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E-raamat: Water: Molecular Structure And Properties

(Univ Of Electronic Sci & Tech Of China, China)
  • Formaat: 492 pages
  • Ilmumisaeg: 03-Jan-2014
  • Kirjastus: World Scientific Publishing Co Pte Ltd
  • Keel: eng
  • ISBN-13: 9789814440448
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  • Formaat: 492 pages
  • Ilmumisaeg: 03-Jan-2014
  • Kirjastus: World Scientific Publishing Co Pte Ltd
  • Keel: eng
  • ISBN-13: 9789814440448

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Pang reviews all of water science from the evolution of the theory of the molecular structure of water to its verification by experimental results of infrared spectra of absorption, measuring the energy spectrum of vibration, success in self-assembly of water molecules, and the numerical simulation of the structure of water. The new theory holds that water is composed of free water molecules and their clusters with different weights and configurations including linear and ring chains, which are formed by virtue of various hydrogen bonds, he says, so water is not a uniform but a non-uniform liquid. He covers molecular structures of water and its features, the properties of water and its anomalies, magnetic field effects on water and its magnetization, water flow and its non-linear excitation states, and water with life and life activity. Annotation ©2014 Ringgold, Inc., Portland, OR (protoview.com)

Preface v
1 Molecular Structures of Water and Its Features
1(88)
1.1 The New Theory of Molecular Structure in Water and Experimental Evidences
1(9)
1.1.1 The Structure of Water Molecule and Its Polarization Feature
1(5)
1.1.2 The Vibrational Feature of Water Molecule and Its Size
6(1)
1.1.3 The Energy of Water Molecule
6(4)
1.2 The New Theory of Water Molecules in Water and Its Experimental Evidences
10(11)
1.2.1 The Features of Infrared Spectra of Absorption of Water
10(3)
1.2.2 The Chain and Cluster Structure of Molecules in Liquid Water
13(8)
1.3 The Verifications of Numerical Simulation of the New Theory
21(13)
1.3.1 The Methods of the Numerical Simulation and Their Results
21(2)
1.3.2 Quo et al.'s Methods of Numerical Simulation and Their Results
23(3)
1.3.3 Kuo et al.'s Result of Numerical Simulation of Structure of Water Molecules at Finite Temperature
26(1)
1.3.3.1 Low-energy structures: BH with OSS2 model
27(5)
1.3.4 The Icosahedral Cluster of 280 Water Molecules ((H2O)280)
32(2)
1.4 The Conformations of Self-assemble Experiments of the New Theory
34(11)
1.4.1 The Form of Helix Structure of Hydrogen-bonded Chains of Water Molecules in a Staircase Coordination Polymer
35(3)
1.4.2 Dodecameric Cluster of Water Molecules Self-assembled in an Organic Supramolecular Complex of a Cryptand
38(4)
1.4.3 Ring Self-assembled Structure of Water Molecules from Achiral Components
42(3)
1.5 The Changes of Structure of Water Molecules with Varying Temperature
45(22)
1.5.1 The Phase Diagram of Water
45(4)
1.5.2 The Properties of Molecular Structure in Vapor Phase and Its Descriptions
49(7)
1.5.3 The Molecular Structure of Water in Solid Phase and Its Properties
56(1)
1.5.3.1 The ordinary ice (Ih)
56(3)
1.5.3.2 The structure of ices II, III, IV and V
59(1)
1.5.3.3 The structures of ices VI, VII, VIII, IX and X
60(3)
1.5.3.4 The structures of ices XI, XII, XIII, XIV and XV
63(2)
1.5.3.5 The structures of vitreous ice and ice Ic
65(2)
1.6 The Phase Diagram for the Structure of Water Molecules
67(6)
1.7 The Energy Spectrum of Vibration of Water Molecules and Its Properties in Water
73(7)
1.8 The Ionization of Water Molecules and Its Properties
80(9)
References
82(7)
2 The Properties of Water and Its Anomalies
89(114)
2.1 The Basic Properties of Water
90(1)
