibration of LIF/CPT Tool
109(1)
B.4.1 Detection System Alignment and Calibration
109(1)
B.4.1.1 Alignment and Focusing of the Detection System
109(1)
B.4.1.2 Imaging
110(1)
B.4.1.3 Linearizing a CCD
111(1)
B.4.2 Calibration of the LIF Probe
111(1)
B.4.2.1 Determination of Instrument Artifacts
111(1)
B.4.2.2 Energy/Photon Normalization
112(2)
B.5 Operation of the LIF/EEM/CPT Tool
114(1)
Glossary of Terms
115(1)
References
116(1)
C. Excitation-Emission Matrices Collected in the Laboratory, from Hanscom AFB, and at Otis ANGB
117


Balshaw-Biddle\, Katharine; Oubre\, Carroll L.; Ward\, C. H.