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E-raamat: Thermodynamic Weirdness

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  • Sari: The MIT Press
  • Ilmumisaeg: 19-Mar-2019
  • Kirjastus: MIT Press
  • Keel: eng
  • ISBN-13: 9780262351331
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  • Formaat: EPUB+DRM
  • Sari: The MIT Press
  • Ilmumisaeg: 19-Mar-2019
  • Kirjastus: MIT Press
  • Keel: eng
  • ISBN-13: 9780262351331

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Don S. Lemons is Professor of Physics Emeritus at Bethel College in North Newton, Kansas, and the author of Drawing Physics: 2,600 Years of Discovery From Thales to Higgs.

Don S. Lemons is Professor of Physics Emeritus at Bethel College in North Newton, Kansas, and the author of Drawing Physics: 2,600 Years of Discovery From Thales to Higgs.

Students of physics, chemistry, and engineering are taught classical thermodynamics through its methods—a “problems first” approach that neglects the subject's concepts and intellectual structure. In Thermodynamic Weirdness, Don Lemons fills this gap, offering a nonmathematical account of the ideas of classical thermodynamics in all its non-Newtonian “weirdness.” By emphasizing the ideas and their relationship to one another, Lemons reveals the simplicity and coherence of classical thermodynamics.

Lemons presents concepts in an order that is both chronological and logical, mapping the rise and fall of ideas in such a way that the ideas that were abandoned illuminate the ideas that took their place. Selections from primary sources, including writings by Daniel Fahrenheit, Antoine Lavoisier, James Joule, and others, appear at the end of most chapters. Lemons covers the invention of temperature; heat as a form of motion or as a material fluid; Carnot's analysis of heat engines; William Thomson (later Lord Kelvin) and his two definitions of absolute temperature; and energy as the mechanical equivalent of heat. He explains early versions of the first and second laws of thermodynamics; entropy and the law of entropy non-decrease; the differing views of Lord Kelvin and Rudolf Clausius on the fate of the universe; and the zeroth and third laws of thermodynamics, and Einstein's assessment of classical thermodynamics as “the only physical theory of universal content which I am convinced will never be overthrown.”

Preface ix
Acknowledgments xiii
1 Inventing Temperature
1(12)
1.1 Hot and Cold
1(1)
1.2 Thermometers
1(3)
1.3 Empirical Temperature
4(1)
1.4 The Problem of Nomic Measurement
4(3)
1.5 Linearity, the Method of Mixtures, and Reproducibility
7(1)
1.6 Air Thermometers
8(2)
Daniel G. Fahrenheit, 1724
10(3)
2 Heat and Caloric
13(22)
2.1 Quantifying and Conserving Heat
13(2)
2.2 Caloric
15(2)
2.3 The Motion We Call Heat
17(1)
2.4 Heat in Thermodynamics
18(17)
Joseph Black 1764
19(4)
Antoine Lavoisier, 1789
23(5)
Benjamin Thompson (Count Rum ford), 1798
28(7)
3 Carnot's Analysis
35(26)
3.1 Steam Engines
35(1)
3.2 Carnot's Law
36(2)
3.3 Carnot's Waterwheel
38(1)
3.4 Carnot's Engine
39(3)
3.5 Reversibility and Carnot's Theorem
42(1)
3.6 Carnot's Function
43(18)
Sadi Carnot, 1824
46(15)
4 Absolute Temperature
61(14)
4.1 William Thomson
61(1)
4.2 Thomson's 1848 Definition of Absolute Temperature
62(2)
4.3 Carnot's Function Revealed
64(1)
4.4 Prelude and Postlude
65(10)
William Thomson (Kelvin), 1848
66(9)
5 Mechanical Equivalent of Heat
75(22)
5.1 Caloric: Conserved or Consumed?
75(2)
5.2 Julius Robert von Mayer
77(1)
5.3 Mechanical Equivalent of Heat
78(4)
5.4 James Joule
82(15)
Robert von Mayer 1842
85(7)
James Joule, 1845
92(5)
6 First Law of Thermodynamics
97(16)
6.1 Rudolf Clausius
97(2)
6.2 System, State, and Boundary
99(2)
6.3 The First Law
101(2)
6.4 Energy in Thermodynamic and Newtonian Systems
103(1)
6.5 The Conservation of Energy
103(10)
Rudolf Clausius 1850
105(3)
Rudolf Clausius, 1854
108(5)
7 Second Law of Thermodynamics
113(5)
7.1 The Independence of the First and Second Laws
113(2)
7.2 Carnot's Second Law
115(2)
7.3 Clausius's Second Law
117(1)
7 A Thomson's Second Law
118(9)
7.5 "As Many Formulations"
120(7)
Rudolf Clausius, 1863
121(6)
8 Absolute Temperature---Again
127(10)
8.1 Another Try
127(3)
8.2 Thomson's Simple Choice
130(2)
8.3 Absolute Zero
132(1)
8.4 The 1848 and 1851 Definitions Harmonized
133(4)
William Thomson (Kelvin), 1851
134(3)
9 Entropy
137(12)
9.1 The Word Entropy
137(1)
9.2 Incrementing Entropy
138(1)
9.3 Entropy's Deep Foundations
139(2)
9.4 Clausius's Theorem Illustrated
141(1)
9.5 But What Is Entropy, Really?
142(7)
Rudolf Clausius, 1862
144(5)
10 Law of Entropy Nondecrease
149(8)
10.1 Irreversible Heat Transfer
149(2)
10.2 Irreversible Work
151(2)
10.3 The Law of Entropy Nondecrease
153(4)
11 The Fate of the Universe?
157(6)
11.1 Energy Dissipation
157(1)
11.2 Universal Heat Death
158(5)
Rudolf Clausius, 1865
160(3)
12 Classical Thermodynamics
163(6)
12.1 The Third Law
163(1)
12.2 The Zeroth Law
164(1)
12.3 Einstein on Classical Thermodynamics
165(4)
Annotated Bibliography 169(4)
Index 173