2.2 The Optical Properties of Water and Its Abnormal Effects
90(14)
2.2.1 Refractive Index of Water and Its Anomaly
90(10)
2.2.2 The Light Scattering of Water
100(1)
2.2.3 The Infrared Absorption of Water and Its Abnormal Effects
101(3)
2.3 The Electromagnetic Properties of Water
104(14)
2.3.1 The Electromagnetic Properties of Water Molecules
104(1)
2.3.2 The Electric Features of Water and Its Singularities
105(5)
2.3.3 The Features of Change of Electromagnetic Property of Water with Varying Electromagnetic and Static Magnetic Fields and Temperature
110(6)
2.3.4 NMR Chemical Shift of Water and Its Peculiarities
116(2)
2.4 Thermodynamic Properties of Water and Its Anomalies
118(24)
2.4.1 Thermal Energy and the Specific Heat of Water and Their Temperature Dependences
118(6)
2.4.2 The Features of Molar Volume and Coefficients of Thermal Expansion of Water
124(4)
2.4.3 The Anomalous Peculiarities of the heat of fusion, Heat of Vaporization, Heat of Sublimation, Entropy of Vaporization and Thermal Conductivity of Water
128(3)
2.4.4 Properties of Melting Point, Boiling Point Molar Heat of Vaporization, Critical Point of Water and Their Anomalies
131(4)
2.4.5 The Properties of Thermal Diffusion Effect of Water and Its Anomaly
135(4)
2.4.6 Thermodynamic Features of Differently Typical Water and Their Anomalies
139(1)
2.4.6.1 The features of supercooled water
139(1)
2.4.6.2 The properties of frozen water
140(1)
2.4.6.3 The peculiarity of superheated water
140(1)
2.4.6.4 Mpemba effect of water
141(1)
2.5 The Mechanical Properties of Water and Its Anomalies
142(6)
2.5.1 The Coefficients of the Compressibility of Water and Its Anomalies
142(4)
2.5.2 The Viscosity of Water and Its Properties
146(2)
2.6 The Properties of Changes in the Structure and Distribution of Molecules in Water in Different Cases
148(19)
2.6.1 The Changes in the Molecular Structure of Water Under Action of High Pressure
148(1)
2.6.2 The Changes in the Number of Nearest Neighbors of Water Molecules in Different Cases
149(1)
2.6.3 The Properties of Motion of Hydrogen Atoms and Molecules in Water
150(2)
2.6.4 The Changes of Vibrational States in Different Water
152(1)
2.6.5 Changes of Thermodynamic Feature of H2O and D2O Liquids
152(5)
2.6.6 The Influences of Solutes and Non-Polar Gases on the Features of Water and Its Solubility
157(2)
2.6.7 The Affections of Salt on Properties of Water
159(2)
2.6.8 The Features of Changes of Speed of Propagation of Sound in Water
161(2)
2.6.9 Changes Density of Distribution of Molecules in Water and its Anomaly in Different Conditions
163(4)
2.7 The Properties of Surface Water and Interfacial Water and Their Anomalies
167(6)
2.7.1 The Features of Surface Tension Coefficient of Water and Its Anomalous Changes
167(4)
2.7.2 The Surface is more Dense than that in Bulk
171(1)
2.7.3 Thermodynamics of the Liquid--Gas Interface for Water
171(2)
2.8 The Quantum Effect of Water and Its Ultrafast Vibrational Dynamics
173(30)
2.8.1 The Isotopic Quantum Effect of Water
173(6)
2.8.2 The Nuclear Quantum Effect of Water
179(3)
2.8.3 Unraveling Quantum Effect of Water and Its Validation
182(3)
2.8.4 Ultrafast Vibrational Dynamics at Water Interfaces
185(5)
References
190(13)
3 The Magnetic Field Effects on Water and Its Magnetization
203(122)
3.1 Investigations on the Interaction of Magnetic Field with Water
203(7)
3.2 Method of Magnetization of Water and Its Technique of Inspection
210(7)
3.2.1 The Correct Method of Magnetization of Water
210(1)
3.2.2 Identified and Inspected Technique of Magnetized Effect of Water
211(5)
3.2.3 Ichiro et al.'s Mechanism of Magnetization of Water Cannot be Accepted
216(1)
3.3 Basic Properties of Magnetized Water
217(20)
3.3.1 Optical Features of Magnetized Water and Corresponding Light Spectra
217(1)
3.3.1.1 Properties of visible and ultraviolet spectra of magnetized water
217(2)
3.3.1.2 Raman spectra of scattering of magnetized water
219(1)
3.3.1.3 Features of infrared absorption of magnetized water
220(5)
3.3.2 The Changes of Mechanical Property of Magnetized Water
225(1)
3.3.2.1 Influence of magnetic field on surface tension force of water
225(3)
3.3.2.2 The changes of viscosity and rheology features of magnetized water
228(4)
3.3.2.3 Influences of the magnetic field on the viscosity of magnetized water
232(1)
3.3.3 The Changes of Electromagnetic Property of Magnetized Water with Varying Externally Applied Field and Magnetized Times
233(2)
3.3.4 The Change of the Thermodynamic Feature of Water Resulting from the Magnetic Field
235(2)
3.4 The Confirmation of Magnetism of Magnetized Water
237(16)
3.4.1 Saturation and Memory Effects of Magnetized Water and Its Hysteresis Curve
237(1)
3.4.1.1 Changed rules for magnetic effect on water with increase in magnetized time and magnetic field strength as well as its saturation effect
237(3)
3.4.1.2 Changes in the feature of magnetized water with decreasing magnetic field and its memory effect
240(1)
3.4.1.3 Hysteresis curve of magnetized water
241(2)
3.4.2 Feature of Interaction of Magnetized Water with Magnetic Nano-Materials
243(2)
3.4.3 Levitation of Magnetized Water in a Magnetic Field and Its Magnetism
245(1)
3.4.3.1 Levitation of magnetized water and its properties
245(3)
3.4.3.2 Discussion of experimental results and the mechanism of magnetized water
248(4)
3.4.4 Measurement of Magnetized Strength of Magnetic Water
252(1)
3.5 Exploration of Mechanism of Magnetization of Water
253(3)
3.6 The Mechanism and Theory of Proton Transfer in Ice and Its Experimental Confirmation
256(28)
3.6.1 The Mechanism and Theory of Proton Transfer in Ice
256(12)
3.6.2 Features of Proton Transfer in Hydrogen-Bonded Systems
268(4)
3.6.3 Mobility and Conductivity of the Protons Conductivity in Ice
272(12)
3.7 Mechanism and Theory of Magnetization of Water
284(3)
3.8 Experimental Confirmation for the Correctness of Theory of Magnetized Water
287(5)
3.9 Instances of Application of Magnetized Water in Biology/Medicine and a Mechanism of Biological Effect of Magnetic Field
292(10)
3.9.1 Biological Effects of Magnetized Water
292(1)
3.9.1.1 Materials and instruments
292(1)
3.9.1.2 The method of investigation
293(2)
3.9.1.3 The experimental results
295(1)
3.9.1.4 The discussion of the results
295(4)
3.9.2 The Distribution and Bio-Functions of Water in Life Bodies and a Mechanism of Biological Effect of Magnetic Field
299(3)
3.10 An Example of Application of Magnetized Water in Industry
302(8)
3.10.1 Enhancement of the Hydrophilic Features of Magnetized Water
302(1)
3.10.2 Changes in the Properties of Concrete Arising from Magnetized Water
303(1)
3.10.2.1 Preparation of concrete containing magnetized water
303(1)
3.10.2.2 Influences of magnetized water on the physical property of concretes
303(7)
3.11 Some Examples of Application of Magnetized Water in Agriculture
310(15)
References
317(8)
4 Water Flow and Its Non-Linear Excitation States
325(64)
4.1 Properties of Steady Flow
325(4)
4.1.1 The States of Laminar Flow of Water
325(2)
4.1.2 The Relationship of Flow Velocity with Flow Quantity of Water
327(1)
4.1.3 The Relationship between Flow Velocity and Pressure and Bernoulli's Equation
328(1)
4.1.4 The Relationship between Flow Quantity and Pressure
328(1)
4.2 Water's Turbulent Flow and Its Properties
329(9)
4.2.1 Water's Turbulent Flow and the Reynolds Number
329(2)
4.2.2 The Essential Differences between Laminar and Turbulent Flows of Water
331(1)
4.2.3 The Dynamic Equation of Movement of the Turbulence
332(1)
4.2.4 The Mechanism of Form of Turbulence and Its Non-Linear Essence
333(5)
4.3 KdV Soliton Excitation in Water and Its Properties
338(6)
4.3.1 Observation of KdV Soliton Excitation in Water
338(1)
4.3.2 Theoretical Description of KdV Soliton in Water
339(5)
4.4 Observation of Non-Propagating Hydrodynamic Soliton in Water and Its Properties
344(28)
4.4.1 Experimental Observation of Non-Propagating Solitary Wave in Water
344(5)
4.4.2 The Properties of Non-Propagating Solitary Wave in Water
349(12)
4.4.3 The Theoretical Researches of Non-Propagating Solitary Wave in Water
361(1)
4.4.3.1 Miles and Larraza et al's theory
361(1)
4.4.3.2 The comparison of the experiment results with the results of the above theories
362(1)
4.4.3.3 Pang's theoretical model of non-propagating solitary wave in water
363(8)
4.4.3.4 Applications of the results in Pang's theoretical model
371(1)
4.5 Form of a Kink Soliton on the Surface of Water and Its Features
372(7)
4.5.1 Experimental Observation of Kink Soliton on the Surface of Water
372(5)
4.5.2 Theoretical Description of Kink Soliton on the Surface of Water
377(2)
4.6 The Vortex States of Water Flows and Its Properties
379(10)
4.6.1 The Vortex Movements of Water Flow and Its Mechanism of Form
379(3)
4.6.2 The Properties of Two-Dimensional Vortexes
382(3)
References
385(4)
5 Water with Life and Life Activity
389(73)
5.1 An Annotation of "There is No Life without Water"
390(5)
5.1.1 The Chain Structures of Protein and Deoxyribonucleic Acid Molecules
390(2)
5.1.2 Annotation of Form of Chain Structure of DNA and Protein Molecules in the Process of Origin of Life
392(3)
5.2 An Explanation of "There is No Life Activity without Water"
395(5)
5.3 Elucidation of "There are no Bio-Cells and Its Proliferation without Water"
400(8)
5.3.1 The Structures of Bio-Cell and Water
400(4)
5.3.2 The Properties and Functions of Intracellular Water
404(2)
5.3.3 The Proliferation of Bio-cells Cannot Depart from Water
406(2)
5.4 No Blood Flow and Transport of Bio-nutritional Material in the Vascellum without Water
408(4)
5.4.1 The Compositions of Blood and Water Biological Functions
408(1)
5.4.2 The Properties of Blood Flow and Its Relationship with Water
409(1)
5.4.3 Water Participates Directly in Some Biological Processes of the Blood Circulation
410(2)
5.5 Hydrophobic and Hydrophilic Effects of Biomolecules
412(16)
5.5.1 Hydrophobic and Hydrophilic Effects of Molecules
412(3)
5.5.2 The Properties of Hydrophobic Hydration Effect
415(3)
5.5.3 Hydrophobic and Hydrophilic Properties of Protein Molecules
418(5)
5.5.4 Hydrophobic and Hydrophilic Properties of DNA
423(5)
5.6 The Hydrations of Ions in Water in Living System
428(7)
5.6.1 The Hydration of Ions in Water
428(4)
5.6.2 The Properties of Water Clustering Around Ions
432(3)
5.7 Hydrations of Salts and Nanocorpuscle in Water in Living System
435(4)
5.7.1 The Hydration State of Salts in Biology
435(1)
5.7.2 The Hydration of Nanocorpuscles in Water
436(3)
5.8 The Interaction of Electrons with Cluster of Water Molecules
439(6)
5.9 Water in Life Systems is a Target of Action of Millimeter Waves
445(9)
5.9.1 Water Molecule's Absorption of Millimeter Wave in the Living Systems
446(2)
5.9.2 Thermal Effects of the Millimeter Waves and Its Biological Functions
448(4)
5.9.3 The Other Mechanism of Thermal Effect of Millimeter Waves
452(2)
5.10 Thermally Biological Effect of Infrared Lights is Due to Thermal Movement of Water Molecules
454(8)
5.10.1 The Mechanism of Thermally Biological Effect of Infrared Lights
455(1)
5.10.2 Thermally Biological Effects of Water Heating by Absorbing Infrared Light
456(4)
5.10.3 Infrared Transmission Spectra of Fingers and Surface of Skin
460(1)
5.10.3.1 Infrared transmission spectrum of person's fingers
461(1)
5.10.3.2 Infrared transmission spectrum of surface skin
461(1)
Acknowledgment 462(1)
References 463(8)
Index 